Konrad Gumowski

Hydrophobization of epoxy nanocomposite surface with 1H,1H,2H,2H-perfluorooctyltrichlorosilane for superhydrophobic properties

Nature inspires the design of synthetic materials with superhydrophobic properties, which can be used for applications ranging from self-cleaning surfaces to microfluidic devices. Their water repellent properties are due to hierarchical (micrometer- and nanometre-scale) surface morphological structures, either made of hydrophobic substances or hydrophobized by appropriate surface treatment. In this work, the efficiency of two surface treatment procedures, with a hydrophobic fluoropolymer, synthesized and deposited from 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS) is investigated. The procedures involved reactions from the gas and liquid phases of the PFOTS/hexane solutions. The hierarchical structure is created in an epoxy nanocomposite surface, by filling the resin with alumina nanoparticles and micron-sized glass beads and subsequent sandblasting with corundum microparticles. The chemical structure of the deposited fluoropolymer was examined using XPS spectroscopy. The topography of the modified surfaces was characterized using scanning electron microscopy (SEM), and atomic force microscopy (AFM). The hydrophobic properties of the modified surfaces were investigated by water contact and sliding angles measurements. The surfaces exhibited water contact angles of above 150° for both modification procedures, however only the gas phase modification provided the non-sticking behaviour of water droplets (sliding angle of 3°). The discrepancy is attributed to extra surface roughness provided by the latter procedure.

Turbulent spots in channel flow: An experimental study - Large-scale flow, inner structure and low-order model

We present new experimental results on the development of turbulent spots in channel flow. The internal structure of a turbulent spot is measured, with Time Resolved Stereoscopic Particle Image Velocimetry. We report the observation of travelling-wave-like structures at the trailing edge of the turbulent spot. Special attention is paid to the large-scale flow surrounding the spot. We show that this large-scale flow is an asymmetric quadrupole centred on the spot. We measure the time evolution of the turbulent fluctuations and the mean flow distortions and compare these with the predictions of a nonlinear reduced order model predicting the main features of subcritical transition to turbulence.Graphical abstract

Dynamic contact of droplet with superhydrophobic surface in conditions favour icing

Flight like droplet impact with superhydrophobic substrate in conditions favour icing is discussed in this work. Test stand with fast camera and equipment eligible to obtain temperatures and humidity at different ranges, lead to results which can prove, that superhydrophobic surface might be good ice repellent substrate. The influence of air humidity on droplet freezing was confirmed.