Liukang Xu

On maintaining pressure equilibrium between a soil CO2 flux chamber and the ambient air

[1]xa0Pressure equilibrium between inside a soil CO2 flux chamber and the surrounding air outside the chamber must be maintained during a measurement if measured soil CO2 flux (FCO2) is to accurately represent the rate occurring naturally outside the chamber. In previous studies a simple vent tube connecting to the chamber has often been used to maintain pressure equilibrium. This approach, however, can be effective only under calm conditions. Under windy conditions, negative pressure excursions will occur inside the chamber that are artifacts resulting from wind passing over the vent tubes external open end, a phenomenon known as the Venturi effect. This causes anomalous mass flow of CO2-rich air from the soil into the chamber, leading to a significant overestimation of FCO2. In this present study, we found that negative chamber pressure excursions due to the Venturi effect cannot be observed unless the differential pressure measurement is made with the chamber resting on an impermeable base. Making pressure measurements with a chamber resting on porous soil can lead to the erroneous conclusion that an anomalous mass flow is not a problem precisely when it is causing serious artifacts. We also present a new vent design for a soil CO2 flux chamber capable of maintaining pressure equilibrium between inside the chamber and the ambient air outside the chamber under both calm and windy conditions. Differential pressure measurements from field experiments show that the pressures inside our newly designed vented chamber equal those outside the chamber when wind speed at a height of 0.5 m is up to 7 m s−1, thus virtually eliminating artifacts due to the Venturi effect. Our field data show that the problem of overestimation in measured FCO2 by a chamber with older vent designs under windy conditions can be avoided with our newly designed vented chamber.

Impact of changes in barometric pressure on landfill methane emission

Landfill methane emissions were measured continuously using the eddy covariance method from June to December 2010. The study site was located at the Bluff Road Landfill in Lincoln, Nebraska, USA. Our results show that landfill methane emissions strongly depended on changes in barometric pressure; rising barometric pressure suppressed the emission, while falling barometric pressure enhanced the emission, a phenomenon called barometric pumping. There was up to a 35-fold variation in day-to-day methane emissions due to changes in barometric pressure. Wavelet coherence analysis revealed a strong spectral coherency between variations of barometric pressure and methane emission at periodicities ranging from 1 day to 8 days. Power spectrum and ogive analysis showed that at least 10 days of continuous measurements was needed in order to capture 90% of the total variance in the methane emission time series at our landfill site. From our results, it is clear that point-in-time measurements taken at monthly or longer time intervals using techniques such as the trace plume method, the mass balance method, or the closed-chamber method will be subject to large variations in measured emission rates because of the barometric pumping phenomenon. Estimates of long-term integrated methane emissions from landfills based on such measurements could yield uncertainties, ranging from 28.8% underestimation to 32.3% overestimation. Our results demonstrate a need for continuous measurements to quantify annual total landfill emissions. This conclusion may apply to the study of methane emissions from wetlands, peatlands, lakes, and other environmental contexts where emissions are from porous media or ebullition. Other implications from the present study for hazard gas monitoring programs are also discussed.