Linfield C. Brown

Lead and Methylene Chloride Exposures Among Automotive Repair Technicians

Potential exposures among repair technicians engaged in vehicle resurfacing operations prior to spray painting have not been thoroughly characterized. Environmental and personal air monitoring conducted in the State of Rhode Island have shown that automotive repair technicians may be exposed to metal particulates in sanding dust and methylene chloride vapors during vehicle paint removal operations. Hand wipe samples demonstrated that metals in sanding dust adhered to the hands of workers throughout the duration of the work day and were available for incidental ingestion from the handling of food/nonfood items and hand-to-mouth contact. A blood lead (PbB) screening effort among 21 workers at 2 facilities showed that 4 non-/less-exposed workers had mean PbB levels at the U.S. geometric mean of 2.8 μg/dL, while 2 out of 9 (22%) dedicated vehicle repair technicians had PbB levels at or above 30 μg Pb/dL whole blood—the level for potential adverse reproductive effects. Methylene chloride exposures were also found to exceed the Occupational Safety and Health Administrations (OSHA) 8-hr time-weighted average (TWA) action level and permissible exposure limit (PEL) in a limited number of samples (120 and 26 ppm, integrated work shift samples). Our findings suggest that thousands of professional technicians and vocational high school students may be at increased risk of adverse reproductive and/or other systemic effects.

Assessing the Performance of Reaeration Prediction Equations

AbstractThe overall performance of 18 commonly used reaeration rate coefficient prediction equations was evaluated using statistical metrics of prediction accuracy and bias by comparing predicted reaeration coefficients to a database of values measured using gas tracer techniques. Adapting a commonly applied concept, predictive equations were evaluated in discrete regions of the velocity-depth space. Results indicate that rarely is there a single best prediction equation in a given velocity-depth region, rather there usually is a group of statistically indistinguishable top-performing equations. Also, no single reaeration equation performed well over all hydraulic conditions. Prediction equations, which include slope as a variable are more accurate and have lower bias than those that do not. However, even the top-performing equations exhibited large prediction errors of at least 40–50% and exceeded 100% in some regions. This level of error in predicting reaeration rate coefficients will continue to have a...

Chemical Characterization of Sanding Dust and Methylene Chloride Usage in Automotive Refinishing: Implications for Occupational and Environmental Health

Surface preparation activities conducted during automotive refinishing present several potential human health and environmental risks. This study examines the chemical composition of vehicle sanding dust and the prevalence of methylene chloride use as a basis for evaluating potential chemical exposures in the work environment, fugitive environmental releases, and take-home toxics. This article reports on the findings of (1) a statewide technology and work practices survey of 353 licensed auto body shops and (2) laboratory analyses of sanding dust representing more than 200 vehicles, 10 commercial body filler compounds, and work shirts worn during vehicle sanding while using nonventilated equipment. Survey data revealed that the majority of shops (78%) do not use ventilated sanding equipment, that most workers (55%) take their work clothes and shoes home at the end of the workday, and that 17% of the respondents used a methylene chloride-based paint stripper as an adjunct to mechanical sanding. Laboratory results showed that Pb, As, Cr, Mn, and Ni were present in the sanding dust at every facility tested. Lead concentrations in sanding dust were found to be highest at facilities that performed complete vehicle refinishing (range 770 to 7300 ppm) and at a collision repair shop that used a high-lead content body filler compound (1800 ppm). Hexavalent chromium also was found in two vocational high school paint dust samples at concentrations of 54 and 710 ppm. When total lead and chromium concentrations reached 7300 and 2300 ppm, respectively, facility sanding dust samples failed the U.S. Environmental Protection Agencys Toxicity Characteristic Leaching Procedure for hazardous waste. Metals found in the sanding dust also were present on the work shirts of technicians-ranging from 0.06 (Cd) to 81 (Mg) microg/inch2 of cloth-who sanded on paint without ventilated equipment. Results suggest that sanding dust and methylene chloride paint strippers used in vehicle resurfacing operations pose a potential hazard to human health and the environment.

APPLICATION OF EXPERT SYSTEMS TECHNOLOGY IN WATER QUALITY MODELING

ABSTRACT Computerized modeling is becoming an integral part of decision making in water pollution control. Expert systems is an innovative methodology that can assist in building, using, and interpreting the output of these models. This paper reviews the use and evaluates the potential of expert systems technology in environmental modeling and describes elements of an expert advisor for the stream water quality model QUAL2E. Some general conclusions are presented about the tools available to develop this system, the level of available technology in knowledge-based engineering, and the value of approaching problems from a knowledge engineering perspective.

Modeling the oxidation of sulfide in pulp and paper wastewaters.

Reactor experiments were conducted to study aerobic sulfide oxidation in pulp and paper wastewaters under typical operating conditions. Data produced from these experiments were used to develop a set of sequential rate equations that describe the significant sulfide and oxygen processes in the reactors. Model parameters were estimated for three different pulp and paper wastewaters using a multiresponse procedure. The sulfide oxidation rate coefficients for the wastewaters ranged from 0.108 to 0.155  min−1 at 35°C and approximately neutral pH. The reaction order with respect to oxygen could not be precisely estimated but appeared to be near the lower boundary for the fitting procedure (essentially zero order). Modeling of the oxygen depletion data provided evidence that the first sulfide oxidation reaction product consumed 0.5 mg of oxygen per mg of sulfide oxidized, suggesting polysulfides and elemental sulfur as the initial reaction products. The oxygen depletion modeling also suggested oxidation of the ...

Effluent carbonaceous biochemical oxygen demand (CBOD) characterization for modern pulp and paper facilities

As receiving water quality models are being used to address dissolved oxygen issues requiring an increased degree of resolution, a more refined characterization of effluent CBOD can become an important aspect of the analysis. The selection and use of kinetic models to identify effluent specific parameters can have a significant impact on this characterization. This study modeled effluents from six pulp and paper facilities in order to reassess the kinetic models, the data, and experimental design used for a typical effluent characterization. The dual first order model fit these effluents with significantly less error than the traditional first order model suggesting a significant fraction of the CBOD is slowly degradable. Because the dual first order model produces a more refined characterization of CBOD kinetics than the first order model, it places an increased demand upon the data used to inform the parameter estimates. Therefore, analysis of the precision of the parameter estimates and methods for improving estimation precision via experimental design are also discussed.