Kang Liu

Tungsten oxide nanowires grown on carbon cloth as a flexible cold cathode.

Figure 1 . a) Optical images of the carbon cloth with TONWs, left-inset and right-inset show the optical images of a carbon cloth with TONWs under slight bending and severe bending, respectively. b,c) SEM images of the carbon cloth before and after growing TONWs, respectively. Inset [∗] X. H. Zhang , Y. Z. Cao , X. Xiao , W. M. Sun , Prof. Y. H. Gao , Prof. J. Zhou , Prof. Z. L. Wang Wuhan National Laboratory for Optoelectronics (WNLO) and College of Optoelectronic Science and Engineering Huazhong University of Science and Technology (HUST) Wuhan, 430074 (P. R. China) E-mail: jun.zhou@mail.hust.edu.cn; zhong.wang@mse.gatech.edu L. Gong , Prof. J. Chen Instrumental Analysis & Research Center Sun Yat-sen University Guangzhou, 510275 (P. R. China) K. Liu , Prof. X. J. Hu School of Power and Mechanical Engineering Wuhan University Wuhan, 430072 (P. R. China) Prof. Z. L. Wang School of Materials Science and Engineering Georgia Institute of Technology Atlanta, Georgia 30332-0245 (USA) Nanowire arrays for fi eld emission have attracted a lot of interest in the last few years because of numerous applications such as fl at-panel displays, X-ray radiotherapy, microwave amplifi ers, and vacuum microelectronic devices. [ 1 , 2 ] The growth of fi eld emitters on fl exible substrates may open up numerous fi elds of applications such as roll-up fi eld emission displays (FEDs), [ 3 ]

Oxygen- and Nitrogen-Enriched 3D Porous Carbon for Supercapacitors of High Volumetric Capacity.

Efficient utilization and broader commercialization of alternative energies (e.g., solar, wind, and geothermal) hinges on the performance and cost of energy storage and conversion systems. For now and in the foreseeable future, the combination of rechargeable batteries and electrochemical capacitors remains the most promising option for many energy storage applications. Porous carbonaceous materials have been widely used as an electrode for batteries and supercapacitors. To date, however, the highest specific capacitance of an electrochemical double layer capacitor is only ∼200 F/g, although a wide variety of synthetic approaches have been explored in creating optimized porous structures. Here, we report our findings in the synthesis of porous carbon through a simple, one-step process: direct carbonization of kelp in an NH3 atmosphere at 700 °C. The resulting oxygen- and nitrogen-enriched carbon has a three-dimensional structure with specific surface area greater than 1000 m(2)/g. When evaluated as an electrode for electrochemical double layer capacitors, the porous carbon structure demonstrated excellent volumetric capacitance (>360 F/cm(3)) with excellent cycling stability. This simple approach to low-cost carbonaceous materials with unique architecture and functionality could be a promising alternative to fabrication of porous carbon structures for many practical applications, including batteries and fuel cells.

Robust and Low-Cost Flame-Treated Wood for High-Performance Solar Steam Generation

Solar-enabled steam generation has attracted increasing interest in recent years because of its potential applications in power generation, desalination, and wastewater treatment, among others. Recent studies have reported many strategies for promoting the efficiency of steam generation by employing absorbers based on carbon materials or plasmonic metal nanoparticles with well-defined pores. In this work, we report that natural wood can be utilized as an ideal solar absorber after a simple flame treatment. With ultrahigh solar absorbance (∼99%), low thermal conductivity (0.33 W m-1 K-1), and good hydrophilicity, the flame-treated wood can localize the solar heating at the evaporation surface and enable a solar-thermal efficiency of ∼72% under a solar intensity of 1 kW m-2, and it thus represents a renewable, scalable, low-cost, and robust material for solar steam applications.

Paper‐Based Active Tactile Sensor Array

A paper-based active tactile sensor -array (PATSA) with a dynamic sensitivity of 0.35 V N(-1) is demonstrated. The pixel position of the PATSA can be routed by analyzing the real-time recording voltages in the pressing process. The PATSA performance, which remains functional when removing partial areas, reveals that the device has a potential application to customized electronic skins.

Solar-driven simultaneous steam production and electricity generation from salinity

Solar-driven interfacial water evaporation, which concentrates solar heating at the water surface, has attracted increasing interest in pursuing highly efficient solar desalination. The rapid evaporation of water at the light absorber surface would induce a high concentration comparable with that of brine underlying the interface, which however has been paid much less attention and has never been proposed to produce electricity. Here in this work, we proved that, the theoretical real-time salinity power generated between the surface water and bulk seawater could be 12.5 W m−2 during steam production under one sun illumination. By employing a hybrid system based on a piece of carbon nanotube modified filter paper and a commercial Nafion membrane, we achieved a maximum solar thermal efficiency of up to 75% and derived extra electricity power of ∼1 W m−2 under one sun illumination. These results provide a novel avenue for blue energy utilization, demonstrating the potential for solar desalination and electricity generation under natural sunlight simultaneously.

Wearable Thermocells Based on Gel Electrolytes for the Utilization of Body Heat

Converting body heat into electricity is a promising strategy for supplying power to wearable electronics. To avoid the limitations of traditional solid-state thermoelectric materials, such as frangibility and complex fabrication processes, we fabricated two types of thermogalvanic gel electrolytes with positive and negative thermo-electrochemical Seebeck coefficients, respectively, which correspond to the n-type and p-type elements of a conventional thermoelectric generator. Such gel electrolytes exhibit not only moderate thermoelectric performance but also good mechanical properties. Based on these electrolytes, a flexible and wearable thermocell was designed with an output voltage approaching 1u2005V by utilizing body heat. This work may offer a new train of thought for the development of self-powered wearable systems by harvesting low-grade body heat.

Induced Potential in Porous Carbon Films through Water Vapor Absorption

Sustainable electrical potential of tens of millivolts can be induced by water vapor adsorption on a piece of porous carbon film that has two sides with different functional group contents. Integrated experiments, and Monte Carlo and abu2005initio molecular dynamics simulations reveal that the induced potential originates from the nonhomogeneous distribution of functional groups along the film, especially carboxy groups. Sufficient adsorbed water molecules in porous carbon facilitate the release of protons from the carboxy groups, resulting in a potential drop across the carbon film because of the concentration difference of the released free protons on the two sides. The potential utilization of such a phenomenon is also demonstrated by a self-powered humidity sensor.

Self-Powered Multimodal Temperature and Force Sensor Based-On a Liquid Droplet

Herein we report a self-powered multimodal temperature and force sensor based on the reverse electrowetting effect and the thermogalvanic effect in a liquid droplet. The deformation of the droplet and the temperature difference across the droplet can induce an alternating pulse voltage and a direct voltage, respectively, which is easy to separate/analyze and can be utilized to sense the external force and temperature simultaneously. In addition, an integral display system that can derive information from external temperature/force concurrently is constructed. Combined with advantages of excellent sensing properties and a simple structure, the droplet sensor has promising applications in a wide range of intelligent electronics.

Thermodynamics of Ion Separation by Electrosorption

We present a simple, top-down approach for the calculation of minimum energy consumption of electrosorptive ion separation using variational form of the (Gibbs) free energy. We focus and expand on the case of electrostatic capacitive deionization (CDI). The theoretical framework is independent of details of the double-layer charge distribution and is applicable to any thermodynamically consistent model, such as the Gouy-Chapman-Stern and modified Donnan models. We demonstrate that, under certain assumptions, the minimum required electric work energy is indeed equivalent to the free energy of separation. Using the theory, we define the thermodynamic efficiency of CDI. We show that the thermodynamic efficiency of current experimental CDI systems is currently very low, around 1% for most existing systems. We applied this knowledge and constructed and operated a CDI cell to show that judicious selection of the materials, geometry, and process parameters can lead to a 9% thermodynamic efficiency and 4.6 kT per removed ion energy cost. This relatively high thermodynamic efficiency is, to our knowledge, by far the highest thermodynamic efficiency ever demonstrated for traditional CDI. We hypothesize that efficiency can be further improved by further reduction of CDI cell series resistances and optimization of operational parameters.

Electrokinetic Supercapacitor for Simultaneous Harvesting and Storage of Mechanical Energy

Energy harvesting and storage are two distinct processes that are generally achieved using two separated parts based on different physical and chemical principles. Here we report a self-charging electrokinetic supercapacitor that directly couples the energy harvesting and storage processes into one device. The device consists of two identical carbon nanotube/titanium electrodes, separated by a piece of anodic aluminum oxide nanochannels membrane. Pressure-driven electrolyte flow through the nanochannels generates streaming potential, which can be used to charge the capacitive electrodes, accomplishing simultaneous energy generation and storage. The device stores electric charge density of 0.4 mC cm-2 after fully charging under pressure of 2.5 bar. This work may offer a train of thought for the development of a new type of energy unit for self-powered systems.