Leticia S. Pibida

Revision of the NIST Standard for (223)Ra: New Measurements and Review of 2008 Data.

After discovering a discrepancy in the transfer standard currently being disseminated by the National Institute of Standards and Technology (NIST), we have performed a new primary standardization of the alpha-emitter 223Ra using Live-timed Anticoincidence Counting (LTAC) and the Triple-to-Double Coincidence Ratio Method (TDCR). Additional confirmatory measurements were made with the CIEMAT-NIST efficiency tracing method (CNET) of liquid scintillation counting, integral γ-ray counting using a NaI(Tl) well counter, and several High Purity Germanium (HPGe) detectors in an attempt to understand the origin of the discrepancy and to provide a correction. The results indicate that a −9.5 % difference exists between activity values obtained using the former transfer standard relative to the new primary standardization. During one of the experiments, a 2 % difference in activity was observed between dilutions of the 223Ra master solution prepared using the composition used in the original standardization and those prepared using 1 mol·L−1 HCl. This effect appeared to be dependent on the number of dilutions or the total dilution factor to the master solution, but the magnitude was not reproducible. A new calibration factor (“K-value”) has been determined for the NIST Secondary Standard Ionization Chamber (IC “A”), thereby correcting the discrepancy between the primary and secondary standards.

Use of resonance ionization mass spectrometry for determination of Cs ratios in solid samples

A method to quantitatively determine the radionuclidic content of complex samples with a minimum of chemical preparation has been under development at the National Institute of Standards and Technology (NIST). Based on earlier studies with resonance ionization mass spectrometry (RIMS), a graphite furnace was added to the RIMS system at NIST. Efficiency determinations for 133Cs in solution and isotopic ratio measurements of cesium (135Cs/137Cs) for an NIST nuclear burn-up sample using RIMS and for a sediment natural matrix standard using thermal ionization mass spectrometry are presented.

Evaluation of Handheld Radionuclide Identifiers

Characterization of commercially available instruments for measurement and identification of unknown radionuclides was carried out in support of the development and testing of the American National Standards Institute (ANSI) standard, N42.34, “Performance Criteria for Hand-held Instruments for the Detection and Identification of Radionuclides.” Measurements were based on the performance of the devices, i.e., the capability of the detectors to ensure a correct radionuclide identification in a given time interval for various radioactive sources.

Development of a calibration methodology for large-volume, solid 68Ge phantoms for traceable measurements in positron emission tomography

We have developed a methodology to calibrate the (68)Ge activity concentration in large (9L) cylindrical epoxy phantoms in a way that is traceable to national standards. The method was tested on two prototype cylindrical phantoms that are being used in a clinical trial and gave (68)Ge activity concentration values with combined standard uncertainties of about 1.1%. Imaging data from the phantoms using a calibrated PET-CT scanner gave values consistent with the calibrated activity concentrations within experimental uncertainties.

A new primary standardization of 229Th.

The National Institute of Standards and Technology (NIST) has certified a high-purity (229)Th Standard Reference Material as SRM 4328C, based on live-timed 4pialphabeta-gamma anticoincidence counting (LTAC) of the equilibrium solution. The LTAC system was optimized to minimize the uncertainty in the result due to the two short-lived ground-states present in the decay chain. Confirmatory measurements were carried out by four other methods. Furthermore, the present absolute activity and measured gamma-ray emission rates were combined to obtain gamma-ray emission probabilities.

Calibration of Traceable Solid Mock (131)I Phantoms Used in an International SPECT Image Quantification Comparison.

The International Atomic Energy Agency (IAEA) has organized an international comparison to assess Single Photon Emission Computed Tomography (SPECT) image quantification capabilities in 12 countries. Iodine-131 was chosen as the radionuclide for the comparison because of its wide use around the world, but for logistical reasons solid 133Ba sources were used as a long-lived surrogate for 131I. For this study, we designed a set of solid cylindrical sources so that each site could have a set of phantoms (having nominal volumes of 2 mL, 4 mL, 6 mL, and 23 mL) with traceable activity calibrations so that the results could be properly compared. We also developed a technique using two different detection methods for individually calibrating the sources for 133Ba activity based on a National standard. This methodology allows for the activity calibration of each 133Ba source with a standard uncertainty on the activity of 1.4 % for the high-level 2-, 4-, and 6-mL sources and 1.7 % for the lower-level 23 mL cylinders. This level of uncertainty allows for these sources to be used for the intended comparison exercise, as well as in other SPECT image quantification studies.

The National Institute of Standards and Technology glow discharge resonance ionization mass spectrometry system

A new resonance ionization mass spectrometry system at the National Institute of Standards and Technology using glow discharge atomization and continuous-wave lasers has been developed. Low concentrations of 133Cs in a silver matrix have been measured using this new system. In addition a detailed characterization of the glow discharge source and laser ionization processes are made.

Determination of photon emission probabilities for the main gamma-rays of 223Ra in equilibrium with its progeny

The currently published (223)Ra gamma-ray emission probabilities display a wide variation in the values depending on the source of the data. The National Institute of Standards and Technology performed activity measurements on a (223)Ra solution that was used to prepare several sources that were used to determine the photon emission probabilities for the main gamma-rays of (223)Ra in equilibrium with its progeny. Several high purity germanium (HPGe) detectors were used to perform the gamma-ray spectrometry measurements.

Measurements of the 82Sr half-life.

Half-life of (82)Sr was measured at the National Institute of Standards and Technology (NIST) using gamma-ray spectrometry and a 4pigamma pressurized ionization chamber. The (82)Sr half-life was found to be 25.36+/-0.03 days (k=1) according to gamma-ray spectrometry and 25.34+/-0.02 days (k=1) according to the 4pigamma pressurized ionization chamber measurements.

Measurements for the Development of a Simulated Naturally Occurring Radioactive Material

Nineteen different commercially available samples containing naturally occurring radioactive materials (NORM) (i.e., natural uranium, thorium, radium and potassium) were investigated, including zircon sand, cat litter, roofing tiles, ice melt and fertilizer among others. A large variation in isotopic composition was observed across the measured samples. As a result of this observation, a need was identified to develop and implement the use of a simulated NORM sample to serve as a reference standard sample containing naturally occurring radioactive elements. The purpose of the simulated NORM sample would be to simulate typical samples containing NORM to be used for testing radiation detection instruments against ANSI/IEEE and IEC document standards requirements. The design and construction of the proposed new simulated NORM sample and the subsequent energy spectra characterization measurements are presented as part of this work.