Kristaps Rubenis

Studies of TiO2 Ceramics Structure after Thermal Treatment at Different Conditions

The present work describes results of investigation of structural characteristics of TiO2 ceramics, depending on temperature and thermal treatment conditions by using a variety of characterization techniques. TiO2 ceramics was prepared by extrusion method and developed as a material for electrodes for innovative water treatment technologies. It was shown that non-stoichiometric phase TiO1.95 was observed after thermal treatment of TiO2 ceramics under high vacuum conditions.

Staphylococcus Epidermidis and Pseudomonas Aeruginosa Adhesion Intensity on a TiO2 Ceramic in an in Vitro Study

Extrusion is a perspective forming technology for obtaining objects with certain profile, important for the TiO2 application as biomaterial. Extruded samples were calcinated at 1100 °C, thermally treated in different atmospheres: at 1450 °C in air and at 1300 °C in vacuum. An approach was made to examine the adhesion and colonization intensity of Staphylococcus epidermidis and Pseudomonas aeruginosa on TiO2 ceramic in vitro. It was found that Ps.aeruginosa demonstrated higher adhesion and colonization intensity as S.epidermidis and TiO2 samples treated in vacuum demonstrated higher attachment of microorganisms as TiO2 samples treated in air. It was supposed that surface charge promoted the bacterial adhesion on the vacuum treated samples.

Investigation of TiO2 Ceramic Surface Conductivity Using Conductive Atomic Force Microscopy

Dense TiO2 (rutile) ceramic samples were prepared by sintering compacts of titanium dioxide anatase powder at 1500 °C for 5h. Sintered samples were polished and annealed in vacuum at 1000 °C for 1h. Structural properties of the samples were studied by X-ray diffraction, polarized light and scanning electron microscopy. The surface topography and local electrical conductivity of the samples were investigated by atomic force microscopy technique under atmospheric conditions. Enhanced electrical conductivity was observed at grain boundaries while the polished, vacuum annealed grains surface showed non-homogeneous conductivity.

Effect of Various Additives and Aeration on the Properties of Lightweight Concrete

In the present study the effect of various additives (silica sand, silica fume, zeolite and cenospheres) as well as the aeration on the properties (consistency, density, compressive and bending strength) of lightweight concrete was studied. Density, compressive and bending strength of the lightweight concrete were substantially reduced by replacing silica sand with censopheres or by adding air entraining agent to the grout used for the preparation of the samples. Silica fume and zeolite admixture improved mechanical properties of the samples. Specific compressive strength of the cenospheres containing samples is comparable or even higher than the ones made of the mixes without the cenospheres.

Hydrothermal Synthesis of SnO2 Structures with Various Morphologies in the Presence of Different Alcoholic Co-Solvents

The addition of certain co-solvents to the hydrothermal synthesis starting solution can greatly alter morphology and enhance different morphology dependent properties of the synthesized material. While ethanol is the most common co-solvent used for the synthesis of various SnO2 nano/microstructures by hydro/solvothermal process, it is not clear how the use of some other alcoholic co-solvents (for example, methanol or isopropanol) affect morphology and properties of SnO2, especially if synthesis is done under similar conditions as in the case of ethanol co-solvent. In the present study, we investigated how the use of various alcoholic co-solvents (methanol, ethanol, 2-propanol, ethylene glycol and glycerol) affects crystal structure, morphology and specific surface area of the hydrothermally synthesized SnO2. Additionally, sensitivity towards 100 ppm ethanol of the synthesized materials was tested. The formation of nanoparticles, rod-cluster structures and spherical SnO2 structures were observed depending on the alcoholic co-solvent used. The highest sensitivity (~22 at 250 °C) showed the material that was synthesized in the presence of ethanol co-solvent.

The influence of thermal treatment conditions on the properties of TiO2 ceramics

The influence of thermal treatment conditions on titanium dioxide ceramics phase transformation, microstructure, physico-mechanical and electrical properties was studied. TiO2 ceramic was prepared using extrusion technology and thermal treatment in air and subsequent annealing under high vacuum conditions. It has been observed that intense TiO2 ceramic mass sintering occurs over the temperature ranging from 950 °C to 1100 °C. It is accompanied by crystallographic modification change from anatase to rutile. Ceramic sample annealing in vacuum causes formation of nonstoichiometric titanium oxide ceramics and as a result electrical conductivity of the material significantly increases. Using extrusion process relatively dense and mechanically resistant ceramic material can be obtained that can be used in different technological processes.

Effect of Shaping Method and Heat Treatment on Microstructure and Thermoelectric Properties of Titanium Dioxide

The TiO2 samples were obtained by two different shaping methods: cold isostatic pressing and cold extrusion, sintered in air at 1373 K, 1573 K, 1773 K and annealed under vacuum at 1373 K. Differences in density, microstructure and thermoelectric properties were observed between the samples depending on the shaping method used. With increase in sintering temperature the electrical conductivity of all samples increased while the Seebeck coefficient decreased. Great microstructural differences were observed between the surface and bulk of the samples made by each of the shaping techniques. It was found that microstructural differences between surface and bulk of the samples affect their thermoelectric properties.