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Featured researches published by L.F. Bobadilla.


Chemsuschem | 2017

Monitoring the reaction mechanism in model biogas reforming by in situ transient and steady-state DRIFTS measurements

L.F. Bobadilla; Victoria Garcilaso; M.A. Centeno; J.A. Odriozola

In this work, the reforming of model biogas was investigated on a Rh/MgAl2 O4 catalyst. In situ transient and steady-state diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) measurements were used to gain insight into the reaction mechanism involved in the activation of CH4 and CO2 . It was found that the reaction proceeds through of an initial pathway in which methane and CO2 are both dissociated on Rh metallic sites and additionally a bifunctional mechanism in which methane is activated on Rh sites and CO2 is activated on the basic sites of the support surface via a formate intermediate by H-assisted CO2 decomposition. Moreover, this plausible mechanism is able to explain why the observed apparent activation energy of CO2 is much lower than that of CH4 . Our results suggest that CO2 dissociation facilitates CH4 activation, because the oxygen-adsorbed species formed in the decomposition of CO2 are capable of reacting with the CHx species derived from methane decomposition.


Applied Catalysis A-general | 2011

Hydrogen production by methanol steam reforming on NiSn/MgO―Al2O3 catalysts: The role of MgO addition

Anna Penkova; L.F. Bobadilla; Svetlana Ivanova; M.I. Domínguez; F. Romero-Sarria; Anne-Cécile Roger; M.A. Centeno; J.A. Odriozola


Applied Catalysis B-environmental | 2010

Synthesis of biodiesel from the methanolysis of sunflower oil using PURAL® Mg-Al hydrotalcites as catalyst precursors

A. Navajas; I. Campo; G. Arzamendi; Willinton Y. Hernández; L.F. Bobadilla; M.A. Centeno; J.A. Odriozola; L.M. Gandía


Applied Catalysis A-general | 2015

Glycerol steam reforming on bimetallic NiSn/CeO2–MgO–Al2O3 catalysts: Influence of the support, reaction parameters and deactivation/regeneration processes

L.F. Bobadilla; Anna Penkova; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola


International Journal of Hydrogen Energy | 2013

Steam reforming of methanol over supported Ni and Ni–Sn nanoparticles

L.F. Bobadilla; S. Palma; Svetlana Ivanova; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola


Applied Catalysis B-environmental | 2014

Effect of gold on a NiLaO3 perovskite catalyst for methane steam reforming

S. Palma; L.F. Bobadilla; A. Corrales; Svetlana Ivanova; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola


International Journal of Hydrogen Energy | 2016

Promoting effect of Sn on supported Ni catalyst during steam reforming of glycerol

L.F. Bobadilla; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola


Journal of CO 2 Utilization | 2016

Enabling continuous capture and catalytic conversion of flue gas CO2 to syngas in one process

L.F. Bobadilla; José M. Riesco-García; Germán Penelas-Pérez; Atsushi Urakawa


Chemical Engineering Journal | 2016

Intensifying glycerol steam reforming on a monolith catalyst: A reaction kinetic model

L.F. Bobadilla; V. Blay; M.I. Domínguez; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola


Applied Catalysis B-environmental | 2018

A direct in situ observation of water-enhanced proton conductivity of Eu-doped ZrO2: Effect on WGS reaction

Nuria García-Moncada; L.F. Bobadilla; R. Poyato; C. López-Cartes; F. Romero-Sarria; M.A. Centeno; J.A. Odriozola

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J.A. Odriozola

Spanish National Research Council

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M.A. Centeno

Spanish National Research Council

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F. Romero-Sarria

Spanish National Research Council

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M.I. Domínguez

Spanish National Research Council

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Svetlana Ivanova

Spanish National Research Council

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Victoria Garcilaso

Spanish National Research Council

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Anna Penkova

Bulgarian Academy of Sciences

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S. Palma

Spanish National Research Council

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V. Blay

Polytechnic University of Valencia

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