Kei Kamada

Development of Pr:LuAG Scintillator Array and Assembly for Positron Emission Mammography

Abstract-In order to detect the breast cancer at the early stage with high efficiency, we intend to develop positron emission mammography (PEM), using Pr:LuAG single crystal as a scintillator of this scanner. PEM has the same mechanism of PET, where two 511 keV annihilation gamma-rays are detected by two gamma cameras at opposite side, and reconstruction of the data shows the position of the cancer with malignancy grades. After cutting and polishing processes for each crystal to a physical dimensions of 2.1 × 2.1 × 15 mm3, Pr:LuAG array covered with BaSO4 reflector was used as a sensor head. The one camera unit consisted of 20 × 64 pixels optically coupled with three H8500-03 multi anode PMTs. Our PEM required four cameras at each side. Finally, eight cameras were installed in both sides of the prototype instrument and the spatial resolution was evaluated using the 18F in the breast phantom.

Scintillator-oriented combinatorial search in Ce-doped (Y,Gd)3(Ga,Al)5O12 multicomponent garnet compounds

Ce-doped (YyGd1−y)3(GaxAl1−x)5O12 (x = 0, 1, 2, 3, 4 and y = 1, 2, 3) single crystals are grown by the micro-pulling down method. X-ray diffraction and electron probe microanalysis techniques are employed to check their structure and chemical composition, respectively. Optical and photoluminescence characteristics are measured and radioluminescence spectra, light yield and scintillation decay measurements are further made to evaluate the scintillation performance. We show that balanced Gd and Ga admixture in the Y3Al5O12 structure can considerably increase the scintillation efficiency, and the spectrally corrected light yield value exceeds 44000photonMeV −1 . Scintillation decay times approach that of Ce 3+ photoluminescence decay and an additional less intense slower component is also observed. Physical aspects of energy transfer process and 5d1 excited state depopulation are discussed. The micro-pulling down technique is shown as an ideal tool for a directed combinatorial search for targeted single crystal compositions to reveal those with the highest figure-of-merit for a given application field. (Some figures may appear in colour only in the online journal)

Scintillation Properties of Praseodymium Activated

Scintillation properties of LuAG:Pr grown by Furukawa Co. Ltd., Japan, have been studied. The best crystals display light outputs up to 19000 ph/MeV and an energy resolution of 4.6% at 662 keV. The scintillation yield is found to be a function of size and temperature of the sample; it can be enhanced by 40% upon heating to 450 K. Radioluminescence spectra show both d- f and f-f transitions of Pr3+ ions; the contribution of the latter increases with temperature. The scintillation decays are complex, with a fast decay constant of 20 ns. The presence of 176Lu induces high background activity.

{\rm Lu}_{3}{\rm Al}_{5}{\rm O} _{12}

Scintillation characteristics such as the pulse height, energy resolution, and decay time of single crystals of Tl-doped NaI (Tl:NaI), Ce-doped Lu2SiO5 (Ce:LSO), Ce-doped YAlO3 (Ce:YAP), Ce-doped Gd3(Al,Ga)5O12 (Ce:GAGG), Pr-doped Lu3Al5O12 (Pr:LuAG), undoped LuAG, and Ce-doped Y3Al5O12 (Ce:YAG) transparent ceramics were compared at 25–150 °C to simulate well logging conditions. For increasing temperature, the light output of the scintillators decreased, mostly because of thermal quenching. Among these samples, Pr:LuAG demonstrated the highest scintillation performance at 150 °C.

Single Crystals

To observe time and wavelength-resolved scintillation events, picosecond pulse X-ray excited streak camera system is developed. The wavelength range spreads from vacuum ultraviolet (VUV) to near infrared region (110–900 nm) and the instrumental response function is around 80 ps. This work describes the principle of the newly developed instrument and the first performance test using BaF2 single crystal scintillator. Core valence luminescence of BaF2 peaking around 190 and 220 nm is clearly detected by our system, and the decay time turned out to be of 0.7 ns. These results are consistent with literature and confirm that our system properly works.

Temperature Dependence of Scintillation Properties of Bright Oxide Scintillators for Well-Logging

A new single-crystal Cerium doped Gd₃Al₂Ga₃ O₁₂₃Al₂Ga₃ O₁₂ (GAGG) scintillation crystal with high luminosity, high density and relatively fast decay time has successfully been grown. We report on the first performance results of the new GAGG scintillation crystal read out with silicon photomultipliers (SiPM) from Hamamatsu (MPPC) and FBK. The best energy resolution (511 keV peak of Ge-68) of 7.9% was attained with GAGG coupled to MPPC and 9.0% with the FBK SiPM after correcting for non-linearity. On the other hand, the best coincidence resolving time (FWHM) of polished 3 × 3 × 5 mm³ and 3 × 3 × 20mm³crystals were 464 ±12 ps and 577 ±22 ps for GAGG crystals compared to 179 ±8 ps and 214 ±6 ps for LYSO crystals respectively with MPPCs. The rise time of GAGG was measured to be 200 ps (75%) and 6 ns (25%) while the decay time was 140 ns (92%), 500 ns (7.7%) 6000 ns (0.3%).

Development and Performance Test of Picosecond Pulse X-ray Excited Streak Camera System for Scintillator Characterization

Ce2%:6LiCaAlF6 (6LiCAF) single crystal (nominal composition) with 2 mm in diameter and 50 mm in length was grown by the micro-pulling-down method. Emission from the perturbed Ce3+ centers was observed in an ¿-ray excited radioluminescence. The neutron response was compared with Li-glass (GS20, Saint-Gobain) using 252Cf. The scintillation decay time of Ce2%: 6LiCAF is 38 nsec, which is twice as short as that of GS20. Using Hamamatsu photomultiplier H7416 the photoelectron yield about a half of that of GS20 has been measured for the Ce: 6LiCAF single crystal . Considering the light yield of GS20 (6000 phot/neutron) and the spectral correction due to the different emission peak position in both materials, the light yield of Ce: 6LiCAF single crystal is estimated about 4200 phot/neutron.

First Performance Results of Ce:GAGG Scintillation Crystals With Silicon Photomultipliers

Ce1%, 2% and 3% doped Gd3(Ga,Al)5O12 (GAGG) single crystals were grown by the Cz method. Luminescence and scintillation properties were measured. Light yield change along the growth direction and effects of Ce concentration on scintillation properties in Ce:GAGG were studied. Ce3+ 5d-4f emission within 520-530 nm was observed in the Ce:GAGG crystals. The Ce1%:GAGG sample with 3×3×1 mm size showed the highest light yield of 46000 photon/MeV. The energy resolution was 7.8%@662 keV. With increasing solidification fraction, the LY were decreased. It is proposed that the increase of Ga concentration along the growth direction is the main cause of the decrease of LY. The scintillation decay times were accelerated with increasing Ce concentration in the Ce:GAGG crystals. The scintillation decay times were 92.0 ns, 79.1 ns and 68.3 ns in the Ce1, 2 and 3% GAGG, respectively.

Single Crystal Growth, Optical Properties and Neutron Response of

Various fundamental characteristics of Y2O3 ceramics, such as optical transmittance, reflectivity, absorption coefficient, refractive index, and dielectric constant, were investigated. Furthermore, in order to evaluate the possible application of this material as γ-ray scintillator, other radiation responses, like the α-ray excited emission spectrum, the γ-ray excited pulse height spectrum, the light yield, the nonproportionality, the energy resolution, and the γ-ray excited scintillation decay curves were obtained. The light yield of Y2O3 ceramics was evaluated in about 1.13 times higher than that of Bi4Ge3O12(BGO):Ce single crystals and was estimated in 9300 photon/MeV. The nonproportionality measurements showed a good proportionality. The scintillation decay curve could be fitted by an exponential function characterized by a fast component of about 34 ns.

{\rm Ce}^{3+}

Scintillation properties of praseodymium doped LuAG have been investigated. The crystal is a dense (6.7 g/cm3) scintillator with a short decay time around 20 ns and wavelength emission spectrum peaked at 310 nm. The tested sample was 10 mm times 10 mm times 5 mm cuboid, polished on all surfaces. The dopant concentration amounts to 0.23 mo1%. A light yield of 16000plusmn1600 ph/MeV was measured using high sensitivity (13.7 muA/1mF) Photonis photomultiplier (PMT) XP5500B. High quantum efficiency of this PMT (35%) allowed us to register 5600plusmn400 phe/MeV using 12 mus shaping time in the spectroscopy amplifier. The measured energy resolution was equal to 5.0plusmn0.1%. Response of LuAG:Pr to gamma-rays was found to be proportional over wide energy range. Deviation from proportionality does not exceed 10% at 16.6 keV. This results in good intrinsic energy resolution of LuAG:Pr amounting to 3.0plusmn0.3%, measured with 662 keV gamma-rays from 137Cs.