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Featured researches published by Kenan Yunlu.


Journal of The Less Common Metals | 1989

Synthesis and spectroscopic characterization of novel cerium(IV) aryl and alkyl silyloxides

Peter S. Gradeff; Kenan Yunlu

Abstract Several new compounds containing the Ce(IV)-O-Si unit have been prepared by exchange reaction of Ce(OiPr)4 [OiPr ≡ isopropoxide] with various silanols or silanediols. The products are mainly yellow solids, soluble in most organic solvents and in some cases suprisingly resistant to hydrolysis. They have been characterized by nuclear magnetic resonance, IR spectroscopy, elemental analyses and, in the case of Ce(OSiPh3)4· x DME, by X-ray structure analysis.


Inorganic Chemistry | 1990

Alcohol adducts of alkoxides intramolecular hydrogen bonding as a general structural feature

Brian A. Vaartstra; John C. Huffman; Peter S. Gradeff; Liliane G. Hubert-Pfalzgraf; Jean Claude Daran; Stephen Parraud; Kenan Yunlu; Kenneth G. Caulton


Inorganic Chemistry | 1991

Photoreduction of cerium (IV) in Ce sub 2 (O sup i Pr) sub 8 ( sup i PrOH) sub 2. Characterization and structure of Ce sub 4 O(O sup i Pr) sub 13 ( sup i PrOH)

Kenan Yunlu; Peter S. Gradeff; Norman M. Edelstein; Wing K. Kot; G. V. Shalimoff; William E. Streib; Brian A. Vaartstra; Kenneth G. Caulton


Inorganic Chemistry | 1990

Synthesis of yttrium and lanthanide silyloxy complexes from anhydrous nitrate and oxo alkoxide precursors and the x-ray crystal structure of [Ce(OSiPh3)3(THF)3](THF)

Peter S. Gradeff; Kenan Yunlu; Timothy J. Deming; Jeffrey M. Olofson; Robert J. Doedens; William J. Evans


Inorganic Chemistry | 1989

Reactivity of ceric ammonium nitrate with sodium cyclopentadienide. The x-ray crystal structure of bis(dimethoxyethane)trinitratocerium

Peter S. Gradeff; Kenan Yunlu; Timothy J. Deming; Jeffrey M. Olofson; Joseph W. Ziller; William J. Evans


Archive | 1987

Ceric hydrocarbyl silyloxides and process for their preparation

Peter S. Gradeff; Kenan Yunlu


Archive | 1988

ALKOXY-TYPE DERIVATIVE COMPOUNDS AND PROCESS FOR PREPARING ALKOXY-TYPE DERIVATIVES OF TRIVALENT GROUP 3B METALS

Peter S. Gradeff; Heiko Mauermann; Kenan Yunlu; Carlos Ramirez


Archive | 1993

Process for the preparation of perovskites on the basis of manganese or chromium and perovskites so obtained.

Marie-Odile Lafon; Hubert Nussbaum; Jean-Michel Tourre; Kenan Yunlu


Archive | 1987

Process for the preparation of ceric hydrocarbyl silyloxides by transetherification of ceric alkoxides

Peter S. Gradeff; Kenan Yunlu


Inorganic Chemistry | 1991

Nature of the phase change in solid bis(isopropyl alcohol)octakis(isopropoxo)dicerium, as determined by variable-temperature x-ray diffraction and deuterium NMR spectroscopy

Beth A. Huggins; Paul D. Ellis; Peter S. Gradeff; Brian A. Vaartstra; Kenan Yunlu; John C. Huffman; Kenneth G. Caulton

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Kenneth G. Caulton

Indiana University Bloomington

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Brian A. Vaartstra

Indiana University Bloomington

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John C. Huffman

Indiana University Bloomington

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