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Dive into the research topics where Leif P. Olson is active.

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Featured researches published by Leif P. Olson.


Tetrahedron Letters | 1993

A rotational kinetic isotope effect in the cyclopropylallene to 3-methylenecyclopentene thermal rearrangement

Leif P. Olson; Joseph J. Gajewski

Abstract The deuterium kinetic isotope effect at the exo-methylene carbon of allenyl-cyclopropane in its thermal 1,3-sigmatropic shift to 3-methylenecyclopentene was found to be 1.15/D 2 at 311.5°C. This is a striking example of a rotational effect.


Chemistry of Materials | 2006

The simple yet elusive crystal structure of silver acetate and the role of the Ag-Ag bond in the formation of silver nanoparticles during the thermally induced reduction of silver carboxylates

Leif P. Olson; David R. Whitcomb; Manju Rajeswaran; and Thomas N. Blanton; Barbara J. Stwertka


Journal of the American Chemical Society | 1996

One- and Two-Metal Ion Catalysis of the Hydrolysis of Adenosine 3‘-Alkyl Phosphate Esters. Models for One- and Two-Metal Ion Catalysis of RNA Hydrolysis

Thomas C. Bruice; Akira Tsubouchi; Robert O. Dempcy; Leif P. Olson


Journal of Physical Chemistry A | 2004

Mechanisms of Peroxynitrous Acid and Methyl Peroxynitrite, ROONO (R = H, Me), Rearrangements: A Conformation-Dependent Homolytic Dissociation

Yi-Lei Zhao; K. N. Houk; Leif P. Olson


Biochemistry | 1996

Mechanism of Aldehyde Oxidation Catalyzed by Horse Liver Alcohol Dehydrogenase

Leif P. Olson; Jia Luo; Orn Almarsson; Thomas C. Bruice


Journal of the American Chemical Society | 2002

Conformation-dependent state selectivity in O-O cleavage of ONOONO: An inorganic Cope rearrangement helps explain the observed negative activation energy in the oxidation of nitric oxide by dioxygen

Leif P. Olson; Keith T. Kuwata; and Michael D. Bartberger; K. N. Houk


Biochemistry | 1995

Electron tunneling and ab initio calculations related to the one-electron oxidation of NAD(P)H bound to catalase.

Leif P. Olson; Thomas C. Bruice


Journal of the American Chemical Society | 1999

Ketone-Catalyzed Decomposition of Peroxynitrite via Dioxirane Intermediates

Dan Yang; Yeung-Chiu Tang; Jian Chen; Xue-Chao Wang; Michael D. Bartberger; K. N. Houk, ,‡ and; Leif P. Olson


Journal of Solid State Chemistry | 2005

Silver-halide/organic-composite structures: Toward materials with multiple photographic functionalities

Joseph F. Bringley; Manju Rajeswaran; Leif P. Olson; Nancy M. Liebert


Journal of the American Chemical Society | 1999

Secondary Deuterium Kinetic Isotope Effects in Irreversible Additions of Hydride and Carbon Nucleophiles to Aldehydes: A Spectrum of Transition States from Complete Bond Formation to Single Electron Transfer

Joseph J. Gajewski; Wojciech Bocian; Nathan J. Harris; Leif P. Olson; John P. Gajewski

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K. N. Houk

University of California

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Joseph J. Gajewski

Indiana University Bloomington

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