Kyoungsik Yu

Three-dimensional nanopillar-array photovoltaics on low-cost and flexible substrates

Solar energy represents one of the most abundant and yet least harvested sources of renewable energy. In recent years, tremendous progress has been made in developing photovoltaics that can be potentially mass deployed. Of particular interest to cost-effective solar cells is to use novel device structures and materials processing for enabling acceptable efficiencies. In this regard, here, we report the direct growth of highly regular, single-crystalline nanopillar arrays of optically active semiconductors on aluminium substrates that are then configured as solar-cell modules. As an example, we demonstrate a photovoltaic structure that incorporates three-dimensional, single-crystalline n-CdS nanopillars, embedded in polycrystalline thin films of p-CdTe, to enable high absorption of light and efficient collection of the carriers. Through experiments and modelling, we demonstrate the potency of this approach for enabling highly versatile solar modules on both rigid and flexible substrates with enhanced carrier collection efficiency arising from the geometric configuration of the nanopillars.

Scaling internet routers using optics

Routers built around a single-stage crossbar and a centralized scheduler do not scale, and (in practice) do not provide the throughput guarantees that network operators need to make efficient use of their expensive long-haul links. In this paper we consider how optics can be used to scale capacity and reduce power in a router. We start with the promising load-balanced switch architecture proposed by C-S. Chang. This approach eliminates the scheduler, is scalable, and guarantees 100% throughput for a broad class of traffic. But several problems need to be solved to make this architecture practical: (1) Packets can be mis-sequenced, (2) Pathological periodic traffic patterns can make throughput arbitrarily small, (3) The architecture requires a rapidly configuring switch fabric, and (4) It does not work when linecards are missing or have failed. In this paper we solve each problem in turn, and describe new architectures that include our solutions. We motivate our work by designing a 100Tb/s packet-switched router arranged as 640 linecards, each operating at 160Gb/s. We describe two different implementations based on technology available within the next three years.

Ordered arrays of dual-diameter nanopillars for maximized optical absorption.

Optical properties of highly ordered Ge nanopillar arrays are tuned through shape and geometry control to achieve the optimal absorption efficiency. Increasing the Ge materials filling ratio is shown to increase the reflectance while simultaneously decreasing the transmittance, with the absorbance showing a strong diameter dependency. To enhance the broad band optical absorption efficiency, a novel dual-diameter nanopillar structure is presented, with a small diameter tip for minimal reflectance and a large diameter base for maximal effective absorption coefficient. The enabled single-crystalline absorber material with a thickness of only 2 μm exhibits an impressive absorbance of ∼99% over wavelengths, λ = 300-900 nm. These results enable a viable and convenient route toward shape-controlled nanopillar-based high-performance photonic devices.

Subwavelength metal-optic semiconductor nanopatch lasers

We report on near infrared semiconductor nanopatch lasers with subwavelength-scale physical dimensions (0.019 cubic wavelengths) and effective mode volumes (0.0017 cubic wavelengths). We observe lasing in the two most fundamental optical modes which resemble oscillating electrical and magnetic dipoles. The ultra-small laser volume is achieved with the presence of nanoscale metal patches which suppress electromagnetic radiation into free-space and convert a leaky cavity into a highly-confined subwavelength optical resonator. Such ultra-small lasers with metallodielectric cavities will enable broad applications in data storage, biological sensing, and on-chip optical communication.

Optofluidic maskless lithography system for real-time synthesis of photopolymerized microstructures in microfluidic channels

The authors propose an optofluidic maskless lithography technique that can dynamically synthesize free-floating polymeric microstructures inside microfluidic channels by selectively polymerizing photocurable resin with high-speed two-dimensional spatial light modulators. The combination of programable optical projection and microfluidic devices allows one to precisely control the timing and location of the photopolymerization process for microstructure fabrication. Real-time generation of microparticles with various shapes, sizes, ordering, and material contents are experimentally demonstrated. Long polymeric structures of which size is not limited by the exposure field of view can also be fabricated.

Efficient photon capturing with ordered three-dimensional nanowell arrays.

Unique light-matter interaction at nanophotonic regime can be harnessed for designing efficient photonic and optoelectronic devices such as solar cells, lasers, and photodetectors. In this work, periodic photon nanowells are fabricated with a low-cost and scalable approach, followed by systematic investigations of their photon capturing properties combining experiments and simulations. Intriguingly, it is found that a proper periodicity greatly facilitates photon capturing process in the nanowells, primarily owing to optical diffraction. Meanwhile, the nanoengineered morphology renders the nanostructures with a broad-band efficient light absorption. The findings in this work can be utilized to implement a new type of nanostructure-based solar cells. Also, the methodology applied in this work can be generalized to rational design of other types of efficient photon-harvesting devices.

Effect of vacuum arc deposition parameters on the properties of amorphous carbon thin films

Abstract Hard and smooth films of amorphous carbon with thicknesses in the nanometer to micrometer range were formed on silicon substrates using a vacuum arc deposition technique. In this technique, a carbon plasma is generated by a vacuum arc plasma source coupled with a magnetic filter for obtaining macroparticle-free amorphous carbon films. The influence of the substrate bias voltage and pulsed bias duty cycle on the film properties was investigated. A significant enhancement of the film quality and adhesion was achieved by applying a negative pulsed bias voltage to the substrate. Nanoindentation, pin-on-disk tribotesting, surface profilometry, Rutherford backscattering spectroscopy, elastic recoil spectroscopy, and Raman spectroscopy were used to characterize the properties and structure of the amorphous carbon films. It was found that the hardest films with the highest density and lowest friction coefficient were obtained at - 100 V pulsed bias voltage, whereas higher pulsed bias voltages improved the film adhesion and reduced the internal stress. For -100 V pulsed bias voltage, the maximum film hardness was achieved with a 50% duty cycle, and was significantly higher than that produced with a d.c. bias.

Black Ge Based on Crystalline/Amorphous Core/Shell Nanoneedle Arrays

Direct growth of black Ge on low-temperature substrates, including plastics and rubber is reported. The material is based on highly dense, crystalline/amorphous core/shell Ge nanoneedle arrays with ultrasharp tips ( approximately 4 nm) enabled by the Ni catalyzed vapor-solid-solid growth process. Ge nanoneedle arrays exhibit remarkable optical properties. Specifically, minimal optical reflectance (<1%) is observed, even for high angles of incidence ( approximately 75 degrees ) and for relatively short nanoneedle lengths ( approximately 1 mum). Furthermore, the material exhibits high optical absorption efficiency with an effective band gap of approximately 1 eV. The reported black Ge could potentially have important practical implications for efficient photovoltaic and photodetector applications on nonconventional substrates.

Wavelength-time spreading optical CDMA system using wavelength multiplexers and mirrored fiber delay lines

We propose a two-dimensional (2-D) code family and transmitter/receiver structures for incoherent multi-wavelength-time spread optical CDMA networks. The combination of metal-coated reflection delay lines and arrayed waveguide gratings (AWG) gives the proposed optical coder/decoder much enhanced flexibility in accommodating different code sets. Successful encoding/decoding has been demonstrated on signals up to 3-GHz time-chip rate with 4/spl times/15 code words.

NanoPen: Dynamic, Low-Power, and Light-Actuated Patterning of Nanoparticles

We introduce NanoPen, a novel technique for low optical power intensity, flexible, real-time reconfigurable, and large-scale light-actuated patterning of single or multiple nanoparticles, such as metallic spherical nanocrystals, and one-dimensional nanostructures, such as carbon nanotubes. NanoPen is capable of dynamically patterning nanoparticles over an area of thousands of square micrometers with light intensities <10 W/cm(2) (using a commercial projector) within seconds. Various arbitrary nanoparticle patterns and arrays (including a 10 x 10 array covering a 0.025 mm(2) area) are demonstrated using this capability. One application of NanoPen is presented through the creation of surface-enhanced Raman spectroscopy hot-spots by patterning gold nanoparticles of 90 nm diameter with enhancement factors exceeding 10(7) and picomolar concentration sensitivities.