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Publication


Featured researches published by Liu Haiou.


无机材料学报 | 2012

预涂晶种诱导法在α-Al 2 O 3 陶瓷管载体上合成ZIF-8膜

Du Shu-Hui; Liu Yaguang; Kong Lingyin; Zhang Jian; Liu Haiou; Zhang Xiongfu

以纳米级ZIF-8晶体粒子为晶种, 利用晶种诱导二次生长法在α-Al 2 O 3 陶瓷管载体上制备出连续的ZIF-8膜, 并详细考察了晶种涂层液中晶种含量、成膜温度和添加剂PEI、甲酸钠用量等参数对ZIF-8成膜的调控影响. 经SEM、XRD和气体渗透分析结果表明: 制备的ZIF-8纳米粒子的粒径约为100~150 nm, 粒度分布较均匀, 适宜作为成膜的晶种; 在晶种液中添加适量的PEI作为偶联剂有利于连续ZIF-8晶种层及膜的形成; 在成膜液中添加适量的甲酸钠能有效阻止载体表面晶种层的溶解脱落. SEM显示所得ZIF-8膜的晶体粒径均一、晶粒间连接紧密且无明显裂痕, 膜层厚度约为18 μm. 单组分气体渗透测试可知, H 2 /CO 2 的分离因数为5.4, H 2 /CH 4 的分离因数为2.56, 气体通过ZIF-8膜均属于努森扩散范围.以纳米级ZIF-8晶体粒子为晶种, 利用晶种诱导二次生长法在α-Al 2 O 3 陶瓷管载体上制备出连续的ZIF-8膜, 并详细考察了晶种涂层液中晶种含量、成膜温度和添加剂PEI、甲酸钠用量等参数对ZIF-8成膜的调控影响. 经SEM、XRD和气体渗透分析结果表明: 制备的ZIF-8纳米粒子的粒径约为100~150 nm, 粒度分布较均匀, 适宜作为成膜的晶种; 在晶种液中添加适量的PEI作为偶联剂有利于连续ZIF-8晶种层及膜的形成; 在成膜液中添加适量的甲酸钠能有效阻止载体表面晶种层的溶解脱落. SEM显示所得ZIF-8膜的晶体粒径均一、晶粒间连接紧密且无明显裂痕, 膜层厚度约为18 μm. 单组分气体渗透测试可知, H 2 /CO 2 的分离因数为5.4, H 2 /CH 4 的分离因数为2.56, 气体通过ZIF-8膜均属于努森扩散范围.


Archive | 2014

Preparation method of metal organic framework ZIF-8 (zero insert force-9) film

Zhang Xiongfu; Liu Yaguang; Kong Lingyin; Li Shaohui; Liu Haiou; Qiu Jieshan


Archive | 2014

ZIF-8 film-coated Pd/ZnO core-shell catalyst and preparation method thereof

Zhang Xiongfu; Lin Lu; Zhang Tong; Liu Haiou; Qiu Jieshan


Archive | 2013

Preparation method for ZIFs membrane containing zinc adopting sandwich structure and supported by high temperature resistant zinc oxide nanorod

Zhang Xiongfu; Li Shaohui; Liu Yaguang; Kong Lingyin; Liu Haiou; Qiu Jieshan


Archive | 2015

Method for performing induced synthesis on MOFs (metal-organic frameworks) membrane by implanting homologous metal oxide particles into surface of macroporous carrier by virtue of swabbing process

Zhang Xiongfu; Kong Lingyin; Liu Haiou; Qiu Jieshan


Archive | 2014

Method for preparing selectivity-adjustable efficient supported precious-metal core-shell catalyst coated with metal-organic framework ZIF-8 membrane

Zhang Xiongfu; Lin Lu; Zhang Tong; Liu Haiou; Qiu Jieshan


Archive | 2014

Method for preparing encapsulated pure silicon mesoporous MSU-1 (molecular sieve unit-1) molecular sieve membrane core-shell catalyst

Zhang Xiongfu; Zhang Jian; Tu Min; Liu Haiou; Qiu Jieshan


Archive | 2014

Preparation method for metallic oxide-metallic organic material hybrid membrane of reinforced concrete structure

Zhang Xiongfu; Li Shaohui; Liu Yaguang; Liu Haiou; Qiu Jieshan


Archive | 2012

Method for synthesizing phenol from benzene by special micro-channel type titanium silicon-palladium double-layer membrane reactor

Deng Hui; Guo Yu; Liu Haiou; Wang Xiaobin; Zhang Xiongfu


Archive | 2016

Method for preparing monodisperse regular-crystal-shape ZSM-5 molecular sieve by using template-free system

Zhang Xiongfu; Wei Hongpeng; Liu Haiou

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Zhang Xiongfu

Dalian University of Technology

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Chen Gang

Dalian University of Technology

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Gao Ruimin

Dalian University of Technology

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Huo Pengju

Dalian University of Technology

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Li Dapeng

Dalian University of Technology

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Li Si

Dalian University of Technology

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Liu Zhiling

Dalian University of Technology

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Lu Yongbin

Dalian University of Technology

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Pei Ting

Dalian University of Technology

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Wang Chengda

Dalian University of Technology

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