Lijuan Han

A novel micro-nano structure profile control agent: graphene oxide dispersion

Graphite oxide sheet, now referred to as graphene oxide (GO), is the product of chemical exfoliation of graphite and has been known for more than a century. A GO sheet is characterized by two abruptly different length scales; the apparent thickness of the functionalized carbon sheet is approximately 1 nm, but the lateral dimensions can range from a few nanometers to micrometers. In this paper, an improved method for the preparation of graphene oxide within a mild condition is described. We have found that cancelling the high-temperature stage and prolonging the reaction time of mid-temperature can improve the efficiency of oxidation process. We utilized FTIR, XRD, Ultraviolet-visible, TGA, Raman spectrum, and XPS measurements to characterize the successfully synthesized GO. SEM images were employed to reveal the interior microstructure of as-prepared GO dispersion. We also wondrously found that the GO dispersion could be used as profile control agent in the oilfield water-flooding. Flooding experiments showed that the GO dispersion has an ability to adjust water injection profile, reduce permeability ratio, and improve conformance factor. So the GO dispersion would have potential applications in oilfield exploitation.

Synthesis and Performance of Functionalized α-Zirconium Phosphate Modified with Octadecyl Isocyanate

The α-zirconium phosphate (α-ZrP) and hydrophobically modified α-zirconium phosphate (α-ZrP-I) were prepared. The grafting of octadecyl isocyanate was confirmed by Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The dispersion of α-ZrP-I was studied by environmental scanning electron microscopy (SEM). The wettability of α-ZrP-I was determined by Kruss DSA30. Then, the effects of decompression and augmented injection of α-ZrP-I have been studied. The results of water flooding experiments show that the appropriate concentration of α-ZrP-I has an effect on the decrease of the water injection pressure.