Karen P. Magee-Sauer

Remote infrared observations of parent volatiles in comets: A window on the early solar system

Abstract Organic volatiles and water in Oort Cloud comets were investigated at infrared wavelengths. The detected species include H 2 O, CO, CH 3 OH, CH 4 , C 2 H 2 , C 2 H 6 , OCS, HCN, NH 3 , and H 2 CO. Several daughter fragments (CN, OH, NH 2 , etc.) are also measured, and OH prompt emission provides a proxy for water. Long-slit spectra are taken at high spectral dispersion and high spatial resolution, eliminating several sources of systematic error. The resulting parent volatile production rates are highly robust, permitting a sensitive search for compositional diversity among comets. Here, seven OC comets are compared. Six (including Halley) exhibit similar compositions (excepting CO and CH 4 ). Their low formation temperatures (∼30 K) suggest this group probably formed beyond 30 AU from the young sun. However, C/1999 S4 is severely depleted in hypervolatiles and also in methanol, and it likely formed near 5–10 AU. C/2001 A2 is discussed briefly to illustrate future prospects.

A Survey of Organic Volatile Species in Comet C/1999 H1 (Lee) Using NIRSPEC at the Keck Observatory

The organic volatile composition of the long-period comet C/1999 H1 (Lee) was investigated using the —rst of a new generation of cross-dispersed cryogenic infrared spectrometers (NIRSPEC, at the Keck Observatory atop Mauna Kea, HI). On 1999 August 19¨21 the organics spectral region (2.9¨3.7 km) was completely sampled at both moderate and high dispersion, along with the CO fundamental region (near 4.67 km), revealing emission from water, carbon monoxide, methanol, methane, ethane, acetylene, and hydrogen cyanide. Many new multiplets from OH in the 1¨0 band were seen in prompt emission, and numerous new spectral lines were detected. Several spectral extracts are shown, and global production rates are presented for seven parent volatiles. Carbon monoxide is strongly depleted in comet Lee relative to comets Hyakutake and Hale-Bopp, demonstrating that chemical diversity occurred in the giant

Water Production Rates, Rotational Temperatures, and Spin Temperatures in Comets C/1999 H1 (Lee), C/1999 S4, and C/2001 A2

Water hot-band lines were detected in comets C/1999 H1 (Lee), C/1999 S4 (LINEAR), and C/2001 A2 (LINEAR) in the 2.9 � m spectral region using high-dispersion (k=� k � 2 ; 10 4 ) infrared spectroscopy with NIRSPEC at the W. M. Keck Observatory. The density of H2O emissions in this spectral region, the spectral coverage and resolution of NIRSPEC, and fluorescence models developed for these hot bands enabled the determination of H2O production rates, rotational temperatures, and ortho-to-para ratios (OPRs) in these comets. Previous studies revealed clear diversity in the volatile organic chemistries of these comets, suggesting that they may have formed in different regions of the early solar nebula. The nuclear spin temperature of H2O as derived from its OPR is another possible indicator of cometary formation temperature and region. Nuclear spin temperatures for H2O were derived on one date in comet S4 and two dates in Lee and A2. Derived spin temperatures for H2O in these comets are � 30, 30 þ15 � 6 ,a nd 23 þ4 � 3 K for S4, Lee, and A2, respectively. Measurements are consistent with a possible link between nuclear spin temperatures and volatile abundances, but studies of more comets and continued improvements in water hot-band fluorescence models are needed to more stringently test this. Subject headingg comets: general — comets: individual (C/1999 S4, C/2001 A2, Lee (C/1999 H1)) — infrared: solar system — techniques: spectroscopic

Identification of two sources of carbon monoxide in comet Hale-Bopp

The composition of ices in comets may reflect that of the molecular cloud in which the Sun formed, or it may show evidence of chemical processing in the pre-planetary accretion disk around the proto-Sun. As carbon monoxide (CO) is ubiquitous in molecular clouds,, its abundance with respect to water could help to determine the degree to which pre-cometary material was processed, although variations in CO abundance may also be influenced by the distance from the Sun at which comets formed. Observations have not hitherto provided an unambiguous measure of CO in the cometary ice (native CO). Evidence for an extended source of CO associated with comet Halley was provided by the Giotto spacecraft, but alternative interpretations exist. Here we report observations of comet Hale–Bopp which show that about half of the CO in the comet comes directly from ice stored in the nucleus. The abundance of this CO with respect to water (12 per cent) is smaller than in quiescent regions of molecular clouds, but is consistent with that measured in proto-stellar envelopes, suggesting that the ices underwent some processing before their inclusion into Hale–Bopp. The remaining CO arises in the coma, probably through thermal destruction of more complex molecules.

Detection of Formaldehyde Emission in Comet C/2002 T7 (LINEAR) at Infrared Wavelengths: Line-by-Line Validation of Modeled Fluorescent Intensities

Formaldehyde (H2CO) was observed in comet C/2002 T7 (LINEAR) with spectral resolving power k/� k � 2.5 ; 10 4 using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA Infrared Telescope Facility, on UT 2004 May 5, 7, and 9. The observations, which sampled emission in the � 1 and � 5 rovibrational bands between 3.53 and 3.62 � m, represent the first spectrally resolved detection, at infrared wavelengths, of monomeric H2CO spanning a range of rotational energies. A comparison of measured line intensities with an existing fluorescence model permitted extraction of rotational temperatures and production rates. Two complementary approaches were used: (1)acorrelationanalysisthatprovidedadirectglobalcomparisonoftheobservedcometaryemissionswiththemodel and (2) an excitation analysis that provided a robust line-by-line comparison. Our results validate the fluorescence model. The overall correlation coefficient was near or above 0.9 in our two principal grating settings. The excitation analysis provided accurate measures of rotational excitation (rotational temperature) on all three dates, with retrieved values of Trot clustering near 100 K. Through simultaneous measurement of OH prompt emission, which we use as a proxy for H2O, we obtained native production rates and mixing ratios for H2CO. The native production of H2CO varied from day to day, but its abundance relative to H2O, Xnative, remained approximately constant within the errors, which may suggest an overall homogeneous composition of the nucleus. We measured a mean mixing ratio Xnative = (0.79 � 0.09) ; 10 � 2 for the three dates. Subject headingg astrochemistry — comets: individual (C/2002 T7 (LINEAR)) — infrared: solar system Online material: color figures

Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley 2

We report measurements of eight primary volatiles (H_(2)O, HCN, CH_4, C_(2)H_6, CH_(3)OH, C_(2)H_2, H_(2)CO, and NH_3) and two product species (OH and NH_2) in comet 103P/Hartley 2 using high-dispersion infrared spectroscopy. We quantified the long- and short-term behavior of volatile release over a three-month interval that encompassed the comets close approach to Earth, its perihelion passage, and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission. We present production rates for individual species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates. The production rates for water, ethane, HCN, and methanol vary in a manner consistent with independent measures of nucleus rotation, but mixing ratios for HCN, C_(2)H_6, and CH_(3)OH are independent of rotational phase. Our results demonstrate that the ensemble average composition of gas released from the nucleus is well defined and relatively constant over the three-month interval (September 18 through December 17). If individual vents vary in composition, enough diverse vents must be active simultaneously to approximate (in sum) the bulk composition of the nucleus. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps (and from the nucleus), and provide insights into the driver for the cyanogen (CN) polar jet. The spatial distributions of C_(2)H_6 and HCN along the near-polar jet (UT October 19.5) and nearly orthogonal to it (UT October 22.5) are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water was 2.85 ± 0.20; the lower bound (2.65) defines T_spin > 32 K. These values are consistent with results returned from the Infrared Space Observatory in 1997.

Detection of CO and Ethane in Comet 21P/Giacobini-Zinner: Evidence for Variable Chemistry in the Outer Solar Nebula

Ethane and carbon monoxide were detected in a short-period comet of probable Kuiper Belt origin. Ethane is substantially less abundant compared with Hyakutake and Hale-Bopp, two comets from the giant-planet region of the solar nebula, suggesting a heliocentric gradient in ethane in precometary ices. It is argued that processing by X-rays from the young Sun may be responsible.

THE VOLATILE COMPOSITION OF THE SPLIT ECLIPTIC COMET 73P/SCHWASSMANN-WACHMANN 3: A COMPARISON OF FRAGMENTS C AND B

The composition of fragments C and B of the Jupiter-family comet 73P/Schwassmann-Wachmann 3 (SW3) was investigated in early April of 2006 at IR wavelengths using high-dispersion echelle spectroscopy. Both fragments were depleted in ethane, and C was depleted in most forms of volatile carbon. In particular, fragment C shows a severe depletion of CH3OH but a “normal” abundance of HCN (which has a similar volatility). Thermal processing is a possible explanation, but since fragment B is perhaps sublimating fresher material because of the frequent outbursts and fragmentation, the observed depletions might have cosmogonic implications. The chemistry of the volatile ices in SW3, like in the Oort Cloud comet C/1999 S4 (LINEAR), may be associated with sublimation of icy mantles from precometary grains followed by subsequent gas-phase chemistry and recondensation. Subject headings: comets: individual (73P/SW3) — Kuiper Belt — solar system: formation

Depleted Carbon Monoxide in Fragment C of the Jupiter-Family Comet 73P/Schwassmann-Wachmann 3

Carbon monoxide emission was targeted in fragment C of the recently split Jupiter-family comet 73P/Schwassmann-Wachmann 3 during its 2006 apparition, using the Cryogenic Echelle Spectrograph (CSHELL) at the NASA IRTF on Mauna Kea, Hawaii. Simultaneous sounding with H2O near 4.65 mm revealed highly depleted CO, consistent with a mixing ratio of 0.5% 0.13%. Along with depleted CH3OH but nearly normal HCN, this may indicate that this comet formed in the inner giant planets’ region or, alternatively, that it formed relatively late, after significant clearing of the protosolar nebula. Subject headings: comets: general — comets: individual (73P/Schwassmann-Wachmann 3) — molecular processes — solar system: formation Online material: color figure

Fabry-Perot observations of Comet Halley H2O+

Abstract High-resolution spectra of Comet Halley H2O+ emissions, primarily the 6158.64, 6158.85 A spin doublet, were obtained in 1985 and 1986 using the Wisconsin 150-mm Fabry-Perot scanning spectrometer at the McMath west auxiliary solar telescope on Kitt Peak. On each night of observations, spectra were obtained at several distances in the range of 0 to 2 × 106 km from the comet head along the anti-Sunward direction. The outflow velocities of the cometary plasma were determined from the Doppler shifts of the emissions. The results usually but not always were consistent with constant acceleration of the plasma along the anti-Sunward direction, but the acceleration varied from night to night over a range of about 30–300 cm sec−2. Unusual kinematics of the plasma on the nights of 14–15 December 1985 and 10 January 1986 could be related to tail disconnection activity reported by other observers.