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Chemical Communications | 2008

Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N3P3Cl6] catalyzed by silylium ions

Yun Zhang; Keith Huynh; Ian Manners; Christopher A. Reed

The temperature required for ring-opening polymerisation of cyclo-N(3)P(3)Cl(6) can be dramatically lowered by employing trialkylsilylium carboranes [R(3)Si(CHB(11)X(11)] as catalysts.


Journal of the American Chemical Society | 2006

Reactions of P-Donor Ligands with N-Silyl(halogeno)organophosphoranimines: Formation of Cations with P-P Coordination Bonds and Poly(alkyl/aryl)phosphazenes at Ambient Temperature

Keith Huynh; and Alan J. Lough; Ian Manners


Journal of the American Chemical Society | 2004

Donor-Stabilized Cations and Imine Transfer from N-Silylphosphoranimines

Eric Rivard; Keith Huynh; and Alan J. Lough; Ian Manners


Chemistry: A European Journal | 2002

Metallochain Cluster Complexes and Metallomacrocyclic Triangles Based on Coordination Bonds between Palladium or Platinum and Diphosphinoacetylene Ligands

Thomas Baumgartner; Keith Huynh; Silvia Schleidt; Alan J. Lough; Ian Manners


Macromolecules | 2010

Synthesis of Poly(alkyl/arylphosphazenes) via the Ambient Temperature Phosphite-Mediated Chain-Growth Polycondensation of (N-Silyl)bromophosphoranimines

Thomas J. Taylor; Alejandro Presa Soto; Keith Huynh; Alan J. Lough; Anthony C. Swain; Nicholas C. Norman; Christopher A. Russell; Ian Manners


Inorganic Chemistry | 2006

Phosphine-Mediated Dehalogenation Reactions of Trichloro(N-silyl)phosphoranimines

Keith Huynh; Eric Rivard; Wesley LeBlanc; Vivienne Blackstone; and Alan J. Lough; Ian Manners


Inorganic Chemistry | 2007

Synthesis and Characterization of New Nitrogen-Donor-Stabilized N-Silylphosphoranimine Cations

Keith Huynh; Eric Rivard; and Alan J. Lough; Ian Manners


Journal of the American Chemical Society | 2009

Synthesis and Reactivity of Phosphine-Stabilized Phosphoranimine Cations, [R3P·PR′2═NSiMe3]+

Keith Huynh; Alan J. Lough; Michelle A. M. Forgeron; Martin Bendle; Alejandro Presa Soto; Roderick E. Wasylishen; Ian Manners


Chemistry: A European Journal | 2007

Synthesis, Structures, and Stability of N-Donor-Stabilized N-Silylphosphoranimine Cations

Keith Huynh; Eric Rivard; Alan J. Lough; Ian Manners


Dalton Transactions | 2011

Donor-stabilised cations, phosphinamide anions, and unusual oxidative cyclisation products from halogenated phosphoranimines and phosphinimines with a bulky 2,4,6-tri-tert-butylphenyl substituent at nitrogen

Keith Huynh; Cindy P. Chun; Alan J. Lough; Ian Manners

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