Lucrezia Lamastra

Recycled paper-paperboard for food contact materials: Contaminants suspected and migration into foods and food simulant

Contaminant residues in food packaging is a new challenge of our time, as it may pose a threat for consumers. Higher levels of contaminants were observed in food packaging made by recycled materials, even if little information is available for some groups of contaminants. The present study proposes a procedure for analyzing three different groups of organic contaminants in recycled paper and paperboard. Seventeen commercial samples were analyzed for the presence of bisphenol A (BPA), bis (2-ethylhexyl) phthalate (DEHP), nonylphenol monoethoxylate (NMP) and nonylphenol di-ethoxilate (NDP). Not all the samples contained all the contaminants; BPA was the only substance present in all the samples. The concentrations detected were quite high and, in most of the cases, in agreement with results reported in previous studies. Substance migration tests from spiked/non-spiked samples for two dry foods and Tenax® food simulant were undertaken. BPA migration quotients were always lower than 1%, whereas the migration quotients of DEHP were higher than 2.0%. The highest nonylphenols migration quotients were 6.5% for NMP and 8.2% for NDP. Tenax® simulates well the contaminants migration from paperboard to dry food, in some cases being even more severe than the food.

Environmental impact of an Italian wine bottle: Carbon and water footprint assessment

The food sector represents one of the major impacting sectors from an environmental point of view and, among all the products, wine emerges as one of the most studied by the literature. Single-issue approaches are commonly used, but a more comprehensive analysis is desirable, since a single indicator does not properly track the pressure on the environment. This paper presents a combined carbon and water footprint assessment, with a cradle to grave approach, for a protected designation of origin Italian red wine, and suggests a correlation among the two indicators across the life cycle phases. A total CF equal to 1.07±0.09kgCO2eq/bottle and a total WF equal to 580±30l/bottle were calculated for the studied product and a direct proportionality was found between the total CF and the sum of WFgrey(indirect) and WFblue.

PAHs content of sewage sludge in Europe and its use as soil fertilizer.

The European Commission has been planning limits for organic pollutants in sewage sludge for 14years; however no legislation has been implemented. This is mainly due to lack of data on sewage sludge contamination by organic pollutants, and possible negative effects to the environment. However, waste management has become an acute problem in many countries. Management options require extensive waste characterization, since many of them may contain compounds which could be harmful to the ecosystem, such as heavy metals, organic pollutants. The present study aims to show the true European position, regarding the polycyclic aromatic hydrocarbons (PAHs) content of sewage sludge, by comparing the Italian PAHs content with European Union countries, and at assessing the suitability of sewage sludge as soil fertilizer. The FOCUS Pearl model was used to estimate the concentration of benzo [a] pyrene (B(a)Pyr), the most toxic PAH in soil, and its exposure to organisms was then evaluated. The simulated B(a)Pyr and PAHs, expressed as B(a)Pyr, concentrations in soil were much lower than the B(a)Pyrs most conservative lowest observable effect concentration (LOEC) for soil organisms. Furthermore, the results obtained indicate that it is more appropriate to apply 5tha(-1) sewage sludge annually than 15tha(-1) triennially. Results suggest, the EU maximum recommended limit of 6mgkg(-)(1) PAHs in sewage sludge, should be conservative enough to avoid groundwater contamination and negative effects on soil organisms.

Herbicide contamination and dispersion pattern in lowland springs

Herbicides reduce the diversity of flora and fauna in freshwater ecosystems and also contaminate groundwater due to leaching. Herbicide contamination can be a serious threat for all groundwater-dependent ecosystems (GDE), altering their chemical and biological quality. Successful management to protect GDE is dependent on detailed knowledge of the hydrogeological and hydrochemical features of the surrounding environment. We consider the possible diffuse contamination by herbicides of groundwater and of GDE as lowland springs, semi-artificial ecosystems with elevated biodiversity. The main objectives of the present work were thus: (1) to map herbicide contamination in lowland springs, (2) to evaluate the potential risk for biota and (3) to quantify the extent of the area from which the herbicide use can affect the water quality of lowland springs. In June and August 2009, nearly 23 springs within the Po River Plain (Northern Italy) were sampled and analyzed for five herbicides used to control weeds in maize. Hydrogeological properties, half-lives of the herbicides and their concentrations in both groundwater and springs were used to quantify the area from which the contamination could originate. Such evaluation was performed by means of GIS techniques. Terbuthylazine were the only herbicide found, together with its metabolite desethylterbuthylazine. In 16 out of 84 measurements, their concentrations were above the threshold for drinking water; however, they were always below the ecotoxicological end-points of aquatic flora and fauna. Spatial analyses reveal that the theoretical area from which herbicides can contaminate spring water is within a distance varying between a few and 1800 m. Our findings indicate that conservation plans should focus on the fields adjacent to or surrounding the springs and should address the optimization of irrigation practices, restoration of buffer strips, crop rotation and in general more sustainable agricultural practices in the proximity of these fragile GDE.

Virtual water trade of agri-food products: Evidence from italian-chinese relations

At global scale, the majority of world water withdrawal is for the agricultural sector, with differences among countries depending on the relevance of agri-food sector in the economy. Virtual water and water footprint could be useful to express the impact on the water resources of each production process and good with the objective to lead to a sustainable use of water at a global level. International trade could be connected to the virtual water flows, in fact through commodities importation, water poor countries can save their own water resources. The present paper focuses on the bilateral virtual water flows connected to the top ten agri-food products traded between Italy and China. Comparing the virtual water flow related to the top 10 agri-food products, the virtual water flow from Italy to China is bigger than the water flow in the opposite direction. Moreover, the composition of virtual water flows is different; Italy imports significant amounts of grey water from China, depending on the different environmental strategies adopted by the two selected countries. This difference could be also related to the fact that traded commodities are very different; the 91% of virtual water imported by Italy is connected to crops products, while the 95% of virtual water imported by China is related to the animal products. Considering national water saving and global water saving, appears that Italy imports virtual water from China while China exerts pressure on its water resources to supply the exports to Italy. This result at global scale implies a global water loss of 129.29millionm3 because, in general, the agri-food products are traded from the area with lower water productivity to the area with the higher water productivity.

The stakeholder-consultation process in developing training and awareness-raising material within the framework of the EU Directive on Sustainable Use of Pesticides: The case of the EU-project BROWSE

In September 2009, the Council of the European Union adopted the Directive on Sustainable Use of Pesticides (SUD). The core idea is that in order to achieve sustainable use of pesticides, it is necessary that everyone is conscious about the risks to both human health and the environment associated with the use of plant protection products. Therefore, in the SUD, training and raising awareness play key roles in order to achieve the objectives of the directive. In this sense, the European-founded project BROWSE (Bystanders, Residents, Operators and WorkerS Exposure models for plant protection products) has, as one of its main objectives, to contribute to the implementation of the SUD through the development and dissemination of communication materials for training and raising awareness. For this reason, a consultation process was implemented involving all relevant stakeholders in order to identify their opinions regarding the subjects to be prioritised, the factors influencing pesticide exposure to be focused on and the most suitable formats to develop training and awareness-raising material as well as identification of target groups. To collect the required information, participants were asked to answer an electronic questionnaire (giving the possibility through several debates for additional comments). The collected findings and the ensuing debates are described in this article and are going to be taken into account in the development of the BROWSE training and communication material for the raising of awareness.

Inclusion of emerging organic contaminants in groundwater monitoring plans.

Groundwater is essential for human life and its protection is a goal for the European policies. All the anthropogenic activities could impact on water quality. • Conventional pollutants and more than 700 emerging pollutants, resulting from point and diffuse source contamination, threat the aquatic ecosystem.• Policy-makers and scientists will have to cooperate to create an initial groundwater emerging pollutant priority list, to answer at consumer demands for safety and to the lack of conceptual models for emerging pollutants in groundwater.• Among the emerging contaminants and pollutants this paper focuses on organic wastewater contaminants (OWCs) mainly released into the environment by domestic households, industry, hospitals and agriculture. This paper starts from the current regulatory framework and from the literature overview to explain how the missing conceptual model for OWCs could be developed.• A full understanding of the mechanisms leading to the contamination and the evidence of the contamination must be the foundation of the conceptual model. In this paper carbamazepine, galaxolide and sulfamethozale, between the OWCs, are proposed as “environmental tracers” to identify sources and pathways ofcontamination/pollution.

Water footprint and economic water productivity of Italian wines with appellation of origin: Managing sustainability through an integrated approach

In the agribusiness wine is certainly a very interesting sector to analyze. The specific aim of this work is to assess water efficiency and economic water productivity for the Italian wines with Appellation of Origin (AO). This assessment could represent a potential management instrument to improve production performances from a more integrated perspective, pursuing new market trends. The study is related to Italy, the first worldwide producer, and analyzes the available data of AO wines, which globally have specific features, being strictly connected with the territory and its background. The results show the top and bottom five AO wines in terms of crop water use and economic water productivity and their trends during the period 2011-2015, based on average annual change rates. Results of this study are relevant for the wine sector since they can guide decision makers on vine variety selection in the context of micro- and macro-level sustainability of water resource use.

A process to provide harmonised criteria for the selection of indicators for pesticide risk reduction within the framework of the sustainable use directive

In October 2009, the Council of the European Union adopted the Directive on Sustainable Use of Pesticides (EU 128/2009/EC). This directive establishes a framework to achieve the sustainable use of pesticides by reducing the risk and impacts of pesticide use on both human health and the environment, and promoting the use of integrated pest management and of alternative approaches or techniques. These risks thus need to be assessed using appropriate risk indicators. The OPERA Research Centre organised an expert working group and has had several consultations with stakeholders in order to identify a common way of thinking in evaluating and identifying the factors that should be considered in selecting each indicator. Harmonised criteria have been suggested to allow the selection of the most appropriate indicators, focusing on the use phase of pesticide, as requested by the sustainable use directive. The proposed methodology has led to a sharing of perspectives and knowledge between the experts involved, and some principles have been identified to help national regulatory institutions to estimate general trends in pesticide risk reduction.

Groundwater nitrate contamination and agricultural land use: A grey water footprint perspective in Southern Apulia Region (Italy)

In this paper, we present a new approach based on the Grey Water Footprint (GWF) concept for the determination of groundwater nitrate contamination, with a focus on the agricultural impact in the Southern Apulia Region (Italy). The GWF assessment allows us to highlight wells where nitrate contamination is higher and for which a verification of the nature of contamination is necessary, potentially identifying certain contexts associated with risk factors present in the area. Data show higher nitrate GWF values for vineyards than for olive groves, particularly in areas used for the production of table grapes. Indeed, it is possible to observe that the Western Ionian-Tarantino arch is characterized by a high average level of the GWF indicator, area characterized by an agricultural land use (vineyards, orchards, simple arable land). Another important area is the Brindisi plain, predominantly characterized by an agricultural vocation and a related fertilizer use. The situation in the whole Salento peninsula is more heterogeneous. The results of the GWF show high values in equally distributed points with a clear frequency in the coastal areas of the Ionic arch (Eastern Tarantino and Salento). The Water Footprint methodology and in particular the GWF approach used in this study conceives a useful indicator for the agricultural policy planning processes, a criterion to establish land use management according to the status of hydrological basin and a tool for assessing the pollution monitoring programs.