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Dive into the research topics where Karel Škoch is active.

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Featured researches published by Karel Škoch.


Chemistry: A European Journal | 2018

Selective Gold-Catalysed Synthesis of Cyanamides and 1-Substituted 1H-Tetrazol-5-Amines from Isocyanides

Karel Škoch; Ivana Císařová; Petr Štěpnička

The newly discovered gold-catalysed reaction of isocyanides with hydrazoic acid generated in situ from trimethylsilyl azide and methanol (or, alternatively, from NaN3 /AcOH) produces either cyanamides or 1-substituted 1H-tetrazol-5-amines, depending on the amount of available HN3 . The reaction proceeds selectively and in generally high yields of either product, thus providing a particularly convenient access to a wide range of substituted 1H-tetrazol-5-amines that are rather difficult to access otherwise.


Zeitschrift Fur Kristallographie-new Crystal Structures | 2017

The crystal structure of (5-methyl-1,2,4-oxadiazol-3-yl)ferrocene, C13H12FeN2O

Karel Škoch; Ivana Císařová; Petr Štěpnička

Abstract C13H12FeN2O, monoclinic, P21/n (no. 14), a = 5.9035(2) Å, b = 20.7111(6) Å, c = 9.1403(3) Å, β = 90.0762(16)°, V = 1117.57(6) Å3, Z = 4, Rgt(F) = 0.0282, wRref(F2) = 0.0656, T = 150(2) K.


Organometallics | 2015

Phosphinoferrocene Ureas: Synthesis, Structural Characterization, and Catalytic Use in Palladium-Catalyzed Cyanation of Aryl Bromides

Karel Škoch; Ivana Císařová; Petr Štěpnička


Inorganic Chemistry | 2014

1'-(Diphenylphosphino)-1-cyanoferrocene: a simple ligand with complicated coordination behavior toward copper(I).

Karel Škoch; Ivana Císařová; Petr Štěpnička


Organometallics | 2013

Synthesis, Molecular Structure, and Catalytic Evaluation of Centrostereogenic Ferrocenophane Phosphines

Petr Štěpnička; Karel Škoch; Ivana Císařová


Chemistry: A European Journal | 2015

Synthesis and Catalytic Use of Gold(I) Complexes Containing a Hemilabile Phosphanylferrocene Nitrile Donor

Karel Škoch; Ivana Císařová; Petr Štěpnička


Organometallics | 2016

Synthesis of a Polar Phosphinoferrocene Amidosulfonate Ligand and Its Application in Pd-Catalyzed Cross-Coupling Reactions of Aromatic Boronic Acids and Acyl Chlorides in an Aqueous Medium

Karel Škoch; Ivana Císařová; Petr Štěpnička


Dalton Transactions | 2016

Silver(I) complexes with 1′-(diphenylphosphino)-1-cyanoferrocene: the art of improvisation in coordination

Karel Škoch; Filip Uhlík; Ivana Císařová; Petr Štěpnička


Organometallics | 2017

Phosphine–Borane Frustrated Lewis Pairs Derived from a 1,1′-Disubstituted Ferrocene Scaffold: Synthesis and Hydrogenation Catalysis

Zhongbao Jian; Sergei Krupski; Karel Škoch; Gerald Kehr; Constantin G. Daniliuc; Ivana Císařová; Petr Štěpnička; Gerhard Erker


Dalton Transactions | 2017

Synthesis and characterization of 1′-(diphenylphosphino)-1-isocyanoferrocene, an organometallic ligand combining two different soft donor moieties, and its Group 11 metal complexes

Karel Škoch; Ivana Císařová; Jiří Schulz; Ulrich Siemeling; Petr Štěpnička

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Petr Štěpnička

Charles University in Prague

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Ivana Císařová

Charles University in Prague

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Filip Uhlík

Charles University in Prague

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Filip Horký

Charles University in Prague

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Ivana Cisarova

Charles University in Prague

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Jiří Schulz

Charles University in Prague

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Petr Stepnicka

Charles University in Prague

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David Lebœuf

Université Paris-Saclay

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