Kosaku Kato

Terahertz wave generation from spontaneously formed nanostructures in silver nanoparticle ink.

We demonstrate terahertz pulse generation from silver nanoparticle ink, originally developed for printed electronics, under irradiation by femtosecond laser pulses. Using metal nanoparticle ink, metallic nanostructures can be easily made in a large area without lithographic techniques. Terahertz pulses were emitted from the baked ink, having spontaneously formed nanostructures of ∼100  nm. From the results of the baking temperature dependence and the polarization measurement, the terahertz generation is attributed to the nonlinear polarization induced by the enhanced local fields around these nanostructures. This study paves the way for the future development of terahertz emitters which have resonances in both the near-infrared light and the terahertz wave, by combining micrometer-scale structures drawn by an inkjet printer and nanometer-scale structures formed during the baking process.

Waveguide resonance mode response of stacked structures of metallic sub-wavelength slit arrays

Detailed measurements of the optical properties of two-tier systems composed of metallic plates perforated with periodic sub-wavelength slit patterns were carried out using terahertz time-domain spectroscopy. We demonstrate that the transmission properties observed experimentally for various configurations can be reproduced successfully by simulations based on the finite-differential time-domain method. Fabry–Perot-like waveguide resonance mode behaviors specific to this quasi-dielectric system were then investigated. For structures with no lateral displacement between the slit-array plates, mode disappearance phenomena, which are caused by destructive interference between the odd-order mode and the blue- or red-shifted even-order modes, were observed experimentally. The uncommon behavior of the even-order modes was examined precisely to explain the slit-width dependence. For structures with half-pitched displacement between the plates, extraordinarily strong transmission was observed experimentally, even...

Terahertz pulse generation from metal nanoparticle ink

Terahertz pulse generation from metallic nanostructures irradiated by femtosecond laser pulses is of interest because the conversion efficiency from laser pulses to terahertz waves is increased by the local field enhancement resulting from the plasmon oscillation. In this talk we present our recent study on terahertz generation from metal nanoparticle ink. We baked a silver nanoparticle ink spin-coated onto a glass coverslip in various temperatures. On the surface of the baked ink, bumpy nanostructures are spontaneously formed, and the average size of bumps depends on the baking temperature. These structures are expected to lead to local field enhancement and then large nonlinear polarizations on the surface. The baked ink was irradiated by the output of regeneratively amplified Ti:sapphire femtosecond laser at an incidence angle of 45°. Waveforms of generated terahertz pulses are detected by electro-optical sampling. The generation efficiency was high when the average diameter of bumps was around 100 nm, which is realized when the ink is baked in 205 to 235°C in our setup. One of our next research targets is terahertz wave generation from micro-patterned metallic nanoparticle ink. It is an advantage of the metal nanoparticle ink that by using inkjet printers one can fabricate various patterns with micrometer scales, in which terahertz waves have a resonance. Combination of microstructures made by a printer and nanostructure spontaneously formed in the baking process will provide us terahertz emitters with unique frequency characteristics.

Significant Volume Expansion as a Precursor to Ablation and Micropattern Formation in Phase Change Material Induced by Intense Terahertz Pulses

With rapid advances occurring in terahertz (THz) radiation generation techniques, the interaction between matter and intense THz fields has become an important research topic. Among different types of THz radiation sources, the free electron laser (FEL) is a promising experimental tool that is expected to pave the way for new forms of material processing, control of phase transitions, and serve as a test bench for extreme operating conditions in high-speed small-size electrical and magnetic devices through the exploitation of strong THz electrical and magnetic fields without the presence of interband electronic excitation. In the current work, we irradiated Ge2Sb2Te5 phase change memory material with intense THz pulse trains from an FEL and observed THz-induced surface changes due to damage as a precursor to ablation and the formation of fine surface undulations whose spatial period is comparable to or slightly smaller than the wavelength of the excitation THz pulses in the material. The formation of undulations as well as the fact that no significant thermal effect was observed below the volume expansion threshold suggests that THz-induced effects mainly contributed to the observed changes. To the best of our knowledge, this is the first experimental observation of THz-induced undulations (so-called “LIPSS”), which are of potential importance for laser material processing.

Layer thickness dependence of the terahertz emission based on spin current in ferromagnetic heterostructures

The emission with a bandwidth of 1.5 terahertz based on the spin current in the ferromagnetic heterostructure Co/Pt is demonstrated. The spin transient launched by the NIR femtosecond laser pulse in the Co/Pt is converted into the in-plane charge current due to the inverse spin Hall effect, which gives rise to the terahertz emission towards free space. The dependence of the terahertz emission on the Pt-layer thickness is investigated. To optimize the geometry structure of the new type of emitter, we developed the theoretical model by carefully analyzing the spin transport. Our model reveals the importance to take into account the interfacial spin loss. It can be used to analyze more complex heterostructures.

Enhanced detection sensitivity of terahertz magnetic nearfield with cryogenically-cooled magnetooptical sampling in terbium-gallium-garnet

Due to its efficient coupling with electron spins, the application of terahertz magnetic nearfield in metallic microstructures has been attracting attention. While paramagnetic materials that exhibit magneto-optical effect have been known to enable visualization of the terahertz magnetic fields (magneto-optical sampling), the low field-detection sensitivity has been setting a practical limit to the broader application of such a method. Here we propose and experimentally demonstrate that the terahertz magnetic nearfield-detection sensitivity of magneto-optical sampling with terbium-gallium-garnet crystal can be drastically enhanced by cooling the crystal down to cryogenic temperatures in accordance with Curies law. Our result paves the way for the efficient characterization of the terahertz magnetic nearfield in planer metamaterials.

Magnetically and electrically polarization-tunable THz emitter with integrated ferromagnetic heterostructure and large-birefringence liquid crystal

A magnetically and electrically polarization-tunable terahertz emitter that integrates a ferromagnetic heterostructure and large-birefringence liquid crystals is demonstrated. The heterostructure and the liquid crystal cell act as the broadband terahertz source and the phase retarder, respectively. The polarization state is switched between linear and circular by changing the direction of the external magnetic field. The phase retardation for frequencies higher than 1 THz is continuously adjustable over a range of π/2 by applying a low voltage. This compact, broadband, economical, and easy-to-regulate terahertz emitter can be widely used in polarization-sensitive research and engineering applications.

Insertion effects of natural dielectric between artificial dielectrics formed by metallic sub-wavelength slit arrays

We investigated the optical transmission properties of a metamaterial system in which a natural dielectric is inserted between metallic sub-wavelength slit arrays that behave as an artificial dielectric when the incident light wavelength is longer than the slit periodicity. Transmission spectra were measured using terahertz time-domain spectroscopy, and the experimental results were analyzed by simulations based on the finite-difference time-domain method. We revealed that the resonance characteristics are defined by the two diffraction-limit frequencies for the inner and outer openings of the slits, which are different for the insertion of the dielectric. We also determined further details on the blue-shift behavior specific to the even-order resonance modes by accounting for the refractive index of the inserted intermediate dielectric. In addition, we experimentally demonstrated that insertion of a dielectric having a high refraction index enhances the frequency repulsion at the anticrossing, i.e., the coupling strength, between the symmetric and antisymmetric optical modes. These experimental and theoretical results will be essential for understanding and developing applications for hybrid systems composed of dielectrics with both fixed and widely tunable refractive indices.We investigated the optical transmission properties of a metamaterial system in which a natural dielectric is inserted between metallic sub-wavelength slit arrays that behave as an artificial dielectric when the incident light wavelength is longer than the slit periodicity. Transmission spectra were measured using terahertz time-domain spectroscopy, and the experimental results were analyzed by simulations based on the finite-difference time-domain method. We revealed that the resonance characteristics are defined by the two diffraction-limit frequencies for the inner and outer openings of the slits, which are different for the insertion of the dielectric. We also determined further details on the blue-shift behavior specific to the even-order resonance modes by accounting for the refractive index of the inserted intermediate dielectric. In addition, we experimentally demonstrated that insertion of a dielectric having a high refraction index enhances the frequency repulsion at the anticrossing, i.e., the ...

Strong yellow emission of high-conductivity bulk ZnO single crystals irradiated with high-power gyrotron beam

We report the strong yellow emission of bulk ZnO single crystals irradiated with the high-power gyrotron beam. Hydrothermally grown bulk crystals with high conductivity are irradiated at room temperature with up to 60-W output of a sub-terahertz gyrotron wave source. During gyrotron irradiation, the high-conductivity crystals exhibit intense emissions with a peak of around 2 eV (600 nm) and a longer-wavelength tail. The sample temperatures were also elevated from room temperature to above 1000 K by irradiation. However, when heated up to 1250 K using a heater without irradiation, the ZnO crystals do not exhibit similar visible emissions. We then use the generalized Plancks radiation in non-equilibrium states as an explanation of our experimental observations. The emission peak intensity can be enhanced by the gyrotron-induced non-equilibrium states, and the emission peak position can be related to the Urbach energy. With high intensities in the visible wavelengths, the emissions of the irradiated crystal...