Laura Rodríguez-Arco

Colloids on the frontier of ferrofluids. Rheological properties.

This paper is devoted to the steady-state rheological properties of two new kinds of ferrofluids. One of these was constituted by CoNi nanospheres of 24 nm in diameter, whereas the other by CoNi nanofibers of 56 nm in length and 6.6 nm in width. These ferrofluids were subjected to shear rate ramps under the presence of magnetic fields of different intensity, and the corresponding shear stress values were measured. From the obtained rheograms (shear stress vs shear rate curves) the values of both the static and the dynamic yield stresses were obtained as a function of the magnetic field. The magnetoviscous effect was also obtained as a function of both the shear rate and the magnetic field. The experimental results demonstrate that upon magnetic field application these new ferrofluids develop yield stresses and magnetoviscous effects much greater than those of conventional ferrofluids, based on nanospheres of approximately 10 nm in diameter. Besides some expected differences, such as the stronger magnetorheological effect in the case of ferrofluids based on nanofibers, some intriguing differences are found between the rheological behaviors of nanofiber ferrofluids and nanosphere ferrofluid. First, upon field application the rheograms of nanofiber ferrofluids present N-shaped dependence of the shear stress on the shear rate. The decreasing part of the rheograms takes place at low shear rate. These regions of negative differential viscosity, and therefore, unstable flow is not observed in the case of nanosphere ferrofluids. The second intriguing difference concerns the curvature of the yield stress vs magnetic field curves. This curvature is negative in the case of nanosphere ferrofluid, giving rise to saturation of the yield stress at medium field, as expected. However, in the case of nanofiber ferrofluid this curvature is positive, which means a faster increase of the yield stress with the magnetic field the higher the magnitude of the latter. These interesting differences may be due to the existence of strong interparticle solid friction in the case of nanofiber ferrofluids. Finally, theoretical models for the static yield stress of the ferrofluids were developed. These models consider that upon field application the ferrofluid nanoparticles are condensed in drops of dense phase. These drops tend to be aligned along the field direction, opposing the flow of the ferrofluids and being responsible for the static quasielastic deformation and the yield-stress phenomena. By considering the existence of interparticle dry friction only in the case of nanofiber ferrofluids, the developed models predicted quite well not only the magnitude of the static yield stress but also the differences in curvature of the yield stress vs magnetic field curves.

Steric repulsion as a way to achieve the required stability for the preparation of ionic liquid-based ferrofluids.

With this work we would like to emphasize the necessity of steric repulsion to stabilize novel ionic liquid-based ferrofluids. For this purpose, we prepared a suspension of magnetite nanoparticles coated with a double layer of oleic acid, dispersed in 1-ethyl-3-methylimidazolium ethylsulphate ([EMIM][EtSO(4)]). For comparison, a suspension of bare magnetite nanoparticles in [EMIM][EtSO(4)] was also prepared. The stability of these suspensions was checked by magnetic sedimentation and centrifugation processes. Furthermore, their yield stress was measured as a function of the applied magnetic field, which gave additional information on their stability. The results of these experiments showed that the suspension of bare nanoparticles was rather unstable, whereas the suspension of double layer coated nanoparticles gave rise to a true (stable) ferrofluid.

Effect of gap thickness on the viscoelasticity of magnetorheological fluids

In this work, the effect of confinement distance on the magnetorheological (MR) properties of a conventional MR fluid, constituted by 30 vol % of iron microparticles dispersed in a liquid carrier, is studied. With this aim a commercial magnetorheometer supplied with parallel-plate geometry was used. The distance between the upper and the lower plate (gap thickness) was tuned from 10 to 400 μm. The steady-state and the dynamic regimes of the MR fluid in the presence of applied magnetic fields were studied as a function of the gap length. The experimental results show that in the preyield regime there is a strong increase in the magnitude of the viscoelastic moduli and the shear stress as the gap thickness is increased. The physical reason for this effect might be the influence of gap thickness on the particle structures induced by the field. This hypothesis is corroborated by microscopic observations in diluted systems. These experiments show that the aspect ratio (length/diameter) of the field-induced str...

Yield stress in magnetorheological suspensions near the limit of maximum-packing fraction

This work deals with the magnetic field-induced static yield stress of magnetorheological (MR) suspensions with concentration near the limit of maximum-packing fraction. With this aim, homogeneous suspensions of iron microparticles with 50 vol.% concentration were prepared, and their yield stress measured as a function of the applied magnetic field. In view of the failure of existing models to predict, on the basis of realistic hypotheses, the values of the yield stress of highly concentrated MR suspensions, we developed a new model. Our model considers that field application induces body-centered tetragonal structures. Upon shearing, these structures deform in such a way that interparticle gaps appear between neighboring particles of the same chain, whereas the approach of particles of parallel chains ensures the mechanical stability of the whole multi-chain structure. Based on this hypothesis, and using finite element method simulations of interparticle magnetic interactions, our model is able to quanti...

Stick–slip instabilities in the shear flow of magnetorheological suspensions

This work is devoted to the stick–slip instabilities that appear in the shear flow of highly concentrated suspensions of magnetic microparticles. The effect of the applied magnetic field strength was analyzed in details. With this aim, homogeneous suspensions of iron microparticles with concentration near the limit of maximum-packing fraction were prepared, and shear-flow measurements were performed in a controlled-rate mode using a rheometer provided with a rough parallel-plate geometry. For each given value of the shear rate, the time evolution of the shear stress was monitored for at least 20 min. Saw-tooth-like stress oscillations, typical of stick–slip instabilities, were obtained at low enough shear rate values. The measurements were restricted to small enough oscillations, at which the rheometer was still able to maintain the shear rate constant. From the microscopic viewpoint, these stick–slip instabilities principally appear due to the periodic failure and healing of the field-induced particle st...

Optimizing the Magnetic Response of Suspensions by Tailoring the Spatial Distribution of the Particle Magnetic Material

We report an experimental enhancement of the magnetic susceptibility of suspensions of particles that is related to the spatial distribution of the magnetic phase in the particles. At low field, the susceptibility of suspensions of nickel-coated diamagnetic spheres was approximately 75% higher than that of suspensions of solid nickel spheres with the same nickel content. This result was corroborated by magnetostatics theory and simulation. The distribution of the magnetic phase in a shell also led to an improvement of the field-induced rheological response of the suspensions.

New Perspectives for Magnetic Fluid-Based Devices Using Novel Ionic Liquids as Carriers

© 2012 Lopez-Lopez et al., licensee InTech. This is an open access chapter distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. New Perspectives for Magnetic Fluid-Based Devices Using Novel Ionic Liquids as Carriers

Stability behavior of composite magnetorheological fluids by an induction method

In this work, we study the stability behavior of composite magnetorheological fluids consisting of magnetic (iron) and non-magnetic (poly(methylmethacrylate)) particles dispersed in mineral oil. Because of the opacity of the suspensions, optical methods traditionally employed for evaluation of the gravitational settling in colloidal suspensions are not suitable for sedimentation follow-up in this case. For this reason, we use an alternative method based on the evaluation of the resonant frequency of the inductance of a thin coil surrounding the sample. The movement of the coil along the height of the container at specified steps and time intervals allows obtaining information about the local volume fraction of particles inside the tube. The obtained successive profiles for the multi-component suspensions show a decrease of the iron particle settling and of the initial rate of settling as the poly(methylmethacrylate) volume fraction is increased. Finally, the increase of the poly(methylmethacrylate) concentration gives rise to an improvement of the rheological properties upon magnetic field application for a given concentration of iron. Both a strong rheological response and a good colloidal stability are essential for practical applications.

N-like rheograms of concentrated suspensions of magnetic particles

We investigate the rheograms of concentrated suspensions of magnetic particles obtained under imposed shear rate in parallel plate geometry. We show that under magnetic field application the usual trend of the rheogram, i.e., increasing shear stress for the whole range of shear rates, is altered by the appearance of a region in which the shear stress decreases as the shear rate is increased. The existence of this region gives to the rheograms an N-like shape. The two initial regions (preyield regime) of these N-like rheograms present unstable flow, characterized by the oscillation of the shear stress with time for each imposed value of shear rate. We also show that rheograms obtained at different sample thicknesses approximately overlap in the developed flow regime, whereas there is a tendency of the shear stress to increase as the thickness is decreased in the preyield regime. This tendency is likely due to the strengthening of pre-existing particle structures by compression as the gap thickness is decre...

Magnetorheological effect in the magnetic field oriented along the vorticity

In this work, we have studied the magnetorheological (MR) fluid rheology in the magnetic field parallel to the fluid vorticity. Experimentally, the MR fluid flow was realized in the Couette coaxial cylinder geometry with the magnetic field parallel to the symmetry axis. The rheological measurements were compared to those obtained in the cone-plate geometry with the magnetic field perpendicular to the lower rheometer plate. Experiments revealed a quasi-Bingham behavior in both geometries with the stress level being just a few dozens of percent smaller in the Couette cylindrical geometry at the same internal magnetic field. The unexpectedly high MR response in the magnetic field parallel to the fluid vorticity is explained by stochastic fluctuations of positions and orientations of the particle aggregates. These fluctuations are induced by magnetic interactions between them. Once misaligned from the vorticity direction, the aggregates generate a high stress independent of the shear rate, and thus assimilated to the suspension apparent (dynamic) yield stress. Quantitatively, the fluctuations of the aggregate orientation are modeled as a rotary diffusion process with a diffusion constant proportional to the mean square interaction torque. The model gives a satisfactory agreement with the experimental field dependency of the apparent yield stress and confirms the nearly quadratic concentration dependency Sigma_Y proportional to Phi^2.2, revealed in experiments. The practical interest of this study lies in the development of MR smart devices with the magnetic field non-perpendicular to the channel walls.