Kristina Šarić

Biogenesis of secondary mycogenic minerals related to wall paintings deterioration process

Present study addresses potential of fungal strains, isolated from deteriorated mural paintings and surrounding air environment of the Church of the Holy Ascension in Veliki Krčimir (Serbia), to precipitate mycogenic minerals, when cultivated on agarized B4 medium. Utilizing culture-based isolation methods, 38 filamentous fungi were obtained in total, 23 from mural paintings and 15 from air, respectively, mainly ascomycetes, while Bjerkandera adusta and Thanatephorus cucumeris were only basidiomycetes. A total of 31 of 38 fungal isolates, more than 80%, were able to form minerals of different morphologies and variable size, determined via SEM-EDS and XRPD, to be either calcite or calcite and weddellite association. Among screened fungi, all Penicillium, Chaetomium and Cladosporium isolates, as well as most of the Aspergillus isolates (8/11) precipitated minerals, whereas cultures of Bionectria, Bjerkandera, and Seimatosporium isolates lacked any observable crystal forms. With the exception of two Alternaria alternata strains, no apparent disparity in potential to precipitate minerals in general, or form particular crystal phase was documented among the air and mural paintings isolates. Possible mechanisms of fungal mineralization of calcite and weddellite are further proposed. In addition to providing experimental evidence for fungal induced precipitation of oxalate and carbonate minerals, presented data suggest that fungal activity could be an important factor in a weathering process affecting cultural heritage exhibited and stored in inadequate conditions. Implementation of B4 plate assay for screening of mineralization potential of the isolated fungi could be used to assess biodegradative risk mycobiota pose to the mural paintings, so appropriate conservation measures may be utilized.

The Upper Cretaceous ophiolite of North Kozara – remnants of an anomalous mid-ocean ridge segment of the Neotethys?

Abstract This study sheds new light on the origin and evolution of the north Kozara ophiolite, a part of the Sava-Vardar Zone. The Sava-Vardar Zone is regarded as a relict of the youngest Tethyan realm in the present-day Balkan Peninsula. The north Kozara ophiolite consists of a bimodal igneous association comprising isotropic to layered gabbros, diabase dykes and basaltic pillow lavas (basic suite), as well as relicts of predominantly rhyodacite lava flows and analogous shallow intrusions (acid suite). The rocks of the basic suite show relatively flat to moderately light-REE enriched patterns with no or weak negative Eu-anomaly, whereas those of the acid suite exhibit steeper patterns and have distinctively more pronounced Eu- and Sr- negative anomalies. Compared to the known intra-ophiolitic granitoids from the Eastern Vardar Zone, the acid suite rocks are most similar to those considered to be oceanic plagiogranites. The new geochemical data suggest that the basic suite rocks are similar to enriched mid-ocean ridge basalts. The geochemical characteristics of the acid suite rocks indicate that their primary magmas most probably originated via partial melting of gabbros from the lower oceanic crust. Our study confirms the oceanic nature of the north Kozara Mts rock assemblage, and suggests that it may have formed within an anomalous ridge setting similar to present-day Iceland.

The Rudnik Mts. volcano-intrusive complex (central Serbia): An example of how magmatism controls metallogeny

This study reports and discusses new radiometric ages, petrographical and volcanological observations and whole rock geochemical data of the rocks of the Rudnik Mts. volcano-intrusive complex. The complex hosts a Pb-Zn-Ag deposit and belongs to the Serbo-Macedonian metallogenetic belt. Two distinct igneous events are distignuished. The first occurred >30 Ma and was mainly characterized by extrusive and shallow intrusive dacites and andesites and was unrelated to mineralization. The second igneous event occurred <23 Ma and was highly heterogeneous in terms of volcanic products and petrographic varieties, but with predominance of quartzlatites. The dacite-andesites (first event) and the quartzlatites (second event) are geochemically similar and display a calc-alkaline affinity and highly incompatible element enriched patterns on spider diagrams, but the younger quartzlatites are richer in K2O, Rb and Ba and poorer in Sr. This is taken as evidence that mixing between an ultrapotassic lamprophyre/lamproite magma and an acid calc-alkaline (dacite-like) magma was essential petrogenetic processes during the second event. The proposed simplified volcanological model suggests that this mixing was responsible for triggering strongly explosive volcanic activity as well as for providing conditions for active hydrothermal and mineralization processes. The observed link between a specific magmatic phase and ore deposit formation can be a general phennomenon in the Balkans, and must be addressed by further and more advanced studies.