Li-bin Pang

Luminescent characteristics of Ba3 Y2(BO3)4:Eu3+ phosphor for white LED

Abstract The Ba 3 Y 2 (BO 3 ) 4 :Eu 3+ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5 D 0- 7 F 2 transition of Eu 3+ , under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba 3 Y 2 (BO 3 ) 4 :Eu 3+ phosphor was effectively excited by ultraviolet (UV) (254, 365 and 400 nm) and blue (470 nm) light. The effect of Eu 3+ concentration on the 613 nm emission of the Ba 3 Y 2 (BO 3 ) 4 :Eu 3+ phosphor was measured. The results showed that the emission intensity increased with increasing Eu 3+ concentration, and then decreased. The CIE color coordinates of Ba 3 Y 2 (BO 3 ) 4 :Eu 3+ phosphor were x =0.641 and y =0.359 at 15 mol.% Eu 3+ .