Liling Fu

Efficient CO2 sorbents based on silica foam with ultra-large mesopores

A series of high-capacity, amine impregnated sorbents based on a cost-effective silica foam with ultra-large mesopores is reported. The sorbents exhibit fast CO2 capture kinetics, high adsorption capacity (of up to 5.8 mmol g−1 under 1 atm of dry CO2), as well as good stability over multiple adsorption–desorption cycles. A simple theoretical analysis is provided relating the support structure to sorbent performance.

Sponges with covalently tethered amines for high-efficiency carbon capture

Adsorption using solid amine sorbents is an attractive emerging technology for energy-efficient carbon capture. Current syntheses for solid amine sorbents mainly based on physical impregnation or grafting-to methods (for example, aminosilane-grafting) lead to limited sorbent performance in terms of stability and working capacity, respectively. Here we report a family of solid amine sorbents using a grafting-from synthesis approach and synthesized by cationic polymerization of oxazolines on mesoporous silica. The sorbent with high amount of covalently tethered amines shows fast adsorption rate, high amine efficiency and sorbent capacity well exceeding the highest value reported to date for low-temperature carbon dioxide sorbents under simulated flue gas conditions. The demonstrated efficiency of the new amine-immobilization chemistry may open up new avenues in the development of advanced carbon dioxide sorbents, as well as other nitrogen-functionalized systems.

Synthesis and Carbon Dioxide Sorption of Layered Double Hydroxide/Silica Foam Nanocomposites with Hierarchical Mesostructure

Layered double hydroxides (LDHs) with a hierarchical mesostructure are successfully synthesized on mesoporous silica foams by simple impregnation and hydrothermal treatment. The as-synthesized LDH/silica foam nanocomposites show well-defined mesostructures with high surface areas, large pore volumes, and mesopores of 6-7 nm. The nanocomposites act as carbon dioxide (CO2 ) sorbents under simulated flue gas conditions. They also exhibit significantly enhanced CO2 capacities under high-pressure conditions and high CO2 /N2 and CO2 /CH4 selectivities.

Superhydrophilic Wrinkle-free Cotton Fabrics via Plasma and Nanofluid Treatment

We demonstrate in this study a wrinkle-free, superhydrophilic cotton fabric (contact angle ∼0°) by uniformly attaching specially engineered nanoparticles to plasma-pretreated cotton fabric. Because of their highly charged nature, the nanoparticles are firmly anchored on the fabric via electrostatic interactions, as confirmed by microscopy and chemical analyses. The durability of wetting behavior and wrinkle-free property of the nanoparticle-coated fabrics were evaluated via aging, laundering, and abrasion tests. The strongly attached coatings are stable enough to maintain their superhydrophilic nature even after 60 days of aging at room temperature, 50 laundering cycles, and 25 000 abrasion cycles. Moreover, the nanoparticle-coated superhydrophilic fabrics exhibit great wrinkle-recovery property, tensile strength, and abrasion resistance performance up to 25 000 abrasion cycles.