Khaliq Majeed

Rice Husk Filled Polymer Composites

Natural fibers from agricultural wastes are finding their importance in the polymer industry due to the many advantages such as their light weight, low cost and being environmentally friendly. Rice husk (RH) is a natural sheath that forms around rice grains during their growth. As a type of natural fiber obtained from agroindustrial waste, RH can be used as filler in composites materials in various polymer matrices. This review paper is aimed at highlighting previous works of RH filled polymer composites to provide information for applications and further research in this area. Based on the information gathered, application of RH filled composites as alternative materials in building and construction is highly plausible with both light weight and low cost being their main driving forces. However, further investigations on physical and chemical treatment to further improve the interfacial adhesion with polymeric matrix are needed as fiber-polymer interaction is crucial in determining the final composite properties. Better understanding on how the used polymer blends as the matrix and secondary fillers may affect the properties would provide interesting areas to be explored.

Characteristic Properties of Nanoclays and Characterization of Nanoparticulates and Nanocomposites

Clays have been one of the more important industrial minerals; and with the recent advent of nanotechnology, they have found multifarious applications and in each application, nanoclays help to improve the quality of product, economize on the cost and saves environment. The chapter describes key characteristics of nanoclays and their classification on the basis of the arrangement of “sheets” in their basic structural unit “layer”. Major groups include kaolin–serpentine, pyrophyllite-talc, smectite, vermiculite, mica and Chlorite. The structural, morphological and physicochemical properties of halloystite and montmorillonite nanoclays, representative of the 1:1 and 2:1 layer groups, respectively, are discussed as well. After briefly introducing the surface modification of clay minerals by modifying or functionalizing their surfaces and their incorporation into polymer matrices to develop polymer/clay nanocomposites, techniques that are being employed to characterize these nanoclays, in general, and the sample preparation for these techniques, in particular, are also reviewed in this chapter.

Enhanced mechanical and thermal properties of hybrid graphene nanoplatelets/multiwall carbon nanotubes reinforced polyethylene terephthalate nanocomposites

The effects of graphene nanoplatelets (GNP) and multiwall carbon nanotube (MWCNT) hybrid nanofillers on the mechanical and thermal properties of reinforced polyethylene terephthalate (PET) have been investigated. The nanocomposites were melt blended using the counter rotating twin screw extruder followed by injection molding. Their morphology, mechanical and thermal properties were characterized. Combination of the two nanofillers in composites formulation supplemented each other which resulted in the overall improvement in adhesion between fillers and matrix. The mechanical properties and thermal stability of the hybrid nanocomposites (PET/GNP1.5/MWCNT1.5) were significantly improved compared to PET/GNP3 and PET/MWCNT3 single filer nanocomposites. However, it was observed that GNP was better in improving the mechanical properties but MWCNT resulted in higher thermal stability of Nanocomposite. The transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM) revealed uniform dispersion of the hybrid fillers in PET/GNP1.5/MWCNT1.5 nanocomposites while agglomeration was observed at higher filler content. The MWCNT prevented the phenomenal stacking of the GNPs by forming a bridge between adjacent GNP planes resulting in higher dispersion of fillers. This complimentary geometrical structure is responsible for the significant improvement in the thermal stability and mechanical properties of the hybrid nanocomposites.

Kenaf-Biocomposites: Manufacturing, Characterization, and Applications

Given the environmental issues faced by the industry, the development of engineering products from natural resources has increased worldwide. The increasing demand for cost and weight reduction can be attained by sustainable manufacturing techniques. Kenaf plants are natural resources, which show high performance compared with other natural fibers. Kenaf fibers can be modified by physical and chemical methods. Kenaf polymer composites are fabricated via processing technologies based on thermoforming, thermoplastics, and thermosets. Thermoplastic processes, such as compression molding, pultrusion, extrusion, and solution blending, have been adapted but are limited to two-dimensional structures based on polymer composites. However, the thermoset processes include sheet molding and resin transfer molding techniques, which were also employed for the fabrication of kenaf polymer composites. Most of the recent work discussed Kenaf-Reinforced Composites (KRCs) prepared by compression molding. However, resin transfer molding has received attention because of its versatility. This chapter aimed to highlight and explore advance research related to the fabrication of kenaf polymer composites by various routes, as well as their physical and mechanical properties. A brief description of KRCs with different additives, fiber loadings, treatment, and polymers is also discussed. Furthermore, these KRCs with versatile mechanical properties may be used for construction, building materials, animal beds, corrosion resistance, marine, electrical, transportation, and automotive applications.

Structural properties of rice husk and its polymer matrix composites: An overview

Abstract There has been enormous interest in natural fiber application as reinforcing filler due to the interests in renewable raw materials and more environmentally friendly and sustainable resources. Rice husk (RH), a natural sheath that forms around rice grains during their growth, is an agro-industrial waste, and its utilization as reinforcement in composite materials has increased tremendously. This chapter describes the key structural properties of RH and its physical and chemical treatment methods to enhance interfacial adhesion of various matrices with RH. After introducing the reinforcing potential of RH on various thermoplastics and thermosets, thermal stability and water absorption properties of the composites are also discussed. A brief overview on the potential of RH to hybridize with other fillers is also included in this chapter.