Lester J. McKee

Transport and retention of nitrogen and phosphorus in the sub-tropical Richmond River estuary, Australia - a budget approach.

Nitrogen and phosphorus loads in the sub-tropicalRichmond River estuary were quantified and materialbudgets were developed over two years of contrastingfreshwater discharge. During both years >74% of thenitrogen and >84% of the phosphorus load enteredthe estuary during one month when flooding occurred inthe catchment. Due to larger flood magnitude, loadsduring the 1995/96 year were 3.3 and 2.5 times greaterthan during the 1994/95 year for nitrogen andphosphorus respectively. During floods the estuarinebasin was completely flushed of brackish water and themajority of the nutrient loads passed directly throughthe estuary. The nutrient load retained in the estuaryduring floods was inversely proportional to floodmagnitude. Annual budgets show that >97% of thenutrient load entering the estuary was from diffusecatchment sources; precipitation, urban runoff, andsewage were negligible. Less than 2.5% of thenitrogen and <5.4% of the phosphorus loads enteringthe estuary were retained in sediments. During dryseasons the estuary became a net sink for nitrogeninput from the ocean and the estuarine sedimentsremained a net source of phosphorus to the watercolumn and ocean. The process of flood scouring islikely to be the cleansing mechanism responsible formaintaining water quality both on an annual basis andover the last 50 years and may also be responsible forpotential nitrogen limitation. The sub-tropicalRichmond River estuary contrasts with the majority oftemperate systems of North America and Europe whichtypically have lower inter- and intra-annual nutrientload variability, longer and less variable flushingtimes, and greater nutrient retention.

Intra- and interannual export of nitrogen and phosphorus in the subtropical Richmond River catchment, Australia

Nitrogen and phosphorus concentrations were measured and exports were calculated in the subtropical Richmond River catchment between July 1994 and June 1996. A stratified sampling approach was adopted owing to the extreme and rapid changes in riverine discharge, which varied by up to 10 000 times over the study period. Nutrient concentrations were lowest during baseflow. During storm discharge, dissolve inorganic and organic and particulate nitrogen and phosphorus concentrations increased two- to five fold, and followed hysteresis patterns that were attributed to the integration and/or depletion of catchment nutrient sources during an event. Dissolved organic nitrogen and particulate phosphorus were the dominant nutrient forms. Land use and antecedent conditions had a large influence on nutrient concentrations and exports. During the 1995–96 year (slightly above the mean annual discharge) 96% of nitrogen and 98% of phosphorus loads were transported in less than 6% of the time. When averaged across the catchment, monthly riverine nutrient loads varied by up to 1061-fold during the study and exports were approximately four-fold greater during the second year relative to the first. The subtropical Richmond River catchment has greater intra- and potential interannual variability in nutrient loads and exports when compared with temperate catchments from other parts of the world. It is suggested that in tropical and subtropical Australian catchments with large intra- and interannual variation in discharge, the need for parameterizing the antecedent conditions, such as the degree of nutrient storage, may make it difficult to model spatial and temporal (short time-scale) nutrient exports. Copyright

Influence of climate,geology and humans on spatial and temporal nutrient geochemistry in the subtropical Richmond River catchment, Australia

Water quality was monitored on a spatial and temporal basis in the subtropical Richmond River catchment over two years. Nutrient concentrations varied seasonally in a complex manner with highest concentrations (maximum =3110 µg N L – 1 and 572 µg P L –1 ) associated with floods. However, median (444 µg N L – 1 and 55 µg P L – 1 ) concentrations were relatively low compared with other parts of the world. The forms of nitrogen and phosphorus in streams varied seasonally, with greater proportions of inorganic nitrogen and phosphorus during the wet season. Minimum nutrient concentrations were found 2—3 months after flood discharge. With the onset of the dry season, concentration increases were attributed to point sources and low river discharge. There were statistically significant relationships between geology and water quality and nutrient concentrations increased downstream and were significantly related to population density and dairy farming. In spite of varying geology and naturally higher phosphorus in soils and rocks in parts of the catchment, anthropogenic impacts had the greatest effects on water quality in the Richmond River catchment. Rainfall quality also appeared to be related both spatially and seasonally to human activity. Although the responses of the subtropical Richmond River catchment to changes in land use are similar to those of temperate systems of North America and Europe, the seasonal patterns appear to be more complex and perhaps typical of subtropical catchments dominated by agricultural land use.

Nitrogen and phosphorus budgets for the sub-tropical Richmond River catchment, Australia

Nitrogen and phosphorus budgets were developed forfour sub-catchments in the Richmond River catchmentfor two study years. The catchment is used for avariety of farming pursuits including dairying, beef,cropping, fruit, nuts, forestry, and sugar cane. Eachsub-catchment varies in hydrology, the proportion ofeach land use, and the population density whichenabled a unique opportunity to study fluxes andstorage associated with a variety of environmentalfactors. Total loadings entering each sub-catchmentvaried from 12 to 57 kg ha−1yr−1 fornitrogen and 0.25 to 6.6 kg ha−1yr−1 forphosphorus with little inter-annual variation.Averaged across the whole catchment, nitrogen fixation(47%) dominated the inputs; fertiliser (26%) andrainfall (21%) made up the next largest inputs.Fertiliser inputs dominated the phosphorus budget(65.5%); rainfall and manures making up 13% and 12%respectively. Produce dominated the outputs of bothnitrogen and phosphorus from the four sub-catchmentsbeing greater than the riverine export. The deliveryof nitrogen to catchment streams ranged from <1 to24% of the total inputs and the delivery of phosphorus to catchment streams ranged from <1 to 39%. Storage of phosphorus in catchment soils varied between −0.32 and 4.46 kg ha−1yr−1. Whendenitrification and volatilisation were estimated using data from other studies, storage of nitrogen ranged from 1 to 24 kg ha−1yr−1. Despite theepisodic nature of runoff in the sub-tropical RichmondRiver catchment, the magnitude of nutrient fluxes andstorage appear similar to other catchments of theworld which have mixed land use and relatively lowcatchment nutrient loadings.