Krzysztof Dragon

Groundwater nitrate pollution in the recharge zone of a regional Quaternary flow system (Wielkopolska region, Poland)

The present study examines the behaviour of nitrate in the recharge zone of a regional Quaternary flow system. The presence of contaminated groundwater with high nitrate content in the shallow part of the flow system was documented. Tritium analyses confirmed that these contaminants can migrate downward. A high downward gradient exists in the study area, extending into the regions of groundwater extraction. In the unconfined part of the flow system, which is the most vulnerable to pollution, a high concentration of nitrate was found to occur at great depth. However, denitrification processes limit nitrate migration. As a result, in the deeper parts of the flow system in regions under confined conditions, an absence of nitrate was observed, and a higher sulphate concentration and total hardness were evident. The denitrification was also confirmed by the existence of a high gaseous N2 concentration. It was documented that denitrification occurs in both the confined and unconfined parts of the flow system, but the potential for denitrification is higher in the confined parts (leading to the disappearance of nitrate in deep aquifers). Autotrophic denitrification supported by sulphide compounds was indicated as the dominant denitrification process.

Identification of groundwater chemistry origins in a regional aquifer system (Wielkopolska region, Poland)

This paper describes the origin of the groundwater chemistry in the regional aquifer located in the Wielkopolska region of western Poland. Factor analysis was used for the identification of geochemical processes that influence the groundwater chemistry. Two groups of processes were identified: anthropogenic (i.e., caused by groundwater contamination) and geogenic (i.e., caused by natural geochemical processes). Based on a background of the natural variations in the groundwater chemistry, the effect of upward groundwater flow from the deep part of the flow system on the groundwater chemistry was identified. The boron concentrations and isotope data allowed for the identification of zones of relatively old groundwater. The spatial distribution of fluoride concentrations allowed for the identification of recharge zones. This study demonstrates the general usefulness of groundwater chemistry differentiation for supporting identification of groundwater flow patterns. It also demonstrates the importance of using chemical data to evaluate the connectivity between different aquifers. These interpretations can be used for better management of water resources on a regional scale.

The changes of groundwater chemistry of semi-confined buried valley aquifer during one decade of water exploitation

This article presents the analysis of the temporal changes in water chemistry in a semi-confined aquifer (Wielkopolska Buried Valley aquifer, Poland) during one decade of water exploitation. It is shown that the groundwater contamination, as documented in a previous work, still persists and has lead to steady groundwater quality deterioration. The most intensive changes in water chemistry due to contamination are observed in the regions recognized earlier as the most vulnerable parts of the aquifer. The influence of contamination is effective despite implementation of groundwater protection activities. The travails of groundwater quality protection of the confined or semi-confined aquifers were accented.

Hydrogeological investigations of river bed clogging at a river bank filtration site along the River Warta, Poland

Abstract River bank filtration (RBF) is a system that enriches groundwater resources by induced infiltration of river water to an aquifer. Problematic during operation of RBF systems is the deterioration of infiltration effectiveness caused by river bed clogging. This situation was observed in the Krajkowo well field which supplies fresh water to the city of Poznań (Poland) during and after the long hydrological drought between the years 1989 and 1992. The present note discusses results of specific hydrogeological research which included drilling of a net of boreholes to a depth of 10 m below river bottom (for sediment sampling as well as for hydrogeological measurements), analyses of grain size distribution and relative density studies. The results obtained have allowed the recognition of the origin of the clogging processes, as well as the documentation of the clogged parts of the river bottom designated for unclogging activities.

Nitrate pollution in the Warta River (Poland) between 1958 and 2016: trends and causes

The article presents analyses of long-term water quality data from the Warta River between 1958 and 2016. A clear increasing trend in nitrate concentrations was observed from 1958 to the early 1990s. This trend was mainly related to the increasing use of fertilizers in Poland in this period. Then, after the early 1990s, a slow decreasing trend related to improvements in water and sewage management and more rational fertilizer use was observed after political and economic changes in Poland. The influence of long-term hydrological droughts on nitrate concentrations was also investigated. Sharp increases in the nitrate concentration in surface water were related to the accumulation of contaminants in the soil and aeration zone during drought periods and the subsequent transport of these contaminants to groundwater and surface water via recharge infiltration after each drought period. The presented results highlight the importance of surface water–groundwater interactions and suggest that groundwater protection in an entire catchment area is essential for surface water quality protection.