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Kresimir Humski

University of Zagreb

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Publication

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Journal of The Chemical Society-perkin Transactions 1 | 1989

Lack of secondary β-deuterium kinetic isotope effect in the solvolysis of 2-chloro-2,6,10-trimethyldodeca-6,10-diene. Indication of extended Π-participation

Stanko Borcic; Kresimir Humski; Vera Imper; Olga Kronja; Mirko Orlovic; Eugenio Polla

The title compound (3) with two deuteriated methyl groups attached to the reaction centre undergoes solvolysis without a kinetic isotope effect indicating participation of both double bonds.

Journal of The Chemical Society, Chemical Communications | 1986

Rate enhancements and secondary β-deuterium kinetic isotope effects as criteria of neighbouring group participation. Solvolysis of some tertiary alk-5-enyl chlorides

Mirko Orlovic; Kresimir Humski; Stanko Borcic; Eugenio Polla

Rate enhancements in solvolysis of several of the title compounds are small or zero but significantly reduced secondary β-deuterium kinetic isotope effects indicate participation of the double bond.

Journal of the American Chemical Society | 1970

THERMODYNAMIC AND KINETIC SECONDARY ISOTOPE EFFECTS IN THE COPE REARRANGEMENT.

Kresimir Humski; R. Malojcic; Stanko Borcic; Dionis E. Sunko

Journal of the American Chemical Society | 1991

Lack of a secondary .beta.-deuterium kinetic isotope effect in the solvolysis of 2-chloro-3-hydrosqualene. A case of extended .pi.-participation and indication of concerted biomimetic polycyclization

Olga Kronja; Mirko Orlovic; Kresimir Humski; Stanko Borcic

Journal of Organic Chemistry | 1986

Rates and alkyl group size in solvolysis of alkyl derivatives

Mirko Orlovic; Olga Kronja; Kresimir Humski; Stanko Borcic; Eugenio Polla

Journal of Organic Chemistry | 1998

Hammett ρ+ Values as Kinetic Evidence for the Concerted Biomimetic Bicyclization Mechanism

Ivica Malnar; Kresimir Humski; Olga Kronja

Croatica Chemica Acta | 1994

A Kinetic Approach to the Mechanism of Cationic Polyolefinic Cyclization. Simple and Extended π-Participation

Stanko Borcic; Olga Kronja; Kresimir Humski

Journal of Organic Chemistry | 1991

Solvolysis rates and .beta.-deuterium secondary kinetic isotope effects of some tertiary and secondary alk-5-enyl derivatives. Evidence for .pi.-participation

Mirko Orlovic; Stanko Borcic; Kresimir Humski; Olga Kronja; Vera Imper; Eugenio Polla; Veron J. Shiner

Journal of Organic Chemistry | 1979

n participation and secondary deuterium isotope effects in solvolysis of 1-aryl-4-methoxy-1-butyl chlorides. Are there two distinct k/sub. delta. / pathways

Ivan Mihel; Josip Sistek; Stanko Borcic; Kresimir Humski; Dionis E. Sunko

Croatica Chemica Acta | 1996

REACTIVITY OF SOME TERTIARY CHLORIDES WITH METHOXY AND OLEFINIC NEIGHBORING GROUP

Stanko Borcic; Olga Kronja; Kresimir Humski; S. Miletic

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Stanko Borcic

University of Zagreb

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Olga Kronja

University of Zagreb

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Dionis E. Sunko

University of Zagreb

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Eugenio Polla

University of Liège

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R. Malojčić

University of Zagreb

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Christopher S. Foote

University of California

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