Karl Peterson

Long-Term Effects of Magnesium Chloride and Other Concentrated Salt Solutions on Pavement and Structural Portland Cement Concrete: Phase I Results

Many state highway agencies use various chemicals to deice or anti-ice pavement and bridge surfaces. Most often these are aqueous solutions of various chlorides (e.g., magnesium chloride, sodium chloride, and calcium chloride) or other chemicals such as calcium magnesium acetate, urea, or others. Possible detrimental effects to concrete caused by these chemicals have not been fully examined and documented. Mortar specimens of three different water-to-cement ratios (0.4, 0.5, and 0.6) were immersed in concentrated solutions of various chemical deicers and held above freezing at a constant temperature of 40°F up to 84 days. Considerable expansion and cracking were noted in specimens immersed in the MgCl2 and CaCl2 solutions. Petrographic analysis and quantitative microanalysis were used to positively identify the presence of Mg(OH)2 (brucite) formation in the outer layers of the specimens. Furthermore, the results presented clear evidence of calcium oxychloride formation in the specimens analyzed. Further r...

CHEMICAL APPROACH TO FORMATION OF CALCITE PRECIPITATE FROM RECYCLED CONCRETE AGGREGATE BASE LAYERS

The use of recycled portland cement concrete aggregate in pavement base layers has been associated with the reduction of filter fabric permittivity and the accumulation of calcite precipitate and other materials in pavement subdrainage systems. A mechanism of portlandite dissolution within base-layer pore waters, followed by exposure to atmospheric carbon dioxide via subdrainage systems, and subsequent calcite precipitation is explored using chemical thermodynamic techniques. Ion activities and pH levels are estimated for the equilibrium states of rainwater entering the pavement, base-layer pore water isolated from the atmosphere, and subdrainage water exposed to the atmosphere. Results derived agree with field and laboratory observations of pH levels.

The Practical Application of a Flatbed Scanner for Air-Void Characterization of Hardened Concrete

Over the past 30 years, with the advent of computers and digital imaging, many automated systems have been introduced for the purpose of air-void characterization. The majority of the systems employs a contrast-enhancement procedure where a polished cross-section of concrete is darkened with paint, and white powder is forced into the depressions left by air-voids. The system described here follows the same approach and uses a flatbed scanner to collect a single digital image of the entire sample. For all of the systems based on contrast enhancement, the first step is to select a threshold level. Image pixels brighter than the threshold level represent air and image pixels darker than the threshold level represent non-air (i.e., paste or aggregate). Further digital processing steps may be employed but the initial selection of threshold level exerts a strong influence on whether a pixel in the final data set is classified as air or non-air. A systematic approach for threshold determination has been proposed based on an iterative procedure that compares automatically determined air-void parameters to manually determined air-void parameters from a set of training specimens. The calibration procedure finds a single optimum threshold level for the automated system that is to be used for all subsequent analyses. The approach was tested on a population of 88 specimens with manually determined air-void parameters, with the goal of determining an appropriate value for the number of training specimens.

Effect of Sample Preparation on Chemical Composition and Morphology of Alkali-Silica Reaction Products

The chemical composition and morphology of alkali–silica reaction (ASR) products is of great importance in studying the reaction mechanism and assessing the effectiveness of mitigation techniques. Epoxy-impregnated, polished thin sections were prepared from an in-service concrete pavement to examine ASR products that originate from chert particles in the fine aggregate. Both hydrous and anhydrous thin-section preparation techniques were used to investigate the influence of sample preparation on the results. Two distinct morphologies of ASR products were observed in the voids adjacent to the chert particles: a bladed crystalline type and a glassy amorphous type. The chemical compositions of the reaction products were determined with a scanning electron microscope via quantitative X-ray energy dispersive spectrometry. Both the chemical composition and morphology were influenced by sample preparation, with hydrous preparation resulting in leaching and degradation. It is recommended that, when conducting studies to assess the ASR mechanism and the effectiveness of mitigation techniques, anhydrous sample preparation be used.

Measurement of entrained air-void parameters in Portland cement concrete using micro X-ray computed tomography

Abstract The entrained air-void system in concrete is closely related to freeze-thaw durability in concrete pavements or other structures. For either research or forensic purposes, reliable and economical methods for the quantification of entrained air are desirable. This study explores the potential of using micro X-ray computed tomography (μCT) to measure entrained air-void parameters in concrete. A series of small cores (6 mm dia.) were retrieved from larger (100-mm-dia.) cores from two different concrete pavements, representing both adequate and marginal air contents, and scanned at a resolution of 7.5 μm/pixel. A systematic procedure based on image processing is proposed to address practical difficulties such as void/solid thresholding, air-type discernment (entrained air-voids vs. voids in aggregate) and the separation of bubbles within close proximity to each other (e.g. clustered air-voids). Air content and specific surface were measured directly from the three-dimensional (3D) reconstructed X-ray images, while values for paste content were derived from manual point counts performed on two-dimensional (2D) slices obtained from the 3D images. The derived values for air content, specific surface and paste content were used to calculate Powers’ spacing factor. To assess the issue of local fluctuations of material constituents and the limited dimensions of the small cores, uncertainty associated with the sample volume of concrete under measurement was also estimated. Based on the results in this study with regard to the work involved in sample preparation, data analysis and uncertainty bounds, μCT has been found to be a viable option for measurement of spacing factor and specific surface, but due to limitations imposed by the dimensions of the sample size (6-mm-dia. cores), the method is not appropriate for bulk air content determination.

Investigation of Portland Cement Concrete Exposed to Automated Deicing Solutions on Colorado’s Bridge Decks

The Colorado Department of Transportation (DOT) has identified potential performance problems in some portland cement concrete (PCC) bridge decks and approach slabs in the form of pattern surface cracking, spalling, and joint and crack deterioration; these problems are suspected to be materials-related distress (MRD). External factors such as deicing and anti-icing chemicals can initiate and increase the rate and magnitude of deterioration caused by MRD and thereby shorten the life of the structure. This study investigated whether highly concentrated deicer solutions that were applied through bridge deck deicing and anti-icing systems that used fixed automated spray technology disproportionately contributed to deterioration of PCC bridge decks and adjacent concrete approach slabs in Colorado and whether mitigation strategies employed by Colorado DOT addressed the problem. The investigation involved visual inspection techniques, materials sampling, and evaluation of sampled concrete by using petrographic methods. In bridge decks studied, the concrete evaluated seemed sufficiently resistant to damage from the intrusion of deicer chemicals. Where full-depth cracking was present, however, obvious signs of the movement of moisture and deicers through the deck were observed. Also, some initial signs of possible chemical attack from deicers were noted, and continued exposure to highly concentrated deicers may have contributed to long-term durability concerns. However, use of polymer-modified asphalt and fabric membranes in conjunction with a hot-mix asphalt overlay seemed effective in preventing the ingress of chlorides into the underlying concrete deck.

EVALUATION OF PREMATURE DETERIORATION OF CONCRETE BRIDGE BARRIERS BY PETROGRAPHIC EXAMINATION

Many of the current-generation concrete bridge barriers used in Michigan have deteriorated at a rate greater than expected. For an assessment of the possible causes of this premature distress with the objective of alleviating future occurrences, sixteen core specimens from eight sites constructed between 1983 and 2001 were evaluated. The evaluation included visual inspection, stereo and petrographic optical microscopy, and scanning electron microscopy. The major observations revealed through this analysis were that poor consolidation, marginal air-void systems, alkali-silica reaction associated with chert and siltstone in the fine aggregate, corrosion of reinforcing steel, and possibly frost susceptibility of fine siltstone aggregates were responsible for the deterioration. These results provide the basis for improving the quality of such barriers in future construction.

Deterioration in Concrete Pavements Constructed with Slag Coarse Aggregate

In Michigan, sections of an Interstate-type pavement are suffering extensive cracking and joint deterioration after 10 years of service, having been constructed in 1992. An adjacent section constructed in 1993 with comparable design features and materials remains in good condition, with little visual sign of distress. A study was conducted to determine, if possible, the cause of the observed distress in the highway built in 1992. In all, cores from nine different projects were evaluated, all of which were made with iron blast-furnace-slag coarse aggregate and natural fine aggregate containing chert constituents. The analyses conducted included stereo and petrographic microscopy and chemical extractions to determine levels of exchangeable and soluble potassium and sodium, as well as sulfates. The findings indicate that, in distressed pavement sections, the chert constituents in the fine aggregate are deleteriously alkali–silica reactive (ASR), whereas these same constituents are not deleterious in the sections rated as fair. Further, the distressed sections all had sulfate levels significantly higher than predicted by the mixture design. It is hypothesized that, in addition to the ASR in the fine aggregate, dissolution of the calcium sulfide dendrites in the slag coarse aggregate is providing excess internal sulfates, resulting in in-filling of the air-void system with ettringite and potentially sulfate attack. The exact nature of the deterioration mechanisms is not fully understood, but it seems clear that some type of interaction exists between the ASR and excess sulfates.

Long-Term Effects of Magnesium Chloride and Other Concentrated Salt Solutions on Pavement and Structural Portland Cement Concrete

Many state highway agencies use various chemicals to deice or anti-ice pavement and bridge surfaces. Most often these are aqueous solutions of various chlorides (e.g., magnesium chloride, sodium chloride, and calcium chloride) or other chemicals such as calcium magnesium acetate, urea, or others. Possible detrimental effects to concrete caused by these chemicals have not been fully examined and documented. Mortar specimens of three different water-to-cement ratios (0.4, 0.5, and 0.6) were immersed in concentrated solutions of various chemical deicers and held above freezing at a constant temperature of 40°F up to 84 days. Considerable expansion and cracking were noted in specimens immersed in the MgCl2 and CaCl2 solutions. Petrographic analysis and quantitative microanalysis were used to positively identify the presence of Mg(OH)2 (brucite) formation in the outer layers of the specimens. Furthermore, the results presented clear evidence of calcium oxychloride formation in the specimens analyzed. Further research is being conducted, including the same immersion test at 40°F on portland cement concrete specimens, to identify whether this distress mechanism is of concern for structures such as roads and bridges when subjected to deicing chemicals containing CaCl2 or MgCl2.

USING EPIFLUORESCENCE OPTICAL MICROSCOPY TO IDENTIFY CAUSES OF CONCRETE DISTRESS: CASE STUDY

Materials-related distress (MRD) has affected many portland cement concrete pavements. Identifying the specific cause of MRD is not always possible, but with the use of appropriate techniques and a diagnostic approach, the cause can be determined in many cases. In a case studied as part of an FHWA project titled Detection, Analysis, and Treatment of Materials-Related Distress in Concrete Pavements, apparent MRDs were identified. In one case study, determination of the effective water-to-cement ratio (w/c) by epifluorescence microscopy was the key to understanding the cause of distress. The effective w/c, which may not be exact for a given concrete on an absolute basis, was used to compare two concrete microstructures on a relative basis. Stereo-optical microscopy, petrographic optical microscopy, and scanning electron microscopy were also used to identify the MRD diagnostic features present in the distressed concrete. As a result of this analysis, evidence of paste freeze–thaw and deicer attack was identified, but the principal cause of the distress probably was a high w/c in the distressed concrete.