Laura Pozo-Morales

OMW spillage control tool based on tracking p-Coumaric acid degradation by HPLC

ABSTRACT Olive mill wastewater (OMW) is a major watercourse pollutant agent with a high concentration of phenolic compounds. It is estimated that 30 million OMW m3 are released into rivers every year. Protecting the health of these courses against the uncontrolled discharges implies establishing an adequate legislation, where spillage control tools play a fundamental role. In this paper, a new tool for OMW spillage control is discussed. It is based on the use of a RP-HPLC-UV protocol to track p-Coumaric acid (pCA), a characteristic OMW phenolic compound, and its derivative compounds through their chemical oxidation and biological anaerobic degradation. Laboratory assays and real-life experiences allowed to determine degradation routes and apparition times for every pCA derivative, making it possible to detect an OMW spill and assess its age. Moreover, this RP-HPLC-UV introduces solid advantages over previous detection procedures, namely, quicker response times and smaller costs than HPLC methods and superior specificity than colorimetric methods. Finally, this tool was put to test in an actual OMW-polluted watercourse. In all scenarios, the tool demonstrated solid reliability. GRAPHICAL ABSTRACT

Olive Mill Industrial Waste as Co-substrate in Anaerobic Digestion with Aim at its Energetic Exploitation

The aim of this paper is to assess the feasibility of the co-digestion of olive mill industrial waste with urban sewage sludge from wastewater treatment plants (WWTP). These wastes include olive mill solid waste (OMSW) and olive mill effluent (OME). This co-digestion process enables the energetic exploitation of OMSW and/or OME and introduces an environmental solution for their highly pollutant compounds. The behaviour of both co-substrates was studied using biochemical methane potential assays. To determine the optimal proportions of each co-substrate, different quantities of OME and OMSW were added to a constant quantity of substrate (urban sewage sludge) and put to test. A small amount of digested sludge from WWTP was used as an inoculum to accelerate the pace of the reactions. Thus, the optimal proportions between substrate and co-substrate were defined. The samples containing OMSW showed a biodegradability around 23%, slightly above that of the substrate on its own (21.3%). Moreover, biogas production in samples containing OMSW was significantly superior to samples containing substrate only. Nevertheless, the samples containing OME as a co-substrate presented an inferior biodegradability (20.3%) to that of the substrate on its own. Similarly, biogas production in OME co-digestion remained within the usual values of urban sewage sludge biogas production. In all cases, the system remained stable and the energetic efficiency of the process was improved in comparison to the digestion of substrate only. Therefore, co-digestion with urban sewage sludge proves to be a cost-effective method for OMSW and OME environmental management.

Naturalization: a New Concept Developed and Carried Out in the Subject " Environmental Technology " of Degree in Industrial Engineering

Environmental Technology is a 6 credits transversal subject included in the curriculum of all the degrees in Industrial Engineering at the Higher Polytechnic School of the University of Seville. In the last 5 academic courses, the students of this matter have been working with the concept of “Naturalization”. In the different topics which are studied in this subject, they have to apply the naturalization of the systems in order to use natural resources for improving processes. The Naturalization implies improvements in energetic efficiency, development of green spaces and CO2 capture and can be applied the majority of the industrial and urban activities. Some of the most meaningful results that our students have researched are: i) Naturalization of a large pond in a business park in Jaen (Spain) performing its layout and eventually implementing it, using plants to improve water quality and stones for fix them and to give support for bacterial biofilms. The students have improved their skills not only in the increase of new knowledge but in the ability of work in groups and carry out a real project under different points of view. ii) Project of naturalization of a neighbourhood in Seville, based on the increase of green spaces, with vegetal species which are able to capture electromagnetic radiations and CO2 emissions as well. iii) Naturalization of the margins of one lagoon in a park in Seville, transforming the precast panelled walls in breakwater bed of stones planted with bank river plants in order to improve the water quality and the landscape.