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Dive into the research topics where Katsuhiko Takenaka is active.

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Featured researches published by Katsuhiko Takenaka.


Polymer | 1987

Protection and polymerization of functional monomers: 8. Anionic living polymerization of 4-[2-(trialkyl)silyloxyethyl]styrene as protected 4-(2-hydroxyethyl)styrene☆

Akira Hirao; Akihiko Yamamoto; Katsuhiko Takenaka; Kazuo Yamaguchi; Seiichi Nakahama

Abstract Anionic polymerizations of 2-(4-vinylphenyl)ethoxy(trialkyl)silanes and 2-(4-vinylphenyl)ethoxy(t-butoxydimethyl)silane were investigated with oligo(α-methylstyryl)dilithium or -dipotassium as initiator in tetrahydrofuran at −78°C. These monomers readily polymerized to form ‘living polymers’. Subsequent deprotection of the silyl groups from the resulting polymers gave poly[2-(4-vinylphenyl)ethanol]s of the desired molecular weights with narrow molecular weight distributions ( M w M n = 1.05–1.21 ). The living polymers of the silyl ethers of 2-(4-vinylphenyl)ethanol can initiate further polymerization of either styrene or α-methylstyrene, yielding new block copolymers containing 2-(vinylphenyl)ethanol blocks.


Macromolecular Chemistry and Physics | 1985

Polymerization of monomers containing functional groups protected by trialkylsilyl groups, 4. Studies on anionic living polymerization of 4-(tert-butyldimethylsilyloxy)styrene†

Akira Hirao; Katsuhiko Takenaka; S. Packirisamy; Kazuo Yamaguchi; Seiichi Nakahama


Die Makromolekulare Chemie, Rapid Communications | 1982

Polymerization of monomers containing functional groups protected by trialkylsilyl groups, 1. Synthesis of poly(4-vinylphenol) by means of anionic living polymerization

Akira Hirai; Kazuo Yamaguchi; Katsuhiko Takenaka; Ken Suzuki; Seiichi Nakahama; Noboru Yamazaki


Macromolecular Chemistry and Physics | 1995

Synthesis of end-functionalized polymers by means of living anionic polymerization, 3. Synthesis of polystyrene and polyisoprene with 1,3-butadienyl termini by reaction of their anionic living polymers with 6-bromo-3-methylene-1-hexene†

Katsuhiko Takenaka; Akira Hirao; Seiichi Nakahama


Polymer International | 1995

Synthesis of end‐functionalized polymer by means of living anionic polymerization. 4. Synthesis of polyisoprene and polystyrene with epoxy termini by reaction of their anionic living polymers with 2‐bromoethyloxirane

Katsuhiko Takenaka; Akira Hirao; Seiichi Nakahama


Journal of Polymer Science: Polymer Letters Edition | 1983

Anionic living polymerization of p-N,N-bis(trimethylsilyl)-aminostyrene. Synthesis of linear poly(p-aminostyrene) with a narrow molecular weight distribution

Kazuo Yamaguchi; Akira Hirao; Ken Suzuki; Katsuhiko Takenaka; Seiichi Nakahama; Noboru Yamazaki


Macromolecular Chemistry and Physics | 1992

Polymerization of monomers containing functional silyl groups, 12. Free-radical polymerization of 2-silyl-substituted 1,3-butadienes†

Katsuhiko Takenaka; Akira Hirao; Seiichi Nakahama


Archive | 1982

Novel living polymer and manufacture of the same

Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka; Kazuo Yamaguchi; Sho Yamazaki


Archive | 1982

Manufacture of styrene derivative polymer

Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka; Kazuo Yamaguchi; Sho Yamazaki


Archive | 1987

Living polymer of butadiene derivative

Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka

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Seiichi Nakahama

Tokyo Institute of Technology

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Akira Hirao

Tokyo Institute of Technology

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Kazuo Yamaguchi

Tokyo Institute of Technology

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Ken Suzuki

Tokyo Institute of Technology

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Akihiko Yamamoto

Tokyo Institute of Technology

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Akira Hirai

Tokyo Institute of Technology

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S. Packirisamy

Tokyo Institute of Technology

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