Kathrin Friedemann

Colloid-Electrospinning: Fabrication of Multicompartment Nanofibers by the Electrospinning of Organic or/and Inorganic Dispersions and Emulsions

Solution-, melt-, and co-axial electrospinning are well-known methods for producing nano- and microfibers. The electrospinning of colloids (or colloid-electrospinning) is a new field that offers the possibility to elaborate multicompartment nanomaterials. However, the presence of colloids in the electrospinning feed further complicates theoretical predictions in a system that is dependent on chemical, physical, and process parameters. Herein, we give a summary of recent important results and discuss the perspectives of electrospinning of colloids for the synthesis and characterization of multicompartment fibers.

Characterization via two-color STED microscopy of nanostructured materials synthesized by colloid electrospinning.

A model system for multicompartment nanofibers was fabricated by colloid electrospinning. The obtained nanostructured material consisted of fluorescent polymer nanoparticles that were synthesized in a miniemulsion and then embedded in fluorescently labeled polymer nanofibers. Because of the absence of contrast between both polymers, the immobilized nanoparticles cannot be reliably identified in the nanofibers via electron microscopy or other techniques. Here, we describe investigations on the hybrid material with two-color STED microscopy to localize the nanoparticles and to quantify their distribution along nanofibers with particle and fiber radii down to 50 nm.

Facile and Large-Scale Fabrication of Anisometric Particles from Fibers Synthesized by Colloid-Electrospinning

A new top-down approach is proposed to form large amounts of anisometric particles. Multicompartment fibers that present different domains composed of silica nanoparticles and larger polystyrene nanoparticles are fabricated by colloid-electrospinning and are subsequently calcinated and broken. The obtained fibers containing voids are subsequently cut via sonication to yield anisometric particles. It is shown that the majority of the fibers can be broken at the voids.

Breaking Nano-Spaghetti: Bending and Fracture Tests of Nanofibers

Nanofibers composed of silica nanoparticles, used as structural building blocks, and polystyrene nanoparticles introduced as sacrificial material are fabricated by bicolloidal electrospinning. During fiber calcination, sacrificial particles are combusted leaving voids with controlled average sizes. The mechanical properties of the sintered silica fibers with voids are investigated by suspending the nanofiber over a gap and performing three-point bending experiments with atomic force microscopy. We investigate three different cases: fibers without voids and with 60 or 260 nm voids. For each case, we study how the introduction of the voids can be used to control the mechanical stiffness and fracture properties of the fibers. Fibers with no voids break in their majority at a single fracture point (70% of cases), segmenting the fiber into two pieces, while the remaining cases (30%) fracture at multiple points, leaving a gap in the suspended fiber. On the other hand, fibers with 60 nm voids fracture in only 25% of the cases at a single point, breaking predominantly at multiple points (75%). Finally, fibers with 260 nm voids fracture roughly in equal proportions leaving two and multiple pieces (46% vs 54%, respectively). The present study is a prerequisite for processes involving the controlled sectioning of nanofibers to yield anisometric particles.