L. González-Rovira

Single-Step Process To Prepare CeO2 Nanotubes with Improved Catalytic Activity

CeO(2) nanotubes have been grown electrochemically using a porous alumina membrane as a template. The resulting material has been characterized by means of scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy, high-angle annular dark-field scanning transmission electron microscopy tomography, high-resolution electron microscopy (HREM), and electron energy loss spectroscopy. According to SEM, the outer diameter of the nanotubes corresponds to the pore size (200 nm) of the alumina membrane, and their length ranges between 30 and 40 microm. HREM images have revealed that the width of the nanotube walls is about 6 nm. The catalytic activity of these novel materials for the CO oxidation reaction is compared to that of a polycrystalline powder CeO(2) sample prepared by a conventional route. The activity of the CeO(2) nanotubes is shown to be in the order of 400 times higher per gram of oxide at 200 degrees C (77.2 x 10(-2) cm(3) CO(2) (STP)/(gxs) for the nanotube-shaped CeO(2) and 0.16 x 10(-2) cm(3) CO(2) (STP)/(gxs) for the powder CeO(2)).

Influence of Surface Pre-treatments on Laser Welding of Ti6Al4V Alloy

In the present study, Ti6Al4V samples have been welded under conduction regime by means of a high power diode laser. The main objective of the work has been to determine the actual influence of the surface pre-treatments on the laser welding process. Thus, six different pre-treatments were applied to Ti6Al4V samples before performing bead-on-plate and butt welding treatments. The depth, width, microstructure, and microhardness of the different weld zones were deeply analyzed. Grinding, sandblasting, and chemical cleaning pre-treatments lead to welds with the highest depth values, presenting high joint strengths. Treatments based on the application of dark coatings generate welds with lower penetration and worse mechanical properties, specially the graphite-based coating.

Laser texturization to improve absorption and weld penetration of aluminum alloys

In the present work, laser texturization treatments have been performed for the first time on aluminum alloys to increase their absorption and weld penetration. Adjusting the experimental conditions, laser texturization increases the roughness and decreases the diffuse and specular reflectance of surfaces. The textured samples were subsequently subjected to bead-on-plate laser weld treatments with a high power diode laser. Taking the weld beads of sandblasted samples as reference, depth improvements percentages around 20% are reached in some textured samples. Laser texturization has demonstrated to increase the weld penetration ability of aluminum alloys, constituting a potential tool to reduce the energetic requirements of the laser welding process.

Adhesive behaviour of carbon fibre reinforced plastic panels manufactured using woven and unidirectional tape after ultraviolet laser surface treatment

This paper describes the results obtained when ultraviolet laser treatment was performed as a surface treatment prior to adhesive bonding for two aeronautical carbon fibre-reinforced plastics based on an epoxy resin prepreg. Different laser-processing parameters were employed, and their effect on the surfaces was analysed through morphological characterisation and wettability studies. X-ray photoelectron spectroscopy measurements were performed to determine the cleaning and activation effects of the treatment. The strength of the bonded joint was studied for laser-treated and manually ground samples. Samples processed under the selected laser conditions exhibited better adhesive behaviour than the manually treated samples, thereby suggesting that ultraviolet laser treatment could be used as an alternative method for surface activation of aeronautical composites based on epoxy resins.

Laser welding of aeronautical and automobile aluminum alloys

Laser beam welding (LBW) show clear advantages compared with other techniques, as the low heat input, the high localization ability, the high welding speed, the high flexibility, the high weld quality and the high production rate. However, its applicability to aluminum alloys is limited, as they generally have high reflectivity, high thermal conductivity and low viscosity. In the present study, it is analyzed the laser weldability of four aluminum alloys (2024, 5083, 6082 and 7075). High penetration butt welds could be obtained with a high power diode laser under conduction regime. The properties of the weld beads such as the microstructure and microhardness were analyzed. A linear function between the input laser fluence and the volume of melted material was obtained for the four alloys.

Analysis of the Laser Weldability under Conduction Regime of 2024, 5083, 6082 and 7075 Aluminium Alloys

Laser beam welding (LBW) show clear advantages compared with other techniques, as the low heat input, the high localization ability, the high welding speed, the high flexibility, the high weld quality and the high production rate. However, its applicability to aluminium alloys is limited, as they generally have high reflectivity, high thermal conductivity and low viscosity. In the present study, the laser weldability of four aluminium alloys (2024, 5083, 6082 and 7075) under conduction regime is analysed. High penetration butt welds could be obtained with a High Power Diode Laser (HPDL) under conduction regime. The properties of the weld beads such as the microstructure and microhardness were analysed. A linear function between the input laser fluence and the volume of melted material was obtained for the four alloys.

Protection by Thermal and Chemical Activation with Cerium Salts of the Alloy AA2017 in Aqueous Solutions of NaCl

A wide variety of anticorrosive treatments for aluminum alloys that can be employed as “green” alternatives to those based on Cr(VI) are currently under development. This article reports a study of the morphological and anticorrosive characteristics of surface layers formed on the Al–Cu alloy AA2017 by immersion treatment in baths of cerium salt, accelerated by increased temperature and the employment of hydrogen peroxide. Scanning electron microscopy (SEM)/X-ray energy dispersive spectroscopy (XEDS) studies of the samples treated have demonstrated the existence of a heterogeneous layer formed by a film of aluminum oxide/hydroxide on the matrix, and a series of dispersed islands of cerium over the cathodic intermetallics. The protective efficacy has been evaluated using electrochemical techniques, linear polarizations (LP) and electrochemical impedance spectroscopy (EIS), and salt spray tests. The results obtained indicate that the layer provided good resistance to corrosion in media with chlorides, and the method gives a considerable reduction of the time required for the immersion treatments.

Application of Laser Texturization to Increase the Depth of AA5083 Welds

The application of laser beam welding to aluminium alloys has some complications, mainly due to their high reflectivity, high thermal conductivity and low viscosity. In order to increase the laser absorption of aluminium alloys, some surface treatments has been applied in the literature, such as the application of dark coatings or sandblasting. However, these conventional superficial treatments have some drawbacks, such as the low weld penetration, the possibility to undergo magnesium evaporation and the impossibility to control and/or change the superficial properties of the treated samples. In the present contribution, laser texturization treatments have been performed with a fibber laser for the first time on aluminium alloys to increase their absorption and weld penetration. The texturised samples leaded to deeper bead welds than the reference sandblasted samples.

Improvements of laser weldability of aluminum alloys by laser texturization

The application of laser beam welding to aluminum alloys has some complications, mainly due to their high reflectivity, high thermal conductivity and low viscosity. In order to increase the laser absorption of aluminum alloys, some surface treatments has been applied in the literature, such as the application of dark coatings or sandblasting. However, these conventional superficial treatments have some drawbacks, such as the low weld penetration, the possibility to undergo magnesium evaporation and the impossibility to control and/or change the superficial properties of the treated samples. In the present contribution, laser texturization treatments have been performed with a fibber laser for the first time on aluminum alloys to increase their weldability. These textured samples have shown better weldability than reference sandblasted samples.