Leonardo Langone

The late-Holocene Gargano subaqueous delta, Adriatic shelf: Sediment pathways and supply fluctuations

The Gargano subaqueous delta formed on the eastern and southeastern sides of the Gargano promontory, in the western Adriatic. This subaqueous deposit represents the southernmost portion of the late-Holocene highstand systems tract (HST) growing along the western side of the Adriatic as an extensive wedge of deltaic and shallow-marine mud. The late-Holocene HST rests above a regional downlap surface that marks the time of maximum landward shift of the shoreline attained around 5.5 cal. kyr BP, at the end of the late-Pleistocene–Holocene sea-level rise. High-resolution seismic–stratigraphic and tephra correlation indicate the presence of a thin basal unit recording condensed deposition between 5.5 and 3.7 cal. kyr BP over much of the basin. Above this unit, sediment accumulation rates increased to high values (as much as 1.5 cm yr−1) reflecting the stabilisation of relative sea level and the forcing from high frequency climatic or anthropogenic changes affecting river dynamics. The late-Holocene mud wedge, of which the Gargano subaqueous delta is a significant component, reaches up to 35 m in thickness and has a volume of ca 180 km3. The shore-parallel thickness distribution of the mud wedge reflects the dominant oceanographic regime of the basin and the asymmetric location of the mostly western sediment sources (with a combined modern delivery of 51.7×106 t yr−1 of mean suspended load). In sections perpendicular to the coast the late-Holocene mud wedge appears composed of forestepping clinoforms with gently dipping foresets (typically 0.5°). The Gargano subaqueous delta is characterised by a submarine topset in water depths shallower than 25–28 m, and accounts for about 1/7th of the total volume of the late-Holocene mud wedge, despite the absence of direct river supply to the Gargano area. In the area of maximum interaction between shore-parallel currents and basin morphology, progradation occurs onto a flat and barren bedrock outcrop in about 50–80 m water depth. The rapid transition from a thickness of 30 m of late-Holocene mud to nil is a good indication of the role of southward-flowing bottom-hugging shelf currents in causing the redistribution of sediment along the Adriatic inner shelf. Additional evidence of this regime comes from: (1) the most recent sigmoid (defined at seismic–stratigraphic scale) deposited since the onset of the Little Ice Age, showing a shore-parallel thickness distribution and a main depocentre to the southeast of the Gargano promontory; (2) the maximum values of sediment accumulation rates over the last century (documented by 210Pb measurements) defining a narrow shore-parallel belt immediately seaward of the depocentre of the most recent sigmoid. The Gargano subaqueous delta grows from the outbuilding of progressively younger progradational sigmoids that tend to parallel the previous ones. The Gargano subaqueous delta differs from other documented late-Holocene subaqueous deltas because its growth reflects: (1) sediment transport dominated by bottom currents sub-parallel to the strike of the composing clinoforms; (2) a complex supply regime including the Po delta (350 km to the north) and several coalescing Apennine rivers acting as ‘line source’; (3) several alternating intervals of enhanced outbuilding and condensed deposition; and (4) an in-phase growth of the most recent sigmoid with the major progradation of the Po delta during the Little Ice Age.

Accumulation rates and137Cs distribution in sediments off the Po River delta and the Emilia-Romagna coast (northwestern Adriatic Sea, Italy)

Abstract Sediment accumulation rate studies were conducted using 210 Pb and 137 Cs with the aim of understanding recent and present sedimentation patterns on the Italian Adriatic continental shelf. Since there is no simple model governing the delivery of radionuclides to coastal sediments a variety of approaches were used to estimate dry mass accumulation rates. At many sites there was little divergence between the various estimates, and the mean value is taken to be a reliable estimate of the net sediment accumulation rate. At other sites greater variation was observed. Reasons for these variations can include both secular changes in accumulation rates, and interruptions to the process of sedimentation arising from, for example, sediment mixing, scouring and focussing. At these sites best estimates of accumulation rates are given on the basis of an assessment of the most appropriate dating technique. Highest mass accumulation rates are found near the Po river (up to 1.80 ± 0.29g cm −2 year −1 ), reflecting the large supply of sedimentary materials from this source. South of the delta accumulation rates were much lower, ranging from 0.22 ± 0.06 to 0.39 ± 0.06g cm −2 year −1 . At a number of sites the 137 Cs activity versus depth profile had a well defined peak (resulting from weapon fallout) which served to identify the depth corresponding to 1963, providing a valuable check on the 210 Pb derived accumulation rates. At other sites this peak was too broad or confused to be a valuable reference. The distribution of 210 Pb and 137 Cs reflect their different geochemical behaviour and sources, and provide information on the process of sediment accumulation.

Metal fluxes to the sediments of the northern Venice Lagoon

Eighteen short cores were analyzed for major and trace metals (Al, Fe, Ca, Mg, Mn, Si, K, Ti, Pb, Zn, Cu, Ni, Cr), 210Pb, 137Cs, and other sediment characteristics, so as to describe the chronology of pollution and calculate metal concentration factors and fluxes. Substantial evidence was found that trace metal profiles are influenced by anthropogenic sources and by changes in sediment composition. Only Zn presents concentrations (up to 13.1 μmol g−) and concentration factors (1.3 to 13.2) that can be attributed to heavy contamination. Pb, Cu and Ni, in this order, are less significant. The areal distribution of concentrations and inventories reflects the importance of direct sources, in particular the industrial area of Porto Marghera and the Dese river. The inventories of excess metals, above pre-industrial levels, were determined for each core and the three different parts of the study area, the amounts of Zn accumulated in sediments are 11.0 Mmol, 5.1 Mmol and 0.37 Mmol in the Campalto, S. Erasmo, and Palude di Cona areas, respectively. Ruxes were also calculated and compared with those suggested for the atmospheric delivery by Cochran et al. [(1995)b. Atmospheric fluxes of heavy metal contaminants to the Venice Lagoon, Rapp. Comm. Int. Mer Medit., 34, 136.], the atmospheric contribution is predominant or significant in many cases, especially at sites far from the major local inputs. Concentrations and fluxes show a significant increase in the anthropogenic metal supply starting from the second decade of this century, with maximum inputs in the period between the (1930)s and the (1970)s. At some stations a decrease in heavy metal contamination of surficial sediments was found and this could be ascribed to a reduced input of pollutants in recent years.

Particle fluxes and biogeochemical processes in an area influenced by seasonal retreat of the ice margin (northwestern Ross Sea, Antarctica)

Abstract Fluxes of biogenic components were determined using time-series sediment trap samples collected at site B (74°01.50′S, 175°05.55′E) in the northern Joides Basin of the Ross Sea from December 1994 to January 1996. In most cases, a great part of the material collected by traps (200 and 540 m depth) was biogenic, opal being the most abundant constituent followed by organic matter. The composition of particles shows a seasonal pattern in the upper trap, which is much less evident at depth. Fluxes showed a marked seasonality due to the presence, in winter, of ice cover. During the sampling period, mass fluxes varied from 0.03 to 120 mg m −2 day −1 and from 24 to 393 mg m −2 day −1 at the upper and bottom level, respectively. Values of 0–64 mg m −2 day −1 of biogenic silica and 0–7.8 mg m −2 day −1 of organic carbon were obtained at 200 m depth. Near-bottom fluxes were almost always much higher: 11–141 and 1.5–19 mg m −2 day −1 , respectively. 210 Pb fluxes are lower than expected, and this means that particles sink rapidly without reaching an equilibrium with the radiotracer. A mechanism of focusing affects the bottom trap and much more, the seafloor. At site B, we measured particle fluxes that are much lower than those obtained at other locations in the Ross Sea. This can be due to low production and export during the sampling period, and underlies the necessity to further investigate the interannual variability of these processes.

Biochemical composition and early diagenesis of organic matter in coastal sediments of the NW Adriatic Sea influenced by riverine inputs

River inputs influence trophodynamic and biogeochemical processes of adjacent continental shelves. In order to provide new insights on the influence of continental inputs on the benthic trophic state and early diagenesis of sediment organic matter we collected surface sediments in the NW Adriatic Sea at three stations located at increasing distance from the Po River. Sediment samples were collected in four periods characterized by different river outflows and analysed for chloropigment content (chlorophyll-a and phaeopygments), protein, carbohydrate and lipid concentrations, prokaryote abundance and aminopeptidase activity. Sediments of the NW Adriatic Sea displayed high organic loads, tightly coupled with the outflow dynamics of the Po River. A major flooding event was responsible of an enhanced accumulation of organic material on the sea bottom. The resulting increased nutrient load in the sediment impaired organic matter degradation processes. The results of the present study suggest that the enhanced trophic state of marine coastal sediments subjected to riverine inputs are related not only to the increased nutrient inputs, but that they may be amplified by impaired degradation processes.

Polychlorinated biphenyls (PCBs) in sediments from the western Adriatic Sea: Sources, historical trends and inventories

Sources, historical trends and inventories of polychlorinated biphenyls (PCBs) were investigated in sediments collected in five transects along the north-south axis of the western Adriatic Sea. The concentration of total PCBs (∑28 PCBs) ranged from <LOD (limit of detection) to 9.0ngg(-1) in the sediment cores and between 0.1 and 2.2ngg(-1) in recent sediments. Chronological records of PCB concentrations displayed a common pattern with historical PCB production and use, with the maximum peak values detected between the 1960s and the 1980s. Sediments deposited within the last two decades presented a ~40% to ~80% PCB reduction in comparison to the peak levels, reflecting the ban on PCB production and use since the late 1970s. PCB levels along with the presence of high-chlorinated congeners decreased southwards, indicating the Po River as the major source of PCBs in the western Adriatic Sea. This is further corroborated by the estimated inventories of PCBs, which were ~4-7 times higher in the Po River prodelta (256ngcm(-2)) in comparison to the middle and southern Adriatic, respectively, and about 100 times higher than the in the deep Adriatic Sea.

Historical pattern and mass balance of trace metals in sediments of the northwestern Adriatic Sea Shelf

In view of the recent action in Marine Strategy Framework Directive, reconstructing the history of anthropogenic metal inputs and calculating the budgets for the northwestern part of the Italian Adriatic basin can provide a benchmark for comparison with new evidences and enlighten recent environmental changes. Among the metals, the attention was focused on Pb and Zn, as they provide the most significant anthropogenic signals. In 1988, areal distributions clearly identified the Po, Adige and Brenta rivers as the main sources of contaminants. The study area was divided in three compartments. The area in front of the Po delta represented a sink for metals but the accumulation of Zn and Pb integrated over the entire study area suggests an effective export throughout southern boundary. Most concentration-depth/year profiles in cores showed an upward increase from the Italian Unification (1861), with a still significant anthropogenic supply at the time of sampling.

Reexposure and advection of 14C‐depleted organic carbon from old deposits at the upper continental slope

represents an additional source of 14 C‐depleted organic carbon supplied to the ocean, in parallel with the weathering of fossil organic carbon delivered by rivers from land. To understand the dynamics and implications of this reexposure at the shelf edge, a biogeochemical study was carried out in the Gulf of Lions (Mediterranean Sea) where erosive processes, driven by shelf dense water cascading, are currently shaping the seafloor at the canyon heads. Mooring lines equipped with sediment traps and current meters were deployed during the cascading season in the southwestern canyon heads, whereas sediment cores were collected along the sediment dispersal system from the prodelta regions down to the canyon heads. Evidence from grain‐size, X‐radiographs and 210 Pb activity indicate the presence in the upper slope of a shelly‐coarse surface stratum overlying a consolidated deposit. This erosive discontinuity was interpreted as being a result of dense water cascading that is able to generate sufficient shear stress at the canyon heads to mobilize the coarse surface layer, eroding the basal strata. As a result, a pool of aged organic carbon (D 14 C= −944.5 ± 24.7‰; mean age 23,650 ± 3,321 ybp) outcrops at the modern seafloor and is reexposed to the contemporary carbon cycle. This basal deposit was found to have relatively high terrigenous organic carbon (lignin = 1.48 ± 0.14 mg/100 mg OC), suggesting that this material was deposited during the last low sea‐level stand. A few sediment trap samples showed anomalously depleted radiocarbon concentrations (D 14 C= −704.4 ± 62.5‰) relative to inner shelf (D 14 C= −293.4 ± 134.0‰), mid‐shelf (D 14 C= −366.6 ± 51.1‰), and outer shelf (D 14 C= −384 ± 47.8‰) surface sediments. Therefore, although the major source of particulate material during the cascading season is resuspended shelf deposits, there is evidence that this aged pool of organic carbon can be eroded and laterally advected downslope.

Mediterranean circulation perturbations over the last five centuries: Relevance to past Eastern Mediterranean Transient-type events

The Eastern Mediterranean Transient (EMT) occurred in the Aegean Sea from 1988 to 1995 and is the most significant intermediate-to-deep Mediterranean overturning perturbation reported by instrumental records. The EMT was likely caused by accumulation of high salinity waters in the Levantine and enhanced heat loss in the Aegean Sea, coupled with surface water freshening in the Sicily Channel. It is still unknown whether similar transients occurred in the past and, if so, what their forcing processes were. In this study, sediments from the Sicily Channel document surface water freshening (SCFR) at 1910 ± 12, 1812 ± 18, 1725 ± 25 and 1580 ± 30 CE. A regional ocean hindcast links SCFR to enhanced deep-water production and in turn to strengthened Mediterranean thermohaline circulation. Independent evidence collected in the Aegean Sea supports this reconstruction, showing that enhanced bottom water ventilation in the Eastern Mediterranean was associated with each SCFR event. Comparison between the records and multi-decadal atmospheric circulation patterns and climatic external forcings indicates that Mediterranean circulation destabilisation occurs during positive North Atlantic Oscillation (NAO) and negative Atlantic Multidecadal Oscillation (AMO) phases, reduced solar activity and strong tropical volcanic eruptions. They may have recurrently produced favourable deep-water formation conditions, both increasing salinity and reducing temperature on multi-decadal time scales.

Atmospheric CO2 concentrations and δ13C values across the Antarctic Circumpolar Current between New Zealand and Antarctica

Measurements of atmospheric CO2 concentrations were repeatedly carried out on the vessel ‘Italica’ of the Italian National Research Program in Antarctica, during cruises from Italy to Antarctica. Discrete air samples were also collected in 4-L Pyrex flasks during these cruises in order to carry out δ13C analyses on atmospheric CO2. The results acquired between New Zealand and Antarctica are reported here. The mean growth rate of the CO2 concentration from 1996 to 2003 in this area of the Southern Oceans is of about 1.8 ppmv yr-1, in good agreement with NOAA/CMDL measurements. The rates of increase from cruise to cruise are rather variable. From 1996.1997 to 1998.1999 cruise the yearly growth rate is 2.75 ppmv yr-1, close to the large growth rates measured in several areas and mainly related to the most severe El Ni.no event of the last years. The other yearly growth rates are of about 1.3 and 2 ppmv for the periods 1998.1999 to 2001.2002 and 2001.2002 to 2003.2004, respectively. The large difference between these two values is probably related to the uncertainty on the only two 2001.2002 discrete measurements of CO2 concentration in this area. The measured δ13C values show two completely different distributions and a large interannual variability. The 1998.1999, 2002.2003, and 2003.2004 results obtained between about 55.S and 65.S across the Antarctic Polar Front show a marked negativization of up to more than 2° when compared to the background values. The results are related to local source regions of CO2, as frequently found in the Southern Ocean by several authors; the negative δ13C values are tentatively related to the possible contribution of different causes. Among them, the southward negative gradient of δ13C of the dissolved inorganic carbon, the contribution from upwelling deep waters and from subsurface processes between the Northern SubAntarctic Front and the Polar Front, and, partly, the contribution of CO2 of biogenic origin, e.g. from heterotrophic activity. The 2001.2002 results are very homogeneous and almost constant, close to .8.5% showing only minor deviations from the oceanic background values. This behaviour may be related to differences in the frontal structure along the 2001.2002 track.