L.F. Bobadilla
Spanish National Research Council
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Publication
Featured researches published by L.F. Bobadilla.
Chemsuschem | 2017
L.F. Bobadilla; Victoria Garcilaso; M.A. Centeno; J.A. Odriozola
In this work, the reforming of model biogas was investigated on a Rh/MgAl2 O4 catalyst. In situ transient and steady-state diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) measurements were used to gain insight into the reaction mechanism involved in the activation of CH4 and CO2 . It was found that the reaction proceeds through of an initial pathway in which methane and CO2 are both dissociated on Rh metallic sites and additionally a bifunctional mechanism in which methane is activated on Rh sites and CO2 is activated on the basic sites of the support surface via a formate intermediate by H-assisted CO2 decomposition. Moreover, this plausible mechanism is able to explain why the observed apparent activation energy of CO2 is much lower than that of CH4 . Our results suggest that CO2 dissociation facilitates CH4 activation, because the oxygen-adsorbed species formed in the decomposition of CO2 are capable of reacting with the CHx species derived from methane decomposition.
Applied Catalysis A-general | 2011
Anna Penkova; L.F. Bobadilla; Svetlana Ivanova; M.I. Domínguez; F. Romero-Sarria; Anne-Cécile Roger; M.A. Centeno; J.A. Odriozola
Applied Catalysis B-environmental | 2010
A. Navajas; I. Campo; G. Arzamendi; Willinton Y. Hernández; L.F. Bobadilla; M.A. Centeno; J.A. Odriozola; L.M. Gandía
Applied Catalysis A-general | 2015
L.F. Bobadilla; Anna Penkova; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola
International Journal of Hydrogen Energy | 2013
L.F. Bobadilla; S. Palma; Svetlana Ivanova; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola
Applied Catalysis B-environmental | 2014
S. Palma; L.F. Bobadilla; A. Corrales; Svetlana Ivanova; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola
International Journal of Hydrogen Energy | 2016
L.F. Bobadilla; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola
Journal of CO 2 Utilization | 2016
L.F. Bobadilla; José M. Riesco-García; Germán Penelas-Pérez; Atsushi Urakawa
Chemical Engineering Journal | 2016
L.F. Bobadilla; V. Blay; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola
Applied Catalysis B-environmental | 2018
Nuria García-Moncada; L.F. Bobadilla; R. Poyato; C. López-Cartes; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola