Karl B. Föllmi

Cyclic phosphate-rich successions in the upper Cretaceous of Colombia

Abstract Upper Cretaceous neritic to hemipelagic successions from the eastern Colombian Cordillera display frequent and rhythmic intercalations of phosphate-rich sediment. Their accumulation is attributed to a back-arc setting between the Andean arctrench system and the Guayana cratonic shield. In three examined sections near Tausa, Tunja, and Iza (all north of Bogota), respectively, the phosphate-rich sediments occur in 1–15 m thick coarsening-upward series ideally consisting — from the base to the top — of porcelanite, organic-rich claystone, siltstone, sandstone, and a condensed and thoroughly burrowed top bed. Phosphatic particles appear either in thin gravity-flow deposits or in pristine, in-situ occurrences near the base of these successions, intercalated in fine-grained biosiliceous or clay-rich sediment, or in the condensed top bed. The major portion of this coarsening-upward series (porcelanite to sandstone) is considered a shallowing-upward succession and the thin condensed phosphatic top bed a deepening-upward succession. These rhythmic successions are interpreted as parasequences resulting from fourth-order relative sea-level changes. Based upon biostratigraphic age estimates, the time span of formation of these parasequences range between approximately 100,000 and 200,00 yr. The allochthonous phosphate intercalations near the base of the parasequences are derived from condensed phosphatic top beds, which may have been exposed at the sediment-water interface in proximal directions. This suggests that the parasequence boundaries, i.e., marine flooding surfaces, are diachronous and become younger in onshore directions. using the vertical stacking patterns of these parasequences, we distinguish between transgressive and highstand-systems tracts (TST and HST). TSTs are characterized by the dominance of phosphatic sediment, laminated and organic-rich claystone, and laminated porcelanite. This suite of sediments documents high nutrient fluxes and the presence of an oxygen-minimum zone, both probably induced by coastal upwelling. HSTs include laminated to well-bioturbated siliciclastic successions, which may reflect a weakening or basinward shift of upwelling cells and higher levles of bottom-water oxygenation. The dominance of siliciclastics in HSTs is indicative of high detrital fluxes, which outpaced sediment-accomodation rates on the shelf. Upper Campanian ammonoids have been found in three levels of the Lower Plaeners Member of the Guadalupe Formation in the section near Tausa — Nostoceras (Nostoceras) liratum sp.n., Exiteloceras jenneyi (Whitfield, 1887), and Libycoceras sp. E. jenneyi is an important zonal marker in the U.S. Western Interior that is also known from the basal Mount Laurel Sand of Delaware, USA. Its occurrence at Tausa is the first record outside the USA and provides an important datum for intercontinental correlation. The type of Libycoceras sp. encountered in Tausa is also known from the upper Campanian of Peru and Angola. Together with the presence of Andalusiella polymorphia (Malloy, 1972), a dinoflagellate cyst, an age range is given for the formation of the Lower Plaeners Member at Tausa (late Campanian to early Maastrichtian).

Palaeoenvironmental significance of Toarcian black shales and event deposits from southern Beaujolais, France

New sedimentological, biostratigraphical and geochemical data recording the Toarcian OceanicAnoxicEvent(T-OAE)arereportedfromamarginalmarinesuccessioninsouthernBeaujolais, France. The serpentinum and bifrons ammonite zones record black shales with high (1-10 wt %) total organic carbon contents (TOC) and dysoxia-tolerant benthic fauna typical of the Schistes Carton facies well documented in contemporaneous nearby basins. The base of the serpentinum ammonite zone, however, differs from coeval strata of most adjacent basinal series in that it presents several massive storm beds particularly enriched in juvenile ammonites and the dysoxia-tolerant, miniaturized gastropod Coelodiscus. This storm-dominated interval records a marked negative 5 ‰ carbonate and organic carbon isotope excursion being time-equivalent with that recording storm- and mass flow-deposits in sections of the Lusitanian Basin, Portugal, pointing to the existence of a major tempestite/turbidite event over tropical areas during the T-OAE. Although several explanations remain possible at present, we favour climatically induced changes in platform morphology and storm activity as the main drivers of these sedimentological features. In addition, we show that recent weathering, most probably due to infiltration of O2-rich meteoric water, resulted in the preferential removal of 12 C-enriched organic carbon, dramatic TOC loss and total destruction of the lamination of the black shale sequence over most of the studied exposure. These latter observations imply that extreme caution should be applied when interpreting the palaeoenvironmental significance of sediments lacking TOC enrichment and lamination from outcrops with limited surface exposures.

Major environmental change and bonebed genesis prior to the Triassic–Jurassic mass extinction

We present new geochemical and sedimentological data from marginal marine strata of Penarth Bay, south Wales (UK) to elucidate the origin of widespread but enigmatic concentrations of vertebrate hard parts (bonebeds) in marine successions of Rhaetian age (Late Triassic). Sedimentological evidence shows that the phosphatic constituents of the bonebeds were subjected to intense phosphatization in shallow current-dominated settings and subsequently reworked and transported basinward by storms. Interbedded organic-rich strata deposited under quiescent and poorly oxygenated conditions record enhanced phosphorus regeneration from sedimentary organic matter into the water column and probably provided the main source of phosphate required for heavy bonebed clast phosphatization. The stratigraphically limited interval showing evidence for oxygen depletion and accelerated P-cycling coincides with a negative 4‰ organic carbon isotope excursion, which possibly reflects supra-regional changes in carbon cycling and clearly predates the ‘initial isotope excursion’ characterizing many Triassic–Jurassic boundary strata. Our data indicate that Rhaetian bonebeds are the lithological signature of profound, climatically driven changes in carbon cycling and redox conditions and support the idea of a multi-pulsed environmental crisis at the end of the Triassic, possibly linked to successive episodes of igneous activity in the Central Atlantic Magmatic Province. Supplementary material: Sample positions, data table and a detailed stratigraphic log from the upper Triassic of Penarth Bay, south Wales, UK are available at http://www.geolsoc.org.uk/SUP18510.

Mercury enrichment indicates volcanic triggering of Valanginian environmental change

The Valanginian stage (Early Cretaceous) includes an episode of significant environmental changes, which are well defined by a positive δ13C excursion. This globally recorded excursion indicates important perturbations in the carbon cycle, which has tentatively been associated with a pulse in volcanic activity and the formation of the Paraná-Etendeka large igneous province (LIP). Uncertainties in existing age models preclude, however, its positive identification as a trigger of Valanginian environmental changes. Here we report that in Valanginian sediments recovered from a drill core in Wąwał (Polish Basin, Poland), and from outcrops in the Breggia Gorge (Lombardian Basin, southern Switzerland), and Orpierre and Angles (Vocontian Basin, SE France), intervals at or near the onset of the positive δ13C excursion are significantly enriched in mercury (Hg). The persistence of the Hg anomaly in Hg/TOC, Hg/phyllosilicate, and Hg/Fe ratios shows that organic-matter scavenging and/or adsorbtion onto clay minerals or hydrous iron oxides only played a limited role. Volcanic outgassing was most probably the primary source of the Hg enrichments, which demonstrate that an important magmatic pulse triggered the Valanginian environmental perturbations.

Mercury enrichments in lower Aptian sediments support the link between Ontong Java large igneous province activity and oceanic anoxic episode 1a

The early Aptian recorded one of the most significant episodes of environmental changenduring the Mesozoic—the Selli oceanic anoxic episode (OAE 1a). It has often been suggestednthat magmatic activity related to the emplacement of the Greater Ontong Java large igneousnprovince (LIP) triggered OAE 1a. A major challenge, however, resides in the establishmentnof precise temporal relationships between the environmental perturbations associated withnOAE 1a and the phases of volcanic activity. In this study, we evaluate the potential of mercuryn(Hg) as a proxy of volcanic activity and investigate lower Aptian sediments with differentntotal organic carbon (TOC) contents, which are exposed at Roter Sattel (Brianconnais, SwissnAlps), Glaise (Vocontian Basin, southeast France), and La Bedoule (South Provencal Basin,nsoutheast France). The intervals equivalent to OAE 1a are marked by significant increasesnin Hg contents, which are only partially dependent on TOC contents. This is shown by thenHg anomalies in the TOC-poor sediments of La Bedoule, the only moderate correlation ofnHg and TOC contents in the TOC-enriched sediments of Roter Sattel (R 2 = 0.48), and thenpersistence of the anomaly in Hg/TOC ratios in all sediments except for the TOC-enrichednones. These results suggest that the Hg anomaly not only is related to primary productivity,nredox conditions, and organic-matter preservation, but has deeper roots. Volcanic outgassingnrelated to Greater Ontong Java LIP activity is taken here as the main source of the Hg enrichmentnrecorded in the western Tethyan sediments. Our Hg data indicate that magmatic pulsesnat the onset and during the OAE 1a triggered the early Aptian environmental perturbations.

Glendonites track methane seepage in Mesozoic polar seas

During the Phanerozoic, Earth has experienced a number of transient global warming events associated with major carbon cycle perturbations. Paradoxically, many of these extreme greenhouse episodes are preceded or followed by cold climate, perhaps even glacial conditions, as inferred from the occurrence of glendonites in high latitudes. Glendonites are pseudomorphs of ikaite (CaCO3 center dot 6H(2)O), a hydrated carbonate mineral increasingly stable at low temperatures. Here, we show that methane seepage and oxidation provide an overriding control on Mesozoic glendonite formation (i. e., ikaite fossilization). Geochemical and petrological analyses of 33 Early Jurassic to Early Cretaceous glendonites from five sections in Siberia (Russia) reveal that most of their infilling carbonate phases are reminiscent of methane- derived authigenic carbonates. Bulk glendonites and surrounding sediments exhibit exceptionally high and low carbon isotope values (+20% to -45% VPDB [Vienna Peedee belemnite]), typical for carbon sources linked to methane generation and oxidation. Gas inclusion data confirm the presence of methane and longer-chain hydrocarbon gases, suggesting a thermogenic source for the methane. Glendonitebearing layers can be traced for hundreds of kilometers, suggesting widespread trapping of methane in the sub-seafloor during the Jurassic. As such, glendonites constitute an unexplored archive for detecting past episodes of methane release and oxidation in polar settings.

The Close-Up Imager Onboard the ESA ExoMars Rover: Objectives, Description, Operations, and Science Validation Activities

Abstract The Close-Up Imager (CLUPI) onboard the ESA ExoMars Rover is a powerful high-resolution color camera specifically designed for close-up observations. Its accommodation on the movable drill allows multiple positioning. The science objectives of the instrument are geological characterization of rocks in terms of texture, structure, and color and the search for potential morphological biosignatures. We present the CLUPI science objectives, performance, and technical description, followed by a description of the instruments planned operations strategy during the mission on Mars. CLUPI will contribute to the rover mission by surveying the geological environment, acquiring close-up images of outcrops, observing the drilling area, inspecting the top portion of the drill borehole (and deposited fines), monitoring drilling operations, and imaging samples collected by the drill. A status of the current development and planned science validation activities is also given. Key Words: Mars—Biosignatures—Plane...The Close-Up Imager (CLUPI) onboard the ESA ExoMars Rover is a powerful high-resolution color camera specifically designed for close-up observations. Its accommodation on the movable drill allows multiple positioning. The science objectives of the instrument are geological characterization of rocks in terms of texture, structure, and color and the search for potential morphological biosignatures. We present the CLUPI science objectives, performance, and technical description, followed by a description of the instruments planned operations strategy during the mission on Mars. CLUPI will contribute to the rover mission by surveying the geological environment, acquiring close-up images of outcrops, observing the drilling area, inspecting the top portion of the drill borehole (and deposited fines), monitoring drilling operations, and imaging samples collected by the drill. A status of the current development and planned science validation activities is also given. Key Words: Mars-Biosignatures-Planetary Instrumentation. Astrobiology 17, 595-611.

Formation and age of sphalerite mineralization in carbonate rocks of Bajocian age in the Swiss Jura Mountains: evidence of Mesozoic hydrothermal activity

AbstractnA combination of petrographic and geochemical techniques was applied to better constrain the origin and evolution of the fluid systems responsible for the formation of disseminated, Cd-rich (up to 0.6 wt%), sphalerite (ZnS) mineralization in the northeastern part of the Jura Mountains, Switzerland. The Rb–Sr ages of sphalerite samples indicate that a main phase of sphalerite formation occurred near the boundary between the late Middle and early Late Jurassic, at around 162xa0Ma. The negative δ34S values (−22.3 to −5.3xa0‰) suggest that biogenic sulfide sulfur was involved in ZnS precipitation. The strontium isotope composition is more radiogenic than that of contemporaneous seawater, reflecting the interaction of mineralizing fluids with silicate rocks. Lead isotope signatures are very uniform (206Pb/204Pbxa0=xa018.63–18.67, 207Pb/204Pbxa0=xa015.63–15.64, 208Pb/204Pbxa0=xa038.51–38.63), indicating an isotopically well-homogenized fluid system. The basement rocks underlying the Jurassic strata are considered to be the main source of metals for the sphalerite mineralization. The migration of deep-sourced hydrothermal saline metal-bearing fluids into the Bajocian host carbonates containing sedimentary reduced sulfur resulted in the precipitation of sulfides. The period of sphalerite formation near the Middle–Late Jurassic boundary is characterized by enhanced tectonic and hydrothermal activity in Europe, related to the opening of the Central Atlantic and tectonic/thermal subsidence during spreading of the Alpine Tethys. Our study provides evidence that the Bajocian carbonate rocks in the Jura Mountains area were affected by the circulation of deep-sourced metal-bearing hydrothermal fluids in response to these continent-wide tectonothermal events. The presence of sphalerite mineralization and associated geochemical anomalies in Zn and Cd contents in carbonate rocks may also be used to trace basement features.

Aptian to Cenomanian Deeper-Water Hiatal Stromatolites from the Northern Tethyan Margin

A suite of deeper-water hiatal (DWH) stromatolites has been identified in the phosphatic and glauconitic sediments of Aptian to Cenomanian age in the alpine Helvetic thrust-and-fold belt, which represents the former northern Tethyan margin. The most important occurrences date from the latest Early to Late Aptian, the late Early to early middle Albian, and the Early Cenomanian. They are invariably associated with condensed phosphatic beds and occur preferentially on top of hardgrounds or on reworked pebbles and fossils. The zone of optimal stromatolite growth and preservation coincides with the zone of maximal sedimentary condensation, in the deeper parts of phosphogenic areas. The DWH stromatolites show variable morphologies, ranging from isolated laminae (“films”) to internally laminated columns and crusts. They reach thicknesses of maximal 10 cm and are either preserved in phosphate or micrite. In the latter case, they may show peripheral impregnations of phosphate or iron oxyhydroxides. The quasi-complete lack of macroscopic sessile organisms suggests that the DWH stromatolites grew close to the upper boundary of an oxygen-minimum zone. Electron-scanning microscopic images show that the Early Cenomanian examples preserved in micrite consist of filamentous structures, which form spaghetti-like assemblages. They are interpreted as the remains of poikiloaerobic, heterotrophic microbes.

Precisely dating the Frasnian–Famennian boundary: implications for the cause of the Late Devonian mass extinction

The Frasnian–Famennian boundary records one of the most catastrophic mass extinctions of the Phanerozoic Eon. Several possible causes for this extinction have been suggested, including extra-terrestrial impacts and large-scale volcanism. However, linking the extinction with these potential causes is hindered by the lack of precise dating of either the extinction or volcanic/impact events. In this study, a bentonite layer in uppermost-Frasnian sediments from Steinbruch Schmidt (Germany) is re-analysed using CA-ID-TIMS U-Pb zircon geochronology in order to constrain the date of the Frasnian–Famennian extinction. A new age of 372.36u2009±u20090.053u2009Ma is determined for this bentonite, confirming a date no older than 372.4u2009Ma for the Frasnian–Famennian boundary, which can be further constrained to 371.93–371.78u2009Ma using a pre-existing Late Devonian age model. This age is consistent with previous dates, but is significantly more precise. When compared with published ages of the Siljan impact crater and basalts produced by large-scale volcanism, there is no apparent correlation between the extinction and either phenomenon, not clearly supporting them as a direct cause for the Frasnian–Famennian event. This result highlights an urgent need for further Late Devonian geochronological and chemostratigraphic work to better understand the cause(s) of this extinction.