Lawrence J. Poppe

Meteoroid mayhem in Ole Virginny: Source of the North American tektite strewn field

New seismic reflection data from Chesapeake Bay reveal a buried, 85-km-wide, 1.5-2.0-km-deep, peak-ring impact crater, carved through upper Eocene to Lower Cretaceous sedimentary strata and into underlying pre-Mesozoic crystalline basement rocks. A polymictic, late Eocene impact breccia, composed mainly of locally derived sedimentary debris (determined from four continuous cores), surrounds and partly fills the crater. Structural and sedimentary characteristics of the Chesapeake Bay crater closely resemble those of the Miocene Ries peakring crater in southern Germany. We speculate that the Chesapeake Bay crater is the source of the North American tektite strewn field.

Sedimentation of lithogenic particles in the deep ocean

Abstract Investigation of lithogenic particles collected by sediment traps in open-ocean stations revealed that the sediment flux increased linearly with depth in the water column. This rate of increase decreased with distance of the station from the continent; it was largest at the Panama Basin station and almost negligible at the E. Hawaii Abyssal Plain station. At the Panama Basin station, smectite flux increased with depth. We suggest that smectite resuspended from bottom sediments of the continental slope west of the sediment-trap station is advected by easterly deep currents, and the suspended particles are then possibly entrapped by large settling particles. On the other hand, the flux of hemipelagic clay particles, kaolinite and chlorite, was nearly constant at all depths; this can be explained by incorporation of these particles in fecal pellets which then settle from the surface water. At the Demerara Abyssal Basin Station, flux of illite and chlorite particles increased with depth and the flux of smectite was constant. A sudden increase of the flux of illite and chlorite was observed near the bottom traps at the Sohm Abyssal Plain station. The flux of quartz and feldspar was 10 to 15% of the clay flux.

Seafloor environments in the Long Island Sound estuarine system

Abstract Four categories of modern seafloor sedimentary environments have been identified and mapped across the large, glaciated, topographically complex Long Island Sound estuary by means of an extensive regional set of sidescan sonographs, bottom samples, and video-camera observations and supplemental marine-geologic and modeled physical-oceanographic data. (1) Environments of erosion or nondeposition contain sediments which range from boulder fields to gravelly coarse-to-medium sands and appear on the sonographs either as patterns with isolated reflections (caused by outcrops of glacial drift and bedrock) or as patterns of strong backscatter (caused by coarse lag deposits). Areas of erosion or nondeposition were found across the rugged seafloor at the eastern entrance of the Sound and atop bathymetric highs and within constricted depressions in other parts of the basin. (2) Environments of bedload transport contain mostly coarse-to-fine sand with only small amounts of mud and are depicted by sonograph patterns of sand ribbons and sand waves. Areas of bedload transport were found primarily in the eastern Sound where bottom currents have sculptured the surface of a Holocene marine delta and are moving these sediments toward the WSW into the estuary. (3) Environments of sediment sorting and reworking comprise variable amounts of fine sand and mud and are characterized either by patterns of moderate backscatter or by patterns with patches of moderate-to-weak backscatter that reflect a combination of erosion and deposition. Areas of sediment sorting and reworking were found around the periphery of the zone of bedload transport in the eastern Sound and along the southern nearshore margin. They also are located atop low knolls, on the flanks of shoal complexes, and within segments of the axial depression in the western Sound. (4) Environments of deposition are blanketed by muds and muddy fine sands that produce patterns of uniformly weak backscatter. Depositional areas occupy broad areas of the basin floor in the western part of the Sound. The regional distribution of seafloor environments reflects fundamental differences in marine-geologic conditions between the eastern and western parts of the Sound. In the funnel-shaped eastern part, a gradient of strong tidal currents coupled with the net nontidal (estuarine) bottom drift produce a westward progression of environments ranging from erosion or nondeposition at the narrow entrance to the Sound, through an extensive area of bedload transport, to a peripheral zone of sediment sorting. In the generally broader western part of the Sound, a weak tidal-current regime combined with the production of particle aggregates by biologic or chemical processes, cause large areas of deposition that are locally interrupted by a patchy distribution of various other environments where the bottom currents are enhanced by and interact with the seafloor topography.

Chemistry and mineralogy of pyrite-enriched sediments at a passive margin sulfide brine seep: abyssal Gulf of Mexico

Pyrite is rapidly accumulating at the contact between the Cretaceous limestones of the Florida Platform and the hemipelagic sediments of the abyssal Gulf of Mexico. Sediments sampled with the submersible “Alvin” in 3266 m of water are associated with a dense community of organisms that depend on chemosynthetic primary production as a food source. Analysis of the chemistry, mineralogy, and textural composition of these sediments indicate that iron sulfide mineralization is occurring at the seafloor within an anoxic micro-habitat sustained by the advection of hydrogen sulfide-charged saline brines from the adjacent platform. The chemosynthetic bacteria that directly overlie the sediments oxidize hydrogen sulfide for energy and provide elemental sulfur that reacts with iron monosulfide to form some of the pyrite. The sediments are mixtures of pyrite (∼ 30 wt.%), BaSr sulfates (∼ 4 wt.%), clays, and locally derived biogenic carbonates and are progressively being cemented by iron sulfides. Oxidation of hydrogen sulfide produces locally acidic conditions that corrode the adjacent limestones. Potential sources of S, H2S, Fe, Ba, and Sr are discussed.

A Visual Basic program to generate sediment grain-size statistics and to extrapolate particle distributions

This paper is not subject to U.S. copyright. The definitive version was published in Computers & Geosciences 30 (2004): 791-795, doi:10.1016/j.cageo.2004.05.005.

Recent geologic history of lake Atitlán, a caldera lake in western Guatemala

Abstract Lake Atitlan, a caldera lake in western Guatemala, was investigated for evidence of recent volcanic and tectonic activity. No vents, faults, or folds are apparent on high-resolution seismic reflection profiles of lake sediment, representing at least 17,500 years and probably more than 35,000 years of deposition. Three post-caldera stratovolcanoes (San Pedro, Toliman, and Atitlan) have grown in southern parts of the caldera and two deltas have grown from the north shore of the lake. Elsewhere, the caldera is occupied by Lake Atitlan, which is more than 300 m deep and has a relatively flat floor. Refraction profiles suggest that the original floor of the caldera lies ca. 300 m below the current lake floor, but prodigious amounts of methane gas in the lake sediment attenuated seismic signals and prevented any detailed view of the original caldera floor or faults along which the floor is presumed to have collapsed. Piston cores from deep basins of Lake Atitlan record ca. 2,000 years of unusually rapid sedimentation (ca. 0.5 cm/yr). Only one thin silicic ash layer was penetrated, and it is probably from a distant source. Cores contain evidence of Mayan disturbance of the environment around the lake and, to a lesser degree, of the lake itself; they might also record episodes of increased thermal activity, each lasting several decades. Heat-flow measurements inside and just outside the caldera are high (290 and 230 mW m −2 ), suggesting hydrothermal convection and a shallow heat source. High heat flow, a geological record of post-caldera silicic eruptions, and unexplained fluctuations of lake level (episodic tumescence ofthe lake floor?) suggest that magma remains beneath Lake Atitlan and that future eruptions are possible.

The Toms Canyon structure, New Jersey outer continental shelf: A possible late Eocene impact crater

Abstract The Toms Canyon structure (~ 20–22 km wide) is located on the New Jersey outer continental shelf beneath 80–100 m of water, and is buried by ~ 1 km of upper Eocene to Holocene sedimentary strata. The structure displays several characteristics typical of terrestrial impact craters (flat floor; upraised faulted rim; brecciated sedimentary fill), but several other characteristics are atypical (an unusually thin ejecta blanket; lack of an inner basin, peak ring, or central peak; being nearly completely filled with breccia). Seismostratigraphic and biostratigraphic analyses show that the structure formed during planktonic foraminiferal biochron P15 of the early to middle late Eocene. The fill unit is stratigraphically correlative with impact ejecta cored nearby at Deep Sea Drilling Project (DSDP) Site 612 and at Ocean Drilling Program (ODP) Sites 903 and 904 (22–35 km southeast of the Toms Canyon structure). The Toms Canyon fill unit also correlates with the Exmore breccia, which fills the much larger Chesapeake Bay impact crater (90-km diameter; 335 km to the southwest). On the basis of our analyses, we postulate that the Toms Canyon structure is an impact crater, formed when a cluster of relatively small meteorites approached the target site bearing ~N 50 °E, and struck the sea floor obliquely.

A geophysical and geological study of Laguna de Ayarza, a Guatemalan caldera lake

Abstract Geologic and geophysical data from Laguna de Ayarza, a figure-8-shaped doublecaldera lake in the Guatemalan highlands, show no evidence of postcaldera eruptive tectonic activity. The bathymetry of the lake has evolved as a result of sedimentary infilling. The western caldera is steep-sided and contains a large flat-floored central basin 240 m deep. The smaller, older, eastern caldera is mostly filled by coalescing delta fans and is connected with the larger caldera by means of a deep channel. Seismicreflection data indicate that at least 170 m of flat-lying unfaulted sediments partly fill the central basin and that the strata of the pre-eruption edifice have collapsed partly along inward-dipping ring faults and partly by more chaotic collapses. These sediments have accumulated in the last 23,000 years at a minimum average sedimentation rate of 7 m/10 3 yr. The upper 9 m of these sediments is composed of > 50% turbidites, interbedded with laminated clayey silts containing separate diatom and ash layers. The bottom sediments have >1% organic material, an average of 4% pyrite, and abundant biogenic gas, all of which demonstrate that the bottom sediments are anoxic. Although thin (

Mesozoic stratigraphy and paleoenvironments of the Georges Bank Basin: A correlation of exploratory and cost wells

Abstract The Exxon 975-1, Conoco 145-1, and Mobil 312-1 hydrocarbon exploratory wells and the Continental Offshore Stratigraphic Test (COST) G-1 and G-2 wells were drilled in the southeastern part of the Georges Bank Basin. We used drill cuttings and logs from these wells to describe and correlate the dominant lithostratigraphic units and to document lateral changes in the depositional environments. The strata penetrated by the Exxon 975-1 and COST G-1 wells are much more terrestrial than at the seaward (downdip) COST G-2, Conoco 145-1, and Mobil 312-1 wellsites. Oldest rocks penetrated by the exploratory wells represent a Middle Jurassic carbonate-evaporite sequence that correlates to the Iroquois Formation. The Iroquois records nonmarine to marginal-marine sabkha, tidal-flat, and restricted lagoonal paleoenvironments in the Exxon 975-1 and COST G-1 wells, but progressively changes to inner neritic, littoral, and lagoonal paleoenvironments at the Mobil 312-1 wellsite. The nonmarine deltaic siliciclastics of the overlying Mohican Formation, Misaine Shale, and Mic Mac-Mohawk Formations are thicker and the marine carbonates of the Scatarie and Bacarro Limestones are usually thinner in the Jurassic strata of the Exxon 975-1 and COST G-1 wells than at the other wellsites. Similarly, lower delta-plain and delta-front facies of the Early Cretaceous Missisuaga and Logan Canyon Formations at the Exxon 975-1 and COST G-1 wellsites reflect a greater terrestrial influence than the laterally-equivalent shallow marine to delta-front facies present at the downdip wellsites.

Silt fraction heavy-mineral distributions in a lateritic environment: the rivers and insular shelf of north-central Puerto Rico

Abstract Mineralogical studies of sediments from the rivers and insular shelf in north-central Puerto Rico examine the effects of lateritic weathering and assess the silt fraction for economically important heavy minerals. This fraction, which is enriched in heavy minerals relative to the sand fraction, is mainly detrital but contains a strong authigenic component. The detrital silt heavy-mineral fraction in the rivers is dominated by an amphibole-garnet-pyroxene-epidote assemblage. Amphiboles are more abundant in the Rio Cibuco; pyroxenes are more abundant in the Rio de la Plata; and epidote and ilmenite are more abundant in the Rio Grande de Manati. The authigenic silt heavy-mineral fraction is largely a product of the lateritic weathering and dominated by iron oxides and alterites. Grains of bladed rutile and leached ilmenite are common. Spatial variability in silt-fraction mineralogy is considerable. Within the Rio Cibuco system variability is related to compositional differences in rapidly eroding source rocks. On the shelf, silt heavy-mineral abundances are greatest at the river mouths and decrease seaward. Variability in the shelf samples is controlled primarily by source rivers and shelf sorting processes. Compositional differences exist between the silt heavy-mineral assemblages in the rivers and the shelf, and between the heavy-mineral assemblages in the silt- and sand-sized fractions from these areas. Minerals of economic importance that occur in the silt fraction within the study area include cerargyrite, chromite, gold, magnetite, and rutile.