Lindsay Miller

Spatial Variability and Application of Ratios between BTEX in Two Canadian Cities

Spatial monitoring campaigns of volatile organic compounds were carried out in two similarly sized urban industrial cities, Windsor and Sarnia, ON, Canada. For Windsor, data were obtained for all four seasons at approximately 50 sites in each season (winter, spring, summer, and fall) over a three-year period (2004, 2005, and 2006) for a total of 12 sampling sessions. Sampling in Sarnia took place at 37 monitoring sites in fall 2005. In both cities, passive sampling was done using 3M 3500 organic vapor samplers. This paper characterizes benzene, toluene, ethylbenzene, o, and (m + p)-xylene (BTEX) concentrations and relationships among BTEX species in the two cities during the fall sampling periods. BTEX concentration levels and rank order among the species were similar between the two cities. In Sarnia, the relationships between the BTEX species varied depending on location. Correlation analysis between land use and concentration ratios showed a strong influence from local industries. Use one of the ratios between the BTEX species to diagnose photochemical age may be biased due to point source emissions, for example, 53 tonnes of benzene and 86 tonnes of toluene in Sarnia. However, considering multiple ratios leads to better conclusions regarding photochemical aging. Ratios obtained in the sampling campaigns showed significant deviation from those obtained at central monitoring stations, with less difference in the (m + p)/E ratio but better overall agreement in Windsor than in Sarnia.

Challenges and Alternatives to Plastics Recycling in the Automotive Sector

Plastics are increasingly a preferred material choice in designing and developing complex, consumer products, such as automobiles, because they are mouldable, lightweight, and are often perceived to be highly recyclable materials. However, actually recycling the heterogeneous plastics used in such durable items is challenging, and presents very different scenarios to how simple products, such as water bottles, are recovered via curbside or container recycling initiatives. While the technology exists to recycle plastics, their feasibility to do so from high level consumer or industrial applications is bounded by technological and economical restraints. Obstacles include the lack of market for recyclates, and the lack of cost efficient recovery infrastructures or processes. Furthermore, there is a knowledge gap between manufacturers, consumers, and end-of-life facility operators. For these reasons, end-of-life plastics are more likely to end up down-cycled, or as shredder residue and then landfilled. This paper reviews these challenges and several alternatives to recycling plastics in order to broaden the mindset surrounding plastics recycling to improve their sustainability. The paper focuses on the automotive sector for examples, but discussion can be applied to a wide range of plastic components from similarly complex products.

Spatial Variability of Volatile Organic Compound Concentrations in Sarnia, Ontario, Canada

As part of a community health study, an air quality investigation was carried out in Sarnia, Ontario, Canada, which is located within a government-designated “Area of Concern”. The Sarnia area, also known as Chemical Valley, has been known to have an abundance of air quality problems that are frequently attributed to the large number of chemical companies located in the area, which are among the largest industrial sources of criteria air pollutants in Canada. Ambient volatile organic compounds (VOC) were monitored during a 2-wk period in October 2005 at 37 sites across the city of Sarnia, using 3M organic vapor monitors. The spatial variability was investigated using ranking and mapping techniques to identify spatial patterns of the VOC across the city. The results show a large spatial variability of most of the VOC investigated. Furthermore, most of the VOC were highly correlated, suggesting common sources in Sarnia. The results also indicate that the industrial and chemical facilities strongly influence the concentrations of VOC in Sarnia, with higher outdoor VOC levels found closer to industrial facilities. The measured VOC and those obtained from a long-term government monitoring station were compared. It was determined that the exposure gradients observed during the study period are relatively representative of the long-term pattern. The results of this study will be used for the community health study.

Innovative financing for renewable energy project development – recent case studies in North America

Abstract Renewable energy can address increasing energy demand while mitigating the effects of climate change. High capital costs and long payback periods require most projects to secure financing for a portion of the initial costs. Market-based incentives and policies can be credited with lowering development costs, but these come with uncertainties and expiration dates. To secure financing, project developers have turned to innovative mechanisms. This paper presents case studies of innovative financing for renewable energy development in North America. Examples include financing through public capital vehicles, hybrid and carbon bonds, and through corporate power purchase agreements. The objective is to determine which mechanisms or which components of these financing packages are replicable for the purpose of encouraging developers to seek the most advantageous solutions.