Luiz Pereira da Costa

Ion-Exchange Properties of Imidazolium-Grafted SBA-15 toward AuCl4– Anions and Their Conversion into Supported Gold Nanoparticles

Imidazolium groups were successfully prepared and grafted on the surface of SBA-15 mesoporous silica. The ion-exchange properties of the functionalized porous solid (SBA-15/R(+)Cl(-)) toward AuCl(4)(-) anions were evaluated through an ion-exchange isotherm. The calculated values of the equilibrium constant (log β = 4.47) and the effective ion-exchange capacity (t(Q) = 0.79 mmol g(-1)) indicate that the AuCl(4)(-) species can be loaded and strongly retained on the functionalized surface as counterions of the imidazolium groups. Subsequently, solids containing different amounts of AuCl(4)(-) ions were submitted to a chemical reduction process with NaBH(4), converting the anionic gold species into supported gold nanoparticles. The plasmon resonance bands, the X-ray diffraction patterns, and transmission electron microscopy images of the supported gold nanoparticles before and after thermal treatment at 973 K indicate that the metal nanostructures are highly dispersed and stabilized by the host environment.

One-step preparation of CdS nanocrystals supported on thiolated silica-gel matrix and evaluation of photocatalytic performance

Here we report the use of a thiol-functionalized silica-gel to prepare supported CdS nanocrystals by a facile one-step procedure. Upon changing the relative proportion of the matrix we obtained nanocrystals with different average sizes and size distributions, as evidenced by spectroscopic measurements as well as TEM images. Photoluminescence spectra also indicated that the main effect of the matrix is related to the size control since the spectral profiles were found to be strongly dependent on the excitation wavelength. The performance of the material in the photocatalytic degradation of two commercial dyes (methylene blue and rhodamine 6G) has been tested under sunlight radiation, showing promising results. Almost complete decolorization has been observed after 80 min of exposure, with no adsorption on the silica surface.

Multifunctional catalytic platform for peroxidase mimicking, enzyme immobilization and biosensing

A hybrid platform based on ionic liquid-based alkoxysilane functionalized mesoporous silica was applied for the synthesis of supported Pt nanoparticles with peroxidase-like catalytic activity. The positively charged groups (imidazolium) chemically bonded to the surface provide dual-functionality as ion-exchangers to the hybrid material, firstly used for the in situ synthesis of the highly dispersed Pt nanostructures and, secondly, for the immobilization of biological species aiming biosensing purposes. The peroxidase-like catalytic activity of the SiO2/Imi/Pt material was evaluated towards the H2O2-mediated oxidation of a chromogenic peroxidase substrate (TMB), allowing the colorimetric detection of H2O2. Finally, to further explore the practical application of this nanomaterial-based artificial system, glucose oxidase (GOx) was immobilized on the catalytic porous platform and a bioassay for the colorimetric determination of glucose was successfully conducted as a model system. The enzyme-like catalytic properties of the SiO2/Imi/Pt as well as its ability to immobilize and keep active biological entities on the porous structure indicate that this hybrid porous platform is potentially useful for the development of biosensing devices.

Hollow carbon nanostructures obtained from hydrothermal carbonization of lignocellulosic biomass

Here we describe a new method for obtaining carbon nanocages at relatively low temperatures using a low-cost lignocellulosic waste material as carbon precursor. Coconut coir dust has been submitted to hydrothermal carbonization in the presence of clays minerals such as sepiolite, attapulgite, and montmorillonite followed by a demineralization step. Just after hydrothermal treatment, the samples prepared in the absence of the clays presented a sponge-like morphology as typically described for hard-plant tissues submitted to this treatment while the samples heated in the presence of clays were fundamentally heterogeneous. After chemical etching with hydrofluoric acid, the sample free from clays exhibited irregular round-shaped particles with poorly defined cavities. For samples containing clays, on the other hand, the chemical etching lead to well-defined carbon nanocages as long as the particles were successfully etched such as attapulgite and montmorillonite. For sepiolite, however, the presence of residual inorganic particles was observed along with irregularly shaped hollow nanostructures. Finally, Raman measurements revealed the typical features of amorphous carbons.

Antibacterial evaluation silver of nanocomposite on Staphylococcus aureus and Escherichia coli

Background The treatment of bacterial diseases has become an increase public health problem, since the conventional antimicrobial substances lose their effectiveness due to the microbial resistance phenomenon [1]. Silver is a metal with potential antibacterial activity, and showed significant efficacy against several species of bacteria. The silver activity to prevent microbial growth is enhanced when the metal is found as nanoparticles [2]. Silver nanoparticles (NPAG) have their bacteriostatic and bactericidal activity based on their ability to kill or inhibit growth of bacteria. Pathogenic microorganisms, both gram positive and negative were sensitive to NPAG. The NPAG may be employed in conjunction with the biopolymers forming a nanocomposite that emerge as a promising therapeutic alternative. The xanthan gum is a biopolymer with interesting properties for food, cosmetic and pharmaceutical industries, acting as gelling and stabilizing [3]. The present study in focused on the evaluation of silver nanocomposite activity against gram positive and gram negative bacteria. The disk diffusion well technique was used to assess the efficiency of the silver nanocomposites against Staphylococcus aureus and Escherichia coli. The results indicated that the developed product has a broad spectrum of activity against the tested bacteria.