Khairul Azlan Mustapha

Biomarkers and inorganic geochemical elements of Late Jurassic-Early Cretaceous limestone sediments from Banik Village in the Kurdistan Region, Northern Iraq: implications for origin of organic matter and depositional environment conditions

Late Jurassic-Early Cretaceous limestone sediments from Banik Village in the Kurdistan Region, Northern Iraq, were analysed based on a combined investigation of elemental composition and biomarker characterisation. These investigations were used to define the origin, type of organic matters and their relation to the environment conditions during deposition. The bulk geochemical characteristics indicated that the Late Jurassic-Early Cretaceous limestone sediments were deposited in a marine environment with calcium-rich seawater. Their biomarkers provide evidence for a major contribution by aquatic organic matter with a minor terrigenous organic matter contribution. This is confirmed by normal alkanes, hopanoids, steroids and related compounds of the saturated hydrocarbons. Moreover, the salinity stratification and relatively reducing bottom water conditions are evidenced in the Late Jurassic-Early Cretaceous limestone sediments, as identified from Sr/Br, V/Ni and Pr/Ph ratios. The occurrence of gammacerane biomarker in the analysed samples is also a strong indicator of reducing and salinity stratification during deposition. Therefore, a stratified water column with salinity and relatively anoxic bottom water conditions contribute to organic matter (OM) preservation.

Geochemical Characteristics of Crude Oils, their Asphaltene and Related organic Matter Source Inputs from Fula Oilfields

The oils were derived from alga organic matter, which was sourced from sediments deposited in a lacustrine environment under suboxic to relatively anoxic conditions and were generated from mature source rock with a wide range of maturity ranging from early to peak oil window. This is indicated by biomarker compositions based on saturated and aromatic fractions and bulk geochemical characteristics. Previous work by Makeen et al. (2013) on the Abu Gabra shales in the basin shows similar organic matter characteristics, palaeo-depositional environment and maturity, suggesting that the Fula oils are derived from the early Cretaceous Abu Gabra shales. This genetic relationship is also confirmed by the similarities in the structural moieties of the Fula oil asphaltenes and Abu Gabra shale kerogens (Makeen et al., 2015).