Keiji Sakaki

The relationship between overpotential and the three phase boundary length

Porous La0.81Sr0.09MnO3 and LSM-YSZ composite electrodes of the solid oxide fuel cell (SOFC) were made, and the relationship between the overpotential and the three phase boundary (TPB) length was investigated by constructing a model. Three-dimensional distribution of TPB for the composite cathode was suggested. The effective thickness of it was observed to be less than 20 μm.

Estimation of the interface states density of a Si/C60 heterojunction by frequency-dependent capacitance–voltage characteristics

Capacitance–voltage (C–V) characteristics of a Si/C60 heterojunction, i.e., a HF solution (7.3% HF+30% NH4F) treated Si surface interfaced solid crystal of C60 molecules, were measured while applying various ac frequencies. The entire C60 thin film and near-interface region of the Si wafer behaved as a depletion region, with the C–V curve showing two distinct regions: one above and one below a threshold bias voltage. Below the threshold, C–V characteristics were dependent on applied frequency, which suggests the presence of interface states that only affect capacitance at lower frequencies. This frequency dependence was analyzed by assuming a suitable equivalent circuit, and based on derived curve-fitting circuit parameters the interface states density was accordingly estimated to have a value as low as ∼1011/cm2 eV. Such a small density indicates that only a few lattice defects occur within the interface of the HF-treated Si surface and C60 crystal. Although no frequency dependence was observed above the...