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Lubin Luo

University of New Orleans

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Journal of Organometallic Chemistry | 1997

Regioselective synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]he ta-2,5-dienyl)-η5-(C5Me5)RuCl complexes

Zhengming Chen; Lubin Luo; Steven P. Nolan; Jeffrey L. Petersen; Mark L. Trudell

Abstract The reactions of Cp∗ Ru(COD)Cl and CpRu(COD)Cl with N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives were found to give η3-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]CpRuCl and η 3 -[N( CO 2 Me )-7- azabicyclo [2.2.1] heptadienyl]Cp ∗ RuCl complexes in good yields (54–78%). The coordination reaction was found to take place regioselectively at the least substituted π-bond of the N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives. The structures of the complexes were determined by 1H and 13C NMR and the structure of η 3 -[N( CO 2 Me)C 6 H 3 (2-p- MeC 6 H 4 SO 2 )(6- CO 2 Me )(5- Me)]Cp ∗ RuCl was unequivocally established by X-ray crystallography.

Organometallics | 1994

Relative Binding Energies of Sterically Demanding Tertiary Phosphine Ligands to the Cp*RuCl (Cp* = .eta.5-C5Me5) Moiety. Thermochemical Investigation of Coordinatively Unsaturated Organoruthenium Complexes

Lubin Luo; Steven P. Nolan

Organometallics | 1995

Enthalpies of reaction of Cp'Ru(COD)Cl (Cp' = C5H5, C5Me5; COD = cyclooctadiene) with P(p-XC6H4)3 (X = Cl, F, H, CH3, CF3, OCH3) ligands : ligand steric vs electronic contributions to the enthalpy of reaction

Scafford A. Serron; Lubin Luo; Chunbang Li; Michele E. Cucullu; Edwin D. Stevens; Steven P. Nolan

Inorganic Chemistry | 1993

Enthalpies of reaction of (diene)- and (enone)iron tricarbonyl complexes with monodentate and bidentate ligands : solution thermochemical study of ligand substitution in the L2Fe(CO)3 complexes

Lubin Luo; Steven P. Nolan

Organometallics | 1999

CORRELATION BETWEEN STRUCTURAL AND SOLUTION CALORIMETRIC DATA FOR CP*RU(PR3)2CL (CP* = C5ME5) COMPLEXES

Dale C. Smith; Christopher M. Haar; Lubin Luo; Chunbang Li; Michele E. Cucullu; Charles H. Mahler; Steven P. Nolan; William J. Marshall; Nancy L. Jones; Paul J. Fagan

Organometallics | 1993

Organoruthenium thermochemistry. Enthalpies of reaction of (Cp*RuCl)4 and Cp*Ru(COD)Cl (Cp* = .eta.5-C5Me5, COD = cyclooctadiene) with dienes and tertiary phosphine ligands

Lubin Luo; Steven P. Nolan; Paul J. Fagan

Organometallics | 1992

Enthalpies of reaction of (benzylideneacetone)iron tricarbonyl, (BDA)Fe(CO)3, with phosphine ligands : thermodynamic insights into iron chemistry

Lubin Luo; Steven P. Nolan

Organometallics | 1995

ENTHALPIES OF REACTION OF (ETA 5-C5H5)RU(CYCLOOCTADIENE)CL WITH TERTIARY PHOSPHINE LIGANDS : LIGANG SUBSTITUTIONF AS A GAUGE FOR METAL BASICITY AND A LINEAR CORRELATION OF BOND LENGTH AND BOND ENTHALPY

Michele E. Cucullu; Lubin Luo; Steven P. Nolan; Paul J. Fagan; Nancy L. Jones; Joseph C. Calabrese

Organometallics | 1996

Organoruthenium thermochemistry : enthalpies of reaction of Cp'Ru(COD)Cl (Cp'=η5-C5H5 and η5-C5Me5) with tertiary phosphite ligands

Scafford A. Serron; Lubin Luo; Edwin D. Stevens; Steven P. Nolan; Nancy L. Jones; Paul J. Fagan

Organometallics | 1996

Relative Binding Energies of Tertiary Phosphine Ligands to the Cp*RuOCH2CF3(Cp* = η5-C5Me5) Moiety

Chunbang Li; Lubin Luo; Steven P. Nolan; William J. Marshall; Paul J. Fagan

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Steven P. Nolan

Ghent University

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Chunbang Li

University of New Orleans

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Michele E. Cucullu

California Institute of Technology

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Paul J. Fagan

DuPont

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Edwin D. Stevens

University of New Orleans

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Scafford A. Serron

University of New Orleans

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Joseph C. Calabrese

University of Wisconsin-Madison

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Nancy L. Jones

La Salle University

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Jeffrey L. Petersen

West Virginia University

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Mark L. Trudell

University of New Orleans

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