Krzysztof Szopa

The origin of magmatic layering in the High Tatra granite, Central Western Carpathians – implications for the formation of granitoid plutons

The High Tatra granite intrusion is an example of a Variscan syn-tectonic, tongue-shaped intrusion. In some portions of the intrusion, structures occur which appear to be of sedimentary origin. These include structures similar to graded bedding, cross-bedding, troughs and flame structures, K-feldspar-rich cumulates and magmatic breccias. Formation of these structures might be related to changing magma properties, including crystal fraction, development of a crystal mush and a decrease in magma viscosity, stimulated by influx of mafic magma and high volatile content. The suggested processes in operation are: gravity-controlled separation, magma flow segregation, deposition on the magma-chamber floor, filter pressing and density currents stimulated by tectonic activity.%The formation of the sedimentary structures was also aided by the presence of large numbers of xenoliths that acted as a heat sink and influenced the thermal field in the intrusion, stimulating rapid cooling and crystal nucleation. Sinking xenoliths deformed the layering and, to some extent, protected the unconsolidated crystal mush from erosion by magma flowing past.%Areas with well-developed sedimentary magmatic structures can be viewed as having involved magma rich in crystals locally forming closely-packed networks from which residual melt was extracted by filter pressing, and preserved in leucocratic pods and dykes. Interleaved, non-layered granite may be interpreted to have formed from the magma with initially low crystal fractions.%It is suggested that the intrusion was formed from numerous magma injections representing different stages in the mixing and mingling of felsic and mafic sources. It solidified by gravitation-driven crystal accumulation and flow sorting on the magma chamber floor and on the surfaces of large numbers of xenoliths. Shear stress acting during intrusion might have influenced the formation of magmatic structures.

Composition and element mobilization in pyrometallurgical slags from the Orzeł Biały smelting plant in the Bytom–Piekary Śląskie area, Poland

Abstract Wastes accumulated at Piekary Śląskie, Poland, are the result of 150 years of continuous working of the Orzel Bialy smelting plant. Slags are composed of: oxides (spinel, hematite, zincite); silicates and aluminosilicates (olivine, monticellite-kirschteinite, titanite, merwinite, pyroxene, melilite, feldspars: plagioclases and plumbean K-feldspar, nepheline, kalsilite, leucite); sulfides (pyrrhotite, rudashevs- kyite, galena), metallic phases (pure iron and iron-arsenic mixture) and secondary phases (gypsum, rapidcreekite, apatite). Interstices between the crystalline phases are filled by glass, concentrating toxic and potentially harmful elements, e.g. up to 53.22 wt.% PbO. The sequence of crystallization of primary phases depended on the local variability of oxygen fugacity and degree of calcination, while the texture type resulted from the cooling time and partial pressure of volatiles. Suggested crystallization temperatures are in the range of 1200 - 1500°C. Bulk chemical analyses show that the slags are composed mainly of SiO2, Fe2O3, MgO and CaO. Among the potentially harmful elements, Zn is the most common, reaching up to 5.93 wt.%, Pb is present in concentrations up to 3.9 wt.% and As in weathered samples exceeds 1 wt.%. Leaching tests of these elements confirms As mobility as Zn and Pb are preferably leached from fresh slags, while As is present in greater amounts in leachate from weathered slag samples. The documented amounts of As, Zn, Pb and their mobility in slags produce an environmental risk, as this material is currently used widely for commercial purposes.

LA-ICP-MS U-Pb apatite dating of Lower Cretaceous rocks from teschenite-picrite association in the Silesian Unit (southern Poland)

Abstract The main products of volcanic activity in the teschenite-picrite association (TPA) are shallow, sub-volcanic intrusions, which predominate over extrusive volcanic rocks. They comprise a wide range of intrusive rocks which fall into two main groups: alkaline (teschenite, picrite, syenite, lamprophyre) and subalkaline (dolerite). Previous 40Ar/39Ar and 40K/40Ar dating of these rocks in the Polish Outer Western Carpathians, performed on kaersutite, sub-silicic diopside, phlogopite/biotite as well as on whole rock samples has yielded Early Cretaceous ages. Fluorapatite crystals were dated by the U-Pb LA-ICP-MS method to obtain the age of selected magmatic rocks (teschenite, lamprophyre) from the Cieszyn igneous province. Apatite-bearing samples from Boguszowice, Puńców and Lipowa yield U-Pb ages of 103± 20 Ma, 119.6 ± 3.2 Ma and 126.5 ± 8.8 Ma, respectively. The weighted average age for all three samples is 117.8 ± 7.3 Ma (MSWD = 2.7). The considerably smaller dispersion in the apatite ages compared to the published amphibole and biotite ages is probably caused by the U-Pb system in apatite being less susceptible to the effects of hydrothermal alternation than the 40Ar/39Ar or 40K/40Ar system in amphibole and/or biotite. Available data suggest that volcanic activity in the Silesian Basin took place from 128 to 103 Ma with the the main magmatic phase constrained to 128-120 Ma.

The Lilliput effect in crinoids at the end of the Oceanic Anoxic Event 2: a Case study from Poland

Abstract. The Cretaceous Period (145–66 Ma) consisted of several oceanic anoxic events (120–80 Ma), stimulated by global greenhouse effects. The Oceanic Anoxic Event 2 (OAE2) occurred worldwide from the late Cenomanian to the early-middle Turonian, causing a significant faunal turnover, mostly in marine biota, pushing some species to the brink of extinction. Some organisms also underwent morphological changes, including reduction in size. This anoxic event drove other changes—e.g., in habitats or strategy of life. We show that stalkless crinoids (comatulids) from the Turonian of Poland adapted to unfavorable environmental conditions by reducing their body size. Furthermore, at the moment when environmental factors became favorable again, these crinoids regained their regular (pre-event) size. This phenomenon likely illustrates the so-called dwarfing mode of the Lilliput effect.

Petrogenesis of kyanite-quartz segregations in mica schists of the Western Tatra Mountains (Slovakia)

Abstract In the Tatra Mountains (Slovakia) metamorphic complex, kyanite-quartz segregations with biotite-rich selvage occur in mylonitized mica schists. In this paper, the problem of fluid flow and aluminium mobility during the uplift of the crystalline massif, and the position of the segregations in the history of Western Tatra metamorphic complex, is adressed. The reaction Alm + Rt ➔ Ilm + Ky + Qtz is considered to be the result of a pressure drop from above to below 9 kbar. Ti-in-biotite geothermometry shows the temperature range to be 579-639°C that is related to heating and decompression associated with granite intrusion. Major-element mass-balance calculations show that Al remained stable in the selvage + segregation system whereas other elements (e.g. Cr, HFSE) were mobilized. The kyanite-quartz segregations formed from local fluids generated during dehydration of the metapelitic rocks during uplift. The main mechanism was likely diffusion-driven mass-transfer into extension-related cracks.

Anti-predator adaptations in a great scallop (Pecten maximus) – a palaeontological perspective

Abstract Shelly fauna was exposed to increased pressure exerted by shell-crushing durophagous predators during the so-called Mesozoic Marine Revolution that was initiated in the Triassic. As a result of evolutionary ‘arms race’, prey animals such as bivalves, developed many adaptations to reduce predation pressure (e.g. they changed lifestyle and shell morphology in order to increase their mechanical strength). For instance, it was suggested that Pectinidae had acquired the ability to actively swim to avoid predator attack during the early Mesozoic. However, pectinids are also know to have a specific shell microstructure that may effectively protect them against predators. For instance, we highlight that the shells of some recent pectinid species (e.g. Pecten maximus) that display cross-lamellar structures in the middle part playing a significant role in the energy dissipation, improve the mechanical strength. In contrast, the outer layers of these bivalves are highly porous, which allow them to swim more efficiently by reducing the shell weight. Pectinids are thus perfect examples of animals optimising their skeletons for several functions. We suggest that such an optimisation of their skeletons for multiple functions likely occurred as a results of increased predation pressure during the so-called Mesozoic Marine Revolution.

Megacrysts of kyanite from Baranec Mt., Western Tatra Mountains, Slovakia

Abstract Large crystals of kyanite (<15 cm in size) occur in quartz segregations in Paleozoic gneissses on Baranec Mt., Western Tatra Mountains, northern Slovakia. Blue kyanite crystals coexist with quartz and plagioclase. The kyanite contains inclusions of apatite, monazite. gamet, rutile and biotite and overgrowths of retrograde sillimanite. muscovite and biotite. The kyanite crystals are the largest found up to now in the Tatra crystalline massif or in the other Western Carpathians crystalline cores. Kyanite. with the co-existing mineral assemblage, is indicative of a HP stage duiing Hercynian metamorphism of the Western Tatra Mountains.

Morphological diversity of microstructures occurring in selected recent bivalve shells and their ecological implications

Abstract Environmental adaptation of molluscs during evolution has led to form biomineral exoskeleton – shell. The main compound of their shells is calcium carbonate, which is represented by calcite and/or aragonite. The mineral part, together with the biopolymer matrix, forms many types of microstructures, which are differ in texture. Different types of internal shell microstructures are characteristic for some bivalve groups. Studied bivalve species (freshwater species – duck mussel (Anodonta anatina Linnaeus, 1758) and marine species – common cockle (Cerastoderma edule Linnaeus, 1758), lyrate Asiatic hard clam (Meretrix lyrata Sowerby II, 1851) and blue mussel (Mytilus edulis Linnaeus, 1758)) from different locations and environmental conditions, show that the internal shell microstructure with the shell morphology and thickness have critical impact to the ability to survive in changing environment and also to the probability of surviving predator attack. Moreover, more detailed studies on molluscan structures might be responsible for create mechanically resistant nanomaterials.

Preliminary investigation of mineralogy and chemistry of peats from the Kietrz site, southern Poland

Abstract Peat bog deposits provide a very important record of past environmental conditions, preserving biotic and abiotic processes that occurred in the vicinity of the bog. In this study, we examined three peat bog profiles from Kietrz, located in the micro-region of the Głubczycki Plateau, southern Poland. The objective of this study was to determine the type of peat occurring in this area, through examination of its mineral composition, and evaluation of the total carbon and total sulphur content. In addition, we measured peat reaction (pH) and identified floral and faunal components occurring within the peat deposits. The peat comprises primarily of fragments of fossilized plant and mollusk remains, as well as minerals (calcium sulphates, calcium carbonates, and pyrites). Additionally, an assemblage of iron oxides/hydroxides, Kfeldspar, apatite, zircon, and quartz grains was identified. A neutral and/or light alkalinity was recorded for the peat deposits, but an increase in acidity (pH) with increasing depth through each peat profile was also recorded. We observed a positive correlation between the pH and chemical composition of deposits, where a significant presence of calcite is associated with higher reaction (higher pH), whilst a lower pH is characteristic for sediments where carbonates are rare. The recognized species of mollusks are typical of shallow, fresh-water stagnant reservoirs with a high fluctuation of water level.

Cu-Zn slags from Røros (Norway): a case study of rapid cooling and crystal nucleation

Abstract The mining town of Røros located in central Norway was established in 1644 and it is known of historical mining industry related to copper. Røros was designated as an UNESCO World Heritage Site in 1980 on the base of mining culture represented by, e.g., unique wooden architecture. Slag pieces are composed of three parts differing in glass to crystallites ratio. Røros slags are composed of olivine- and pyroxene- group minerals accompanied by sulphides, with glass in the interstices. Temperature gradient and volatiles content were determined as the main factor influencing crystallization process in this material