Kirsten Barlow

A review of the effects of wastewater sodium on soil physical properties and their implications for irrigation systems

This paper reviews the effects of wastewater sodium on soil physical properties, particularly with respect to irrigation systems. Fundamental sodicity concepts are examined including (i) sodicity definitions, (ii) the effects of sodium on soil properties, (iii) a discussion of factors that impede the infiltration rate and hydraulic conductivity, (iv) the changes that occur in ionic strength of percolating water in soil, and (v) consideration of the wastewater and soil constituents that modify the effective sodium adsorption ratio. Importantly, the ability for soils to assimilate wastewater over time changes, but these changes are not often considered prior to the planning of such irrigation systems, or after the irrigation systems are operating. The general lack of understanding of sodicity is in part due to the considerable variation in sodicity definitions. Exchangeable sodium percentage (ESP) values that are reported to pose a sodicity problem vary around the world due to the different mineralogy of the soils investigated, but variations in threshold ESP values have also been caused by a lack of consideration of the solution electrolyte concentration when determining ESP. In practice, the effects of sodicity may be evident in soils that are well under reported threshold values. When the effects of sodicity are identified, the landholder at least has the opportunity to implement remediation practices. However, more often than not, the effects of sodium from irrigation water are latent, leading to considerable problems following the cessation of effluent irrigation and changed land use.

Phosphorus export at the paddock, farm-section, and whole farm scale on an irrigated dairy farm in south-eastern Australia

Phosphorus (P) exported from agricultural land contributes to the eutrophication of inland water systems. Although P export has been extensively researched at the paddock scale, our understanding of farm-scale export is limited. This paper presents the results of a 3-year monitoring project that investigated P export at the paddock, farm- section, and whole farm scales on an irrigated dairy farm in south-eastern Australia. Annual average concentrations of 2.2-11 mg P/L, and annual loads of 2.5-23 kg P/ha were measured at the paddock and farm-section scale over the 3 years, with the quality of irrigation water applied having no significant effect on P export in surface runoff. At the farm scale, effective management of the water reuse system significantly reduced phosphorus export by up to 98%. During the 3-year period, P concentrations and loads exported in surface runoff consistently decreased between the paddock and farm-section scales (e.g. P-28 exported 13.8 kg P/ha, whereas S-4 exported 6.7 kg/ha in 2001), with the decrease in P export described using a scaling factor. Our results suggest that data on paddock-scale P export can rarely be proportionally assigned to predict section- or farm-scale export, at least on irrigated dairy farms in south-eastern Australia. Additional keywords: spatial scale, nutrient, surface runoff, overland flow.

Modelling phosphorus exports from rain-fed and irrigated pastures in southern Australia

Pasture-based grazing systems contribute to the excessive nutrients found in some streams in south-eastern Australia. This study investigated phosphorus (P) exported in runoff from a rain-fed dairy pasture (Darnum) and 4 bays of irrigated dairy pasture (MRF). Runoff was monitored for 7 years at Darnum and 2 years at the MRF to identify factors associated with the variation in total P (TP) concentrations between events. The flow-weighted mean annual P concentrations in runoff varied between 3.3 and 28.2 mg TP/L for Darnum and 6.2 and 31.5 mg TP/L for the MRF. The relationships between TP concentrations in runoff and days between fertiliser application and runoff, days between grazing and runoff, and total storm flow were examined using an additive component model that explained 61% and 70% of the variation in log-transformed TP for Darnum and the MRF, respectively. The interval between application of fertiliser and runoff and the effect of year were highly significant and explained most of the variation in TP. Grazing and fertiliser application were identified as the major factors that may affect TP concentrations that the land manager can control (preventable). The estimates of year effect (i.e. the component of TP not explained by the other variables and over which the land manager had no apparent means of control) ranged from 1.60 mg (s.e. 1.99) to 7.14 mg (s.e. 1.90) TP/L in non-drought years (>45 kL/ha runoff annually). The year effect averaged 5.7 and 6.9 mg TP/L for Darnum and the MRF, respectively. It is shown that an additive component model provides a useful structure for investigating similar, field-scale data.

A comparison of some surface soil phosphorus tests that could be used to assess P export potential

Phosphorus (P) exports from agricultural land are a problem world-wide and soil tests are often used to identify high risk areas. A recent study investigated changes in soil (0–20 mm), soil water and overland flow in 4 recently laser-graded ( 10 years) irrigated pastures in south-eastern Australia before and after 3 years of irrigated dairy production. We use the results from that study to briefly examine the relationships between a series of ‘agronomic’ (Olsen P, Colwell P), environmental (water-extractable P, calcium chloride extractable P, P sorption saturation, and P sorption), and other (total P, organic P) soil P tests. Of the 2 ‘agronomic’ soil P tests, Colwell P explained 91% of the variation in Olsen P, and Colwell P was better correlated with the other soil tests. With the exception of P sorption, all soil P tests explained 57% or more of the total variation in Colwell P, while they explained 61% or less of Olsen P possibly due to the importance of organic P in this soil. Variations in total P were best explained by the organic P (85%), Calcium chloride extractable P (83%), water-extractable P (78%), and P sorption saturation (76%). None of the tests adequately predicted the variation in P sorption at 5 mg P/L equilibrating solution concentration. The results of this limited study highlight the variability between soil P tests that may be used to estimate P loss potential. Moreover, these results suggest that empirical relationships between specific soil P tests and P export potential will have limited resolution where different soil tests are used, as the errors in the relationship between soil test P and P loss potential are compounded by between test variation. We conclude that broader study is needed to determine the relationships between soil P tests for Australian soils, and based on that study a standard protocol for assessing the potential for P loss should be developed.

Controlling soil water content in fertiliser dissolution experiments

Phosphorus lost in runoff from agricultural land leads to the enrichment of surface waters and contributes to algal blooms. Fertilisers are one source of this P. To compare the water available P of different fertiliser formulations in the laboratory it is necessary to control environmental conditions, temperature, relative humidity and soil water content, prior to simulating rainfall. Two chambers were designed in which relative humidity and soil water content were controlled using salt solutions. An initial design comprising a sealed chamber with three layers of soil samples over a salt bath was found to be inferior to a single layer design. The changes in water content of soil samples were used to test the single layer chamber in a constant temperature environment (15 °C) using a saturated KCl solution (90% relative humidity). Based on the final soil water content of the samples, the spatial variation within the chamber was within tolerable limits. The single layer chamber was used for a simulation experiment comparing the water available P of two commercial fertilisers. Using a saturated resorcinol solution (95% relative humidity) soil samples were equilibrated at 15 °C for 21 days, fertiliser added, and the water available P measured up to 600 h after fertiliser application. The results indicate that the amount of water available P was related to the fertiliser compound and exponentially related to the time since fertiliser application. It was concluded that the single layer chamber is suitable for controlling relative humidity and soil water content in trials such as these where the water available P of fertilisers are being compared.