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Dive into the research topics where Kohji Kamada is active.

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Featured researches published by Kohji Kamada.


Journal of Prosthetic Dentistry | 1998

Effect of ceramic surface treatments on the bond of four resin luting agents to a ceramic material

Kohji Kamada; Keiichi Yoshida; Mitsuru Atsuta

PURPOSE This study evaluated the effect of various ceramic surface treatments on the shear bond strengths of four resin luting agents to Cerec 2 ceramic material. MATERIAL AND METHODS Four ceramic surface treatments were performed. All groups were subjected to the control treatment, which was abrasion with No. 600 silicon carbide paper. The other three group treatments were etching with phosphoric acid gel, application of bonding agent containing silane coupler, and application of silane coupling agent after etching with phosphoric acid gel. Cerec 2 ceramic specimens were treated with one of the four methods and then cemented together with each of the four resin luting agents (Super-Bond C&B, Panavia 21, Clapearl, and Vita Cerec Duo Cement). Half of the specimens were stored in water and the other half were thermal cycled before shear bond strength testing. RESULTS Treatment with the silane coupler improved the shear bond strength compared only with the abrasion with carbide paper (control). When the ceramic material was treated with the silane coupler or the silane coupling agent after etching with phosphoric acid gel, no significant differences in bond strength were noted between water storage and 20,000 thermal cycles for any of the four resin luting agents. After 20,000 thermal cycles, all specimens treated with the silane coupling agent with phosphoric acid gel except those cemented with Super-Bond C&B resin luting agent after etching showed cohesive failures within the ceramic. CONCLUSION Combined surface treatment of etching with phosphoric acid and application of silane coupling agent provides the highest bond strengths of resin luting agents to Cerec 2 ceramic material after thermal cycling.


Journal of Dentistry | 2000

Effect of thione primers on bonding of noble metal alloys with an adhesive resin

H. Matsumura; Kohji Kamada; Naomi Tanoue; Mitsuru Atsuta

OBJECTIVES The purpose of the current study was to evaluate the effects of two metal conditioners on the bond durability of an adhesive resin joined to noble metal alloys by comparing pre- and post-thermocycling bond strengths. METHODS Two different sizes of disk specimens (10 and 8mm in diameter by 2.5mm thickness) were prepared from silver-indium (Ag-In-Zn, Salivan), silver-palladium-copper-gold (Ag-Pd-Cu, Castwell M.C.12), metal-ceramic gold (Au-Pt-Pd, Degudent-Universal), metal-ceramic palladium (Pd-Ga-Co, PTM 88), type IV gold (type IV, Casting Gold) alloys, and pure silver (pure Ag). The specimens were air-abraded with 50-microm grain sized alumina, conditioned either with a thiouracil primer (Metaltite) or with a thione-phosphate primer (Alloy Primer), then bonded with an adhesive resin (Super-Bond Opaque). Shear bond strengths were determined both before and after repeated thermocycling (4 degrees C and 60 degrees C, 1min each, 100, 000cycles). The results were compared by analysis of variance and post-hoc multiple comparison intervals. RESULTS The average post-thermocycling bond strengths in MPa (n=8) generated with the thiouracil primed and thione-phosphate primed groups, respectively, were: 3.4 and 5.8 for the Ag-In-Zn alloy, 40.4 and 37.7 for the Ag-Pd-Cu alloy, 26.4 and 33.5 for the Au-Pt-Pd alloy, 27.4 and 36.6 for the Pd-Ga-Co alloy, 40.2 and 40.3 for the type IV alloy, and 37.3 and 32.4 for the pure Ag. The Ag-In-Zn alloy exhibited significantly lower bond strength than the other alloys, whereas the Ag-Pd-Cu and type IV alloys exhibited the greatest magnitude of bond strength for both primers (p<0.05). CONCLUSIONS It can be concluded that the combined use of either of the two thione primers and the adhesive resin is effective for bonding the metal/alloys examined, with the exception of the Ag-In-Zn alloy.


Journal of Prosthetic Dentistry | 1996

Shear bond strengths of three resin cements used with three adhesive primers for metal

Keiichi Yoshida; Kohji Kamada; Mika Tanagawa; Mitsuru Atsuta

This study compared the durability and shear bond strengths of combinations of three adhesive primers and three resin cements bonded to silver-palladium-copper-gold (Ag-Pd-Cu-Au) and cobalt-chromium (Co-Cr) alloys. The adhesive luting cements Imperva Dual, Panavia 21, and Super-Bond C&B and the adhesive primers Metal Primer material, V-Primer material, and Cesead Opaque Primer material were used. The application of Metal Primer material was effective in improving the shear bond strengths between each of the three resin cements and Ag-Pd-Cu-Au alloy compared with nonprimed specimens. Co-Cr alloy primed with Cesead Opaque Primer, followed by cementation with Imperva Dual or Super-Bond C&B luting cements yielded the strongest shear bond strengths after 50,000 thermocycles, and Panavia 21 cement did not reveal any significant differences in bond strengths between nonprimed specimens and those primed with Cesead Opaque Primer at all thermocycles.


Journal of Biomedical Materials Research | 1999

Thin sol-gel-derived silica coatings on dental pure titanium casting.

Keiichi Yoshida; Kohji Kamada; Koichi Sato; Ruriko Hatada; K. Baba; Mitsuru Atsuta

The sol-gel dipping process, in which liquid silicon alkoxide is transformed into a solid silicon-oxygen network, can produce a thin film coating of silica (SiO(2)). The features of this method are high homogeneity and purity of the thin SiO(2) film and a low sinter temperature, which are important in the preparation of coating films that can protect metallic ion release from the metal substrate and prevent attachment of dental plaque. We evaluated the surface properties of dental pure titanium casting coated with a thin SiO(2) or SiO(2)/F-hybrid film by the sol-gel dipping process. The metal specimens were pretreated by dipping in isopropylalcohol solution containing 10 wt% 3-aminopropyl trimethoxysilane and treated by dipping in the silica precursor solution for 5 min, withdrawal at a speed of 2 mm/min, air-drying for 20 min at room temperature, heating at 120 degrees C for 20 min, and then storing at room temperature. Both SiO(2) and SiO(2)/F films bonded strongly (above 55 MPa) to pure titanium substrate by a tensile test. SiO(2(-)) and SiO(2)/F-coated specimens immersed in 1 wt% of lactic acid solution for two weeks showed significantly less release of titanium ions (30. 5 ppb/cm(2) and 9.5 ppb/cm(2), respectively) from the substrate than noncoated specimens (235.2 ppb/cm(2)). Hydrophobilization of SiO(2(-)) and SiO(2)/F-coated surfaces resulted in significant increases of contact angle of water (81.6 degrees and 105.7 degrees, respectively) compared with noncoated metal specimens (62.1 degrees ). The formation of both thin SiO(2) and SiO(2)/F-hybrid films by the sol-gel dipping process on the surface of dental pure titanium casting may be useful clinically in enhancing the bond strength of dental resin cements to titanium, preventing titanium ions release from the substrate, and reducing the accumulation of dental plaque attaching to intraoral dental restorations.


Journal of Dentistry | 2008

Effects of primers containing sulfur and phosphate monomers on bonding type IV gold alloy.

Yohsuke Taira; Kohji Kamada

OBJECTIVE The purpose of the present study was to evaluate the effect of five primers (two sulfur, one phosphate, and two sulfur-phosphate dual-function primers) on the bond strength between a self-curing luting agent and gold-copper-silver (Au-Cu-Ag) alloy. METHODS The primers used were two sulfur primers (V-Primer and Metaltite), one phosphate primer (Epricord), and two primers which contained a sulfur monomer and a phosphate monomer (Alloy Primer and Metaltite/Epricord). The surface of Au-Cu-Ag specimens were blasted with alumina, and then bonded with acrylic rods using a tri-n-butylborane-initiated self-curing luting agent. Shear bond strengths were determined after 5000 thermocycles. An additional alumina-blasted Au-Cu-Ag alloy specimen was subjected to X-ray photoelectron spectroscopy (XPS) analysis. RESULTS The maximum shear bond strengths were obtained with Metaltite/Epricord (29.6+/-2.3 MPa) and Alloy Primer (23.0+/-1.6 MPa), followed by Metaltite (10.3+/-4.2 MPa), V-Primer (8.9+/-0.6 MPa), Epricord (6.4+/-1.5 MPa), and No primer control (2.0+/-0.5 MPa). The XPS analysis detected six chemical elements (Au, Cu, Ag, Al, O, and C) on the Au-Cu-Ag alloy. In addition to pure Au element, the metal oxide-states of Ag2O, AgO, Cu2O, and CuO were suggested. CONCLUSION The combined use of a sulfur monomer and a phosphate monomer significantly improved the bond strength of resin to Au-Cu-Ag alloy which should be especially significant to clinicians.


Journal of Biomedical Materials Research | 1999

Silica coatings formed on noble dental casting alloy by the sol-gel dipping process.

Keiichi Yoshida; Mika Tanagawa; Kohji Kamada; Ruriko Hatada; K. Baba; Takeshi Inoi; Mitsuru Atsuta

The sol-gel dipping process, in which liquid silicon alkoxide is transformed into the solid silicon-oxygen network, can produce a thin film coating of silica (SiO2). The features of this method are high homogeneity and purity of the thin SiO2 film and a low sinter temperature, which are important in preparation of coating films that can protect from metallic ion release from the metal substrate and prevent attachment of dental plaque. We evaluated the surface characteristics of the dental casting silver-palladium-copper-gold (Ag-Pd-Cu-Au) alloy coated with a thin SiO2 film by the sol-gel dipping process. The SiO2 film bonded strongly (over 40 MPa) to Ti-implanted Ag-Pd-Cu-Au alloy substrate as demonstrated by a pull test. Hydrophobilization of Ti-implanted/SiO2-coated surfaces resulted in a significant increase of the contact angle of water (80.5 degrees) compared with that of the noncoated alloy specimens (59.3 degrees). Ti-implanted/SiO2-coated specimens showed the release of many fewer metallic ions (192 ppb/cm2) from the substrate than did noncoated specimens (2,089 ppb/cm2). The formation of a thin SiO2 film by the sol-gel dipping process on the surface of Ti-implanted Ag-Pd-Cu-Au alloy after casting clinically may be useful for minimizing the possibilities of the accumulation of dental plaque and metal allergies caused by intraoral metal restorations.


Journal of Dentistry | 1998

Metal chloride primers for bonding dentine with tri-n-butylborane-initiated luting agents

Yohsuke Taira; H. Matsumura; Keiichi Yoshida; Kohji Kamada; Takuo Tanaka; Mitsuru Atsuta

OBJECTIVES The bonding of resin to dentine is dependent largely on surface modifications. The purpose of the present study was to test the hypothesis that a role of the metal chlorides used as primers is to initiate polymerization of resin at the resin-dentine interface, thereby affecting bond strength. METHODS Nine primers were evaluated, comprising aqueous 2-hydroxyethyl methacrylate (HEMA) solutions containing AICl3, CeCl3, CoCl2, CuCl2, FeCl3, NiCl2, MgCl2, SnCl2 or ZnCl2, respectively. One of the two luting agents (Super-Bond resin) consisted of methyl methacrylate (MMA), 4-methacryloyloxyethyl trimellitate anhydride (4-META) and tri-n-butylborane (TBB) initiator. The other luting agent (MMA-TBB resin) consisted of MMA and TBB without 4-META. Extracted bovine teeth were ground to expose the dentine, etched with an aqueous solution of 10% phosphoric acid, primed, and then bonded with stainless-steel rods; tensile bond strengths were determined after 1-day immersion in water. Data were analysed by ANOVA and Duncans new multiple range test (P < 0.05). RESULTS Four of the metal chlorides (CuCl2, FeCl3, MgCl2 and ZnCl2) enhanced the bond strengths of MMA-TBB resin to dentine. With Super-Bond resin, maximum bond strengths of 15.6 MPa and 19.0 MPa were recorded with primer containing 2.0 x 10(-5) mol g(-1) FeCl3 and 2.0 x 10(-6) mol g(-1) CuCl2, respectively. CONCLUSIONS Bonding techniques, combining the use of either cupric primer or ferric primer with 10% phosphoric acid etchant may be suitable for application in seating resin-bonded prostheses with TBB-initiated luting materials.


Journal of Prosthodontic Research | 2010

Flexural strength of the joint between glass-infiltrated alumina frames and the alumina-magnesia modifier

Yohsuke Taira; Junichi Fukui; Tetsuro Odatsu; Kohji Kamada; Takashi Sawase

PURPOSE The purpose of the present study was to evaluate the flexural strength of the joint between glass-infiltrated alumina frames and the experimental adjusting agent (MA modifier) that contains alumina and magnesia. METHODS A commercially available adjusting agent (Optimizer), a slurry of alumina powder (Alumina modifier), and a bulk specimen (joint-free alumina) were used as controls. Beam-shaped alumina specimens were machined from an alumina block. The ends of two alumina beams were positioned at an interval of 1.0 mm and joined with each adjusting agent. The joined specimens were subjected to sintering, glass infiltration firing, glass control firing, and then a three-point bending test was carried out to evaluate the flexural strength. RESULTS The maximum flexural strength was observed in the joint-free alumina, followed by MA modifier, Optimizer and Alumina modifier. With the exception for joint-free alumina, the failure modes after three-point bending test tended to shift from adhesive failure at substrate material-adjusting agent interface to cohesive failure within adjusting agent as the flexural strength increased. CONCLUSIONS The use of MA modifier significantly improved the flexural strength of joined glass-infiltrated alumina frame. The MA modifier could be applied for adjusting the margin as an alternative to Optimizer when fabricating crown and bridge substructures with In-Ceram Alumina system.


Journal of Dental Sciences | 2018

Effect of tetrabutylammonium dihydrogen trifluoride treatment on durability of resin–titanium bond strengths

Yohsuke Taira; Takafumi Egoshi; Michino Sakihara; Kei Kaida; Kohji Kamada

Abstract This study investigated the effect of titanium surface treatment with tetrabutylammonium dihydrogen trifluoride (TDTF) on the bond between the titanium and resins for dental applications. Commercially pure titanium (cpTi) specimens were air-abraded with alumina particles, surface-treated with an etchant containing TDTF (Monobond Etch & Prime; ETCH) for 10 s (ETCH10) or 30 s (ETCH30), rinsed with water, treated with a phosphoric monomer-based primer, and bonded to an indirect resin composite. Non-ETCH-treated specimens (no-ETCH) were prepared as a control. The shear bond strengths were determined before and after 100,000 thermocycles, and the means and standard deviations for eight specimens were calculated and statistically analyzed using a non-parametric Steel–Dwass test (α = 0.05). The ETCH10 and ETCH30 specimens exhibited the highest bond strengths, which were maintained for 100,000 thermocycles, while significantly lower values were obtained for no-ETCH specimens. In conclusion, the surface treatment with a TDTF-containing etchant considerably improved the durability of the resin–cpTi bond strength. Appropriate surface treatment of cpTi should be selected for achieving longer-lasting treatments and better clinical solutions for patients.


Journal of Dental Sciences | 2017

Evaluation of five primers and two opaque resins for bonding ceria-stabilized zirconia/alumina nanocomposite

Kohji Kamada; Yohsuke Taira; Ikuya Watanabe; Takashi Sawase

The purpose of this study was to evaluate the effect of five primers [Super-Bond C&B Monomer (SB), Clearfil Ceramic Primer, Alloy Primer, M.L. Primer, and AZ Primer] and two undercoating opaque resins [Super-Bond C&B (S-opaque) and Ceramage Pre-opaque (C-opaque)] on the bonding of a resin composite veneering material to a ceria-stabilized tetragonal zirconia polycrystals/alumina nanocomposite (Ce-TZP/Al2O3). Disk-shaped specimens of Ce-TZP/Al2O3 were sandblasted with alumina and primed. The undercoating opaque resins and resin composites were subsequently applied to the specimen, and then light cured. After 5000 thermocycles at 4°C and 60°C, shear bond strengths were determined. Data were analyzed using analysis of variance, Tukey–Kramer honest significant difference test, and Student t test (n = 10, α = 0.05). With the exception of SB/S-opaque, all S-opaque groups exhibited significantly higher bond strengths than C-opaque groups. The use of S-opaque resin is recommended when veneering frameworks made of Ce-TZP/Al2O3.

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Ruriko Hatada

Technische Universität Darmstadt

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