Luca Martire

The role of bacteria in the formation of cold seep carbonates: geological evidence from Monferrato (Tertiary, NW Italy)

Abstract Methane-derived carbonate rocks (Lucina limestone and Marmorito limestone) crop out in Monferrato (NW Italy) and represent one of the first described examples of rocks produced at fossil cold seeps. These rocks, of Miocene age, consist of strongly carbonate-cemented siliciclastic sediments ranging in grain size from mud to coarse sand. The methane-related origin of Monferrato carbonates is based on: (a) outcrop-scale evidence: patchiness of cementation, chemosymbiotic fossil communities, presence of a network of polyphase carbonate-filled veins not related to tectonics; (b) isotope geochemistry: very depleted δ13C values, as low as −50‰ PDB; (c) peculiar petrographic features. Diverse microbial communities have been observed in present-day cold seeps. These communities include sulphate-reducing, sulphur-oxidizing and methane-oxidizing bacteria. The present work is focused on the identification and description of fossil evidence of such microbial activity in the Monferrato carbonates. Examples of fossilization of microbial structures are probably represented by pyritic rods and dolomite tubes referable to sulphur-oxidizing and to unspecified bacteria, respectively. Less direct but more abundant evidence has been found through petrographic and SEM studies of seep carbonates. Many features point to the presence of organic clumps or mats capable of trapping sediment and promoting carbonate precipitation: microcrystalline calcite peloids; dolomite crystals with irregular hollow cores; dolomite spheroids with dumbbell-shaped cores; laminated internal sediments lining cavities completely. All these features are interpreted to result from bacterially mediated, sedimentary and diagenetic processes and can therefore be considered as an additional evidence of ancient methane seeps.

Discontinuities in carbonate successions: identification, interpretation and classification of some Italian examples

Abstract The growing use of unconformities as bounding surfaces for new types of stratigraphic units seems not to be matched by a corresponding effort on process-oriented researches on unconformities themselves. This paper aims at giving a contribution to classification and understanding of discontinuities in carbonate successions from the outcrop perspective, based on some Italian examples. A number of integrated criteria (geometry, sedimentology, diagenesis, biostratigraphy) is proposed to recognise stratigraphic breaks. Old terms are discussed and sometimes redefined, while some new terms are introduced. The term discontinuity surface (DS) is proposed as a general one to indicate any stratigraphic interface where an interruption of sedimentation can be proved. A DS can be characterized as a firm ground or a rock ground depending on its coherence at the moment of the renewal of sedimentation. Polygenic and simple omission surfaces are separated within firm grounds if a recognizable gap is either present or not; a third kind of firm ground, revealed only by biostratigraphy, has been called hidden discontinuity surface. Two categories of rock grounds are also distinguished: hard grounds and inherited rock grounds if, respectively, generation of the DS and/or deposition of the overlying sediments took place in the same environment of the underlying sediments or not. A genetic interpretation for each type of discontinuity is proposed. The largest variety of DSs occurs in pelagic sediments. Some discontinuities (hard grounds and simple omission surfaces) are attributed to increased bottom-current activity during sea-level falls; others (polygenic omission surfaces and hidden DSs) are interpreted as submarine slide scars either with or without the overprint due to exposure on the seafloor. The DSs separating different facies (e.g. platform and pelagic ones) are interpreted to be due to tectonics. The relevance of the recognized DSs to sequence stratigraphy is briefly discussed.

Authigenic carbonates in Upper Miocene sediments of the Tertiary Piedmont Basin (NW Italy): Vestiges of an ancient gas hydrate stability zone?

A wide array of carbonate-rich rocks has been recognized in the Tertiary Piedmont Basin (NW Italy), hosted in lower Messinian slope deposits. Carbonate cements show negative δ 13 C values and positive δ 18 O values, suggesting that carbonate precipitation was induced by microbial degradation of methane produced from gas hydrate destabilization. Two groups of rocks have been distinguished: (1) Lucina -bearing mud breccias, representing the seafloor product of an ancient seepage site; and (2) Lucina -free concretions, originating below the sediment-water interface. Within this group, two subtypes have been further distinguished: stratiform concretions and cylindrical concretions. Stratiform concretions result from precipitation of dolomite in the pores of muddy sediments. Some of them display a brecciated structure; others show a network of septarian-like cracks that are empty, filled with sediments, or zoned carbonate cements. Their internal features are related to the formation of gas hydrates within the sediments and to their destabilization. Thus, these rocks mark a portion of the sedimentary column located within a (paleo) gas hydrate stability zone. Cylindrical concretions represent ancient fluid conduits related to the upward migration of CH 4 -rich fluids subsequent to gas hydrate destabilization. The carbonate-rich rocks of the Tertiary Piedmont Basin stand as one of the first examples of methane-derived rocks that record successive episodes of dissociation and re-formation of gas hydrates, and they provide precious elements to model the general evolution of a portion of the sedimentary column located within the hydrate stability zone.

Tectono-sedimentary evolution of the Pliocene to Lower Pleistocene succession of the Apricena-Lesina-Poggio Imperiale quarrying district (western Gargano, southern Italy)

The post-Miocene marine succession of the «Apricena horst» is described with the purpose to verify the chronostratigraphic constraints for the type-locality of the Pirro Nord Faunal Unit. The stratigraphic succession has been subdivided in four units bounded by ubiquitous unconformities with evidence of subaerial exposure. The two basal units (dated late Zanclean to at most early Piacenzian) are formally grouped in the Lago di Varano Fm. that on the whole consists of sediments ranging from lagoonal to circalittoral environments. Within the lowermost unit, a megabreccia is interpreted as the product of a tsunami event. The third unit, Gelasian in age, is informally cited as Calcari a Briozoi Fm. The last unit, the Lower Pleistocene Serracapriola Fm., consists of siliciclastic deltaic sediments and represents the closure of the marine cycle. Conspicuous lateral facies and thickness changes, and the frequency of unconformities are the consequence of an intense synsedimentary tectonic activity developed in the frame of the southern Apulia foredeep closure. In the study area, such activity is documented by two E-W trending normal faults which, during Zanclean and at least the earliest Gelasian, controlled the Pliocene horst-graben system of the Apricena-Poggio Imperiale area.

Fragments of the Western Alpine Chain as Historic Ornamental Stones in Turin (Italy): Enhancement of Urban Geological Heritage through Geotourism

In Piemonte, stone has always been the most widely used raw material for buildings, characterizing the architectural identity of the city of Turin. All kinds of rocks, metamorphic, igneous, and sedimentary, are represented, including gneisses, marbles, granitoids, and, less commonly, limestones. The great variety of ornamental stones is clearly due to the highly composite geological nature of the Piemonte region related to the presence of the orogenic Alpine chain and the sedimentary Tertiary Piemonte Basin. This paper provides a representative list of the most historic ornamental stones of Piemonte, which have been used over the centuries in buildings and architecture. The main stones occurring in Turin have been identified and described from a petrographic and mineralogical point of view in order to find out the corresponding geological units and quarry sites, from which they were exploited. This allows the associated cultural and scientific interest of stones to be emphasized in the architecture of a town which lies between a mountain chain and a hilly region.

New data on post-Eocene tectonic evolution of the External Ligurian Briançonnais (Western Ligurian Alps)

A new structural setting for the central part of the External Ligurian Brianconnais (CELB) is proposed. CELB is divided into km-scale tectonic units that still preserve pre-Alpine geological features at several stratigraphic levels. Macro-, meso- and microscale primary features, such as paleoescarpments, unconformities and depositional or diagenetic fabrics are thus well preserved and can be still mapped and studied in detail at many stratigraphic levels. Significant transposition of bedding is recorded only in Upper Cretaceous and Eocene marly limestones and shales and in major km-long shear zones, where intense development of closely spaced tectonic foliations occurred. Several features indicate that the CELB tectonic evolution took place at shallow crustal levels: 1) strong localization of deformation along the weakest stratigraphic levels; 2) absence of diffuse recrystallization of rocks; 3) minor occurrence or absence of transposition of bedding; 4) kinematic evolution of fold axial plane foliations into frictional slip cleavages. A gradual decrease in the intensity of deformation from the Internal Ligurian Brianconnais to CELB and Dauphinois Domain is observed, although the boundaries of these three domains correspond, in the study area, to several Km-long, transpressive shear zones whose kinematic role in the evolution of the southern termination of the Western Alps should be carefully considered.

Pseudoborings in Ammonite Molds: The Combined Result of Predation and Taphonomic-reworking (Bajocian, Normandy, N. France)

Abstract Unusual structures, observed on taphonomically-reworked ammonite molds collected in the Oolithe Ferrugineuse de Bayeux Formation (Bajocian, Normandy), are described. They appear as depressions in the mold, located below “holes” in the shell, and they are filled with a sediment plug texturally different from the mold. These structures are called “pseudoborings” because of their similarity in both external shape and size (from 2 mm to over 10 mm in diameter) to bivalve borings. Detailed analyses of polished surfaces and thin sections cut through the mold show that the depth of penetration of pseudoborings and the irregularity of the plug-mold boundary exclude a bioerosional origin. The origin of pseudoborings is hypothesized to be due to erosion of unlithified sediments and exhumation of sediment-filled ammonite shells, previously damaged by attacks by cephalopod predators, resulting in a partial emptying of the conch.

Geological setting of the southern termination of Western Alps

A revision of the stratigraphic and tectonic setting of the southern termination of the Western Alps, at the junction of the Maritime Alps with the westernmost Ligurian Alps, is proposed. In response to the Alpine kinematic evolution, a number of tectonic units formed on the deformed palaeo-European continental margin and were arranged in a NW–SE striking anastomosed pattern along the north-eastern boundary of the Argentera Massif. Because these tectonic units often cut across the palaeogeographic subdivision of the Alpine literature and show only partial affinity with their distinctive stratigraphic features, new attributions are proposed. The Subbriançonnais domain is here intended as a “deformation zone”, and its tectonic units have been attributed to Dauphinois and Provençal domains; furthermore, the Eocene Alpine Foreland Basin succession has been interpreted, based on the affinity of its lithologic characters and age, as a single feature resting above all the successions of the different Mesozoic domains. The Cretaceous tectono-sedimentary evolution of the studied domains was characterized by intense tectonic controls on sedimentation inducing lateral variations of stratigraphic features and major hydrothermal phenomena. Since the early Oligocene, transpressional tectonics induced a NE–SW shortening, together with significant left-lateral movements followed by (late Oligocene–middle Miocene) right-lateral movements along E–W to SE–NW striking shear zones. This induced the juxtaposition and/or stacking of Briançonnais, Dauphinois and Ligurian tectonic units characterized by different metamorphic histories, from anchizonal to lower greenschist facies. This evolution resulted in the arrangement of the tectonostratigraphic units in a wide “transfer zone” accommodating the Oligocene WNW-ward movement of portions of the palaeo-European margin placed at the south-western termination of Western Alps and the Miocene dextral shearing along SE striking faults that bound the Argentera Massif on its NE side.

JURASSIC SEDIMENTARY AND TECTONIC PROCESSES AT MONTAGNA GRANDE (TRAPANESE DOMAIN, WESTERN SICILY, ITALY)

The Rosso Ammonitico of the Montagna Grande area is very interesting because of the great diversification in facies and thickness in three very closely situated sections. The Jurassic succession in this area is that typical of the Trapanese Domain. It starts with a thick pile of platform limestones (Inici Formation: Hettangian - Sinemurian) that are overlain by typically condensed and commonly nodular pelagic limestones (Rosso Ammonitico: Middle Jurassic - lowermost Cretaceous). The good exposure of this succession in active quarries allows observation of sedimentological and palaeontological details and to improve the understanding of the Jurassic tectono-sedimentary evolution. The Rocca chi Parra quarry shows a stepped surface, with a relief of some metres, incised in the Inici Formation. It is covered by lenticular or wedge-shaped lithosomes a few metres-thick of highly condensed Rosso Ammonitico. It is interpreted as a slide scar along which a thin but extensive block of lithified platform limestones was detached and slid downslope. The Poggio Roccione quarry shows neptunian sills and collapse structures in the middle part of the Rosso Ammonitico that on the whole is thicker (about 12 m) than at Rocca chi Parra. They indicate sea-floor instability probably due to seismic shocks with brittle to plastic behaviour of sediments depending on their coherence. The Montagna Grande outcrop shows an even thicker succession which includes a wedge of cherty limestones about 10 m thick intercalated between a lower and an upper Rosso Ammonitico calcareous unit. The features described in these three sections document a highly irregular sea-floor topography which in turn was controlled by several phases of extensional tectonics during Mid and Late Jurassic pelagic sedimentation. Structurally higher sectors closer to fault scarps were affected by a very condensed sedimentation, the opening of subvertical dykes and the triggering of large slides. Structurally lower sectors allowed preservation of thicker successions that were affected by gravitationally-induced soft to hard sediment deformation when tectonics resulted in an oversteepening of the slope.

Geology of the Entracque–Colle di Tenda area (Maritime Alps, NW Italy)

The 1:25,000 geological map of the Entracque–Colle di Tenda area covers an area of about 130 km2 in the Italian Maritime Alps, between the Gesso and Vermenagna valleys. The map area is of great relevance since the Alpine units of this region sampled a geological nodal point in the Mesozoic, at the transition between two different sedimentation domains of the Alpine Tethys European palaeomargin (the Dauphinois basin to the NW and the Provençal platform to the SE). During the Cenozoic, this palaeogeographic hinge was progressively incorporated along multiple shear zone systems developed at the southern termination of the Western Alps arc.