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无机材料学报 | 2014

Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @V 2 O 5 核壳复合材料的制备及其电化学性能

Nie Wen-Bo; Xiao Qi-Chang; Wang Jing-Liang; Lei Gangtie; Xiao Qizhen; Li Zhaohui

采用溶胶-凝胶技术在富锂锰基固溶体Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 表面包覆V 2 O 5 , 制备了Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @ V 2 O 5 核壳复合材料。通过扫描电镜(SEM)和透射电镜(TEM)观察其形貌, X射线衍射(XRD)分析确定其结构。结果显示, 结晶态的V 2 O 5 均匀包覆在类球形Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 颗粒表面, Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 材料的晶体结构在包覆前后保持不变。X射线光电子能谱(XPS)分析结果表明, 该核壳复合材料首次充电时, 锂离子嵌入V 2 O 5 包覆层。电化学测试结果表明, 表面包覆15%V 2 O 5 的核壳复合材料具有最佳的电化学性能: 0.1 C 倍率下放电比容量为276 mAh/g, 首次充放电库仑效率达到94%, 50次循环后容量保持率达89%。采用溶胶-凝胶技术在富锂锰基固溶体Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 表面包覆V 2 O 5 , 制备了Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @ V 2 O 5 核壳复合材料。通过扫描电镜(SEM)和透射电镜(TEM)观察其形貌, X射线衍射(XRD)分析确定其结构。结果显示, 结晶态的V 2 O 5 均匀包覆在类球形Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 颗粒表面, Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 材料的晶体结构在包覆前后保持不变。X射线光电子能谱(XPS)分析结果表明, 该核壳复合材料首次充电时, 锂离子嵌入V 2 O 5 包覆层。电化学测试结果表明, 表面包覆15%V 2 O 5 的核壳复合材料具有最佳的电化学性能: 0.1 C 倍率下放电比容量为276 mAh/g, 首次充放电库仑效率达到94%, 50次循环后容量保持率达89%。


Journal of Nanoscience and Nanotechnology | 2016

Freestanding Silver-Coated Co3O4 Nanosheets Network as Anode of Lithium Ion Batteries with High Capacity and Rate Capability

Luo Zhongping; Wu Lijun; Lei Gangtie; Li Zhaohui; Sun Tianlei; Xiao Qizhen


Archive | 2014

Three-dimensional porous nanocarbon composite lithium manganate spherical positive electrode material and preparation method thereof

Li Zhaohui; Zhang Honglai; Xiao Qizhen; Lei Gangtie


Journal of Inorganic Materials | 2018

Ferric Oxide-reduced Graphene Oxide Composite Material: Synthesis Based on Covalent Binding and Its Lithium-Storage Property

Qin Shi-Lin; Li Ji-Cheng; Li Zhaohui; Hu Zhongliang; Ding Yan-Huai; Lei Gangtie; Xiao Qizhen


Archive | 2017

Method for preparing nano zinc oxide by electrolysis

Zhan Pengxin; Xiao Qizhen; Cao Zhen; Wang Xingzhu; Li Zhaohui; Lei Gangtie; Zhang Teng; Zhang Libing; Zhu Jinyun


Archive | 2017

Preparation method of lithium-ion battery cathode material silica aerogel

Xiao Qizhen; Liu Xiongfeng; Li Zhaohui; Lei Gangtie


Archive | 2017

Magnesium doped vanadium pentoxide/carbon compound positive electrode material and preparation method of magnesium doped vanadium pentoxide/carbon compound positive electrode material

Li Zhaohui; Xiao Fang; Song Xuexia; Xiao Qizhen; Lei Gangtie


Archive | 2017

Preparation method of power type nanometer lithium manganate

Xiao Qizhen; Cao Zhen; Li Zhaohui; Lei Gangtie


Archive | 2017

Molybdenum and bismuth composite oxide, preparation method thereof, and organic solar cell

Lei Gangtie; Cai Yufeng; Chen Xiaolan; Wang Xiangdong; Xiao Qizhen; Li Zhaohui


Archive | 2016

Gel polymer electrolyte membrane and preparation method thereof

Li Zhaohui; Li Wenjun; Liu Hongyan; Xiao Qizhen; Lei Gangtie

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