Laly A. Pothen

Environmental friendly method for the extraction of coir fibre and isolation of nanofibre.

The objective of this work was to develop an environmental friendly method for the effective utilization of coir fibre by adopting steam pre-treatment. The retting of the coconut bunch makes strong environmental problems which can be avoided by this method. Chemical characterization of the fibre during each processing stages confirmed the increase of cellulose content from raw (40%) to final steam treated fibres (93%). Morphological and dynamic light scattering analyses of the fibres at different processing stages revealed that the isolation of cellulose nano fibres occur in the final step of the process as an aqueous suspension. FT-IR and XRD analysis demonstrated that the treatments lead to the gradual removal of lignin and hemicelluloses from the fibres. The existence of strong lignin-cellulose complex in the raw coir fibre is proved by its enhanced thermal stability. Steam explosion has been proved to be a green method to expand the application areas of coir fibre.

Biopolymer Nanocomposites: Processing, Properties, and Applications

Interest in biopolymer nanocomposites is soaring. Not only are they green and sustainable materials, they can also be used to develop a broad range of useful products with special properties, from therapeutics to coatings to packaging materials. With contributions from an international team of leading nanoscientists and materials researchers, this book draws together and reviews the most recent developments and techniques in biopolymer nano-composites. It describes the preparation, processing, properties, and applications of biopolymer nanocomposites developed from chitin, starch, and cellulose, three renewable resources.

Nanocelluloses from jute fibers and their nanocomposites with natural rubber: Preparation and characterization.

Nanocellulose fibers having an average diameter of 50nm were isolated from raw jute fibers by steam explosion process. The isolation of nanocellulose from jute fibers by this extraction process is proved by SEM, XRD, FTIR, birefringence and TEM characterizations. This nanocellulose was used as the reinforcing agent in natural rubber (NR) latex along with crosslinking agents to prepare crosslinked nanocomposite films. The effects of nanocellulose loading on the morphology and mechanics of the nanocomposites have been carefully analyzed. Significant improvements in the Youngs modulus and tensile strength of the nanocomposite were observed because of the reinforcing ability of the nanocellulose in the rubber matrix. A mechanism is suggested for the formation of the Zn-cellulose complex. The three-dimensional network of cellulose nanofibers (cellulose/cellulose network and Zn/cellulose network) in the NR matrix plays a major role in improving the properties of the crosslinked nanocomposites.

Evaluation of in-vitro cytotoxicity and cellular uptake efficiency of zidovudine-loaded solid lipid nanoparticles modified with Aloe Vera in glioma cells

Zidovudine loaded solid lipid nanoparticles of stearic acid modified with Aloe Vera (AV) have been prepared via simple emulsion solvent evaporation method which showed excellent stability at room temperature and refrigerated condition. The nanoparticles were examined by Fourier transform infrared spectroscopy (FT-IR), which revealed the overlap of the AV absorption peak with the absorption peak of modified stearic acid nanoparticles. The inclusion of AV to stearic acid decreased the crystallinity and improved the hydrophilicity of lipid nanoparticles and thereby improved the drug loading efficacy of lipid nanoparticles. Dynamic light scattering (DLS) and transmission electron microscopy (TEM) imaging revealed that, the average particle size of unmodified (bare) nanoparticles was 45.66±12.22nm and modified solid lipid nanoparticles showed an average size of 265.61±80.44nm. Solid lipid nanoparticles with well-defined morphology were tested in vitro for their possible application in drug delivery. Cell culture studies using C6 glioma cells on the nanoparticles showed enhanced growth and proliferation of cells without exhibiting any toxicity. In addition, normal cell morphology and improved uptake were observed by fluorescence microscopy images of rhodamine labeled modified solid lipid nanoparticles compared with unmodified nanoparticles. The cellular uptake study suggested that these nanoparticles could be a promising drug delivery system to enhance the uptake of antiviral drug by brain cells and it could be a suitable drug carrier system for the treatment of HIV.

The role of interface modification on the mechanical properties of injection-moulded composites from commingled polypropylene/banana granules

Commingled polypropylene (PP)/banana granules were fabricated from slivers by mixing PP fibers and banana fibers by textile equipment. By twisting the sliver, the reinforcing fibers were compacted and bonded with the molten matrix material. PP/banana composites were prepared from commingled PP/banana granules by injection moulding method with special reference to the effect of maleic anhydride modified polypropylene (MAH-PP) concentration. The mechanical properties of the composites were found to depend on the concentration of MAH-PP. The tensile and flexural properties of the composites increased with the addition of MAH-PP up to 2 wt%. After 2 wt% addition of MAH-PP, these properties tend to be stabilized. On the other hand the unmodified composites showed the maximum impact strength. Fourier transform infrared spectroscopic (FTIR) analysis of the MAH-PP modified composites showed evidence of a chemical bridge between the hydroxyl group of the banana fiber and maleic anhydride of the MAH-PP through an esterification reaction. The feature peak of the esterification occurred in the range ∼ 1743 cm−1. In order to confirm the esterfication reaction further, FTIR spectra of the banana microfibrils and MAH-PP modified PP/banana microfibril composites were taken and compared. The tensile fracture surfaces of the unmodified and MAH-PP modified PP/banana composites were studied by scanning electron microscopy (SEM). An improvement in adhesion between the fiber and the matrix was observed in the case of MAH-PP modified composites. Two different processing methods, both injection and compression mouldings were performed to prepare the PP/banana composites. Tensile properties of the composites prepared by these two methods were compared. The enhancement of tensile properties for injection-moulded composites compared to the compression-moulded composites is owing to the occurrence of orientation, better mixing and interaction between the fiber and the matrix during injection moulding. Finally, experimental results of the tensile properties of the injection-moulded composites have been compared with theoretical predictions.

Natural fibre and polymer matrix composites and their applications in aerospace engineering

Fibre-reinforced polymer composite materials are fast gaining ground as preferred materials for construction of aircrafts and spacecrafts. In particular, their use as primary structural materials in recent years in several technology demonstrator front-line aerospace projects worldwide has provided confidence that has led to their acceptance as prime materials for aerospace vehicles. Fibre polymer composites alongside aluminium alloys are the most frequently used materials in aircraft structures. The use of composites in civil aircraft, military fighters and helicopters has increased rapidly since the 1990s, and composites are now competing head-to-head with aluminium as the materials of choice in many airframe structures. The use of composites in gas turbine engines for both civil and military aircraft is also growing. The main reasons for using composites are to reduce weight, increase specific stiffness and strength, extend fatigue life and minimize problems with corrosion. Natural fibre composites present several advantages over man-made fibre composites such as low cost, light weight, high specific mechanical properties, nonhazardous nature, eco-friendliness, renewability and so on, and consequently their utilization in various industrial sectors including aerospace engineering is highly promising. This chapter discusses different aspects of natural fibre as well as conventional polymer matrix composites, focussing on aerospace applications.

Raw and Renewable Polymers

Biopolymers from renewable resources have attracted much attention in recent years. Increasing environmental consciousness and demands of legislative authorities have given significant opportunities for improved materials from renewable resources with enhanced support for global sustainability. High-performance plastics are the outcome of continuous research over the last few decades. The real challenge of renewable polymers lies in finding applications, which will result in mass production, and price reduction. This can be attained by improving the end performance of the biodegradable polymers. The structure, properties, and applications of polymers derived from natural resources are discussed in this article.

CHAPTER 11:Micro and Nano Metal Particle Filled Natural Rubber Composites

The insulating host NR material can be turned into conducting or semi-conducting, depending on the amount of metal particles dispersed throughout the medium. Ferromagnetic iron, nickel and cobalt, aluminium particles, etc. are the choices as metallic magnetic fillers. The composites show a ferromagnetic behaviour and the saturation magnetization is found to increase with the metal content. It is observed that dielectric permittivity increases with an increase as the concentration of filler and decreased by the rise in temperature and the magnetic properties of the composite can be increased by incorporating appropriate amounts of metal particles. Due to to to many advantaged properties of them, they are widely used in chemical sensors, electroluminescent devices, electrocatalysis, batteries, smart windows and memory devices. They also used as microwave absorbers and flexible magnets.

Adhesion and Wettability Characteristics of Chemically Modified Banana Fibre for Composite Manufacturing

In this work banana fibre was chemically modified using various chemical agents. The surface energy of the fibre is an important parameter and one which governs the interaction of fibre with polymeric matrices. This paper describes the influence of various chemical treatments on the surface energy of the banana fibre investigated by contact angle measurements, spectroscopic analysis and surface morphology studies. The surface energy, work of adhesion, polarity, spreading coefficient, interfacial energy and interaction parameter were determined in the case of raw and chemically modified fibres. Chemical modification has been found to have a profound effect on the surface energy. The polar and dispersive components of the surface energy were also found to be dependent on the chemical treatment involved. The chemical modifications done in this work were: alkali treatment, silanation, benzoylation, formylation, potassium permanganate treatment and acetylation. Of all the modifications, the relative surface energy was found to be a maximum for alkali treated fibre and minimum for silanated fibre. Contact angle measurements were found to be an effective tool in predicting the possible interaction of the fibres with phenol formaldehyde matrix resin. Atomic force microscopy roughness analysis revealed a significant decrease in surface roughness for the chemically modified fibre. An increase both in fibre/matrix adhesion and interfacial shear strength has been observed for all surface modified fibres except for those modified by benzoylation and acetylation.

Novel dendritic structure of alginate hybrid nanoparticles for effective anti-viral drug delivery

Lipid-polymer hybrid nanoparticles have recently gathered much attention as nanoplatforms for drug delivery applications due to their unique structural properties. In this study zidovudine (AZT) loaded hybrid nanoparticles of alginate (ALG) and stearic acid- poly ethylene glycol (SA-PEG) were synthesized. The structural characterization of drug loaded hybrid nanoparticles were studied using FT-IR spectroscopy, DLS and TEM analysis. These hybrid nanoparticles showed dendritic morphology and it can be used as an efficient carrier for zidovudine. In this drug loaded hybrid system of Alginate -Stearicacid/Poly (ethyleneglycol) Nanoparticles (ASNPs), AZT and alginate form the core wherein SA-PEG forms the external shell. We observed a dendritic morphology with internal voids and channels formed by the core molecule and the external shell forms the closed pack surface groups. The optimized formulation achieved a sub micron size of 407.67±19.18nm with drug encapsulation of 83.18±1.22%, and surface potential of -42.53mV, and has significant stability for six months. Haemolysis and aggregation studies revealed that there were no lysis and aggregation in WBC, RBC and platelets. In-vitro cytotoxicity and cellular uptake of the nanoparticles in Glioma, Neuro2a and Hela cells showed that ASNPs are non toxic. The results indicate that the synthesized hybrid nanoparticles represent a potential carrier for zidovudine, thus possibly increasing zidovudines efficiency as an anti-HIV drug.