Lydie Le Forestier

Hydro-chemio-mechanical coupling effects on permeability and swelling behaviour of a Ca smectite soaked by Cu solutions

Hydro-chemio-mechanical coupling effects in an expansive clay have been studied along soaking paths with oedometer cells equipped with two solute injection systems. Two sets of boundary conditions for soaking were applied: solute and gas–solute mixture. The clay used for the experiments was a Ca French expansive clay known as Fo–Ca. The role of solute chemistry on clay permeability, swelling strain, porosity and on the retention curve was investigated. Copper cations were chosen for taking into account strong adsorption capacity, as the migration of toxic cations normally occurs in acid solutions, exchanges being produced with alkaline content. Permeability as well as swelling strain changes along soaking paths have been investigated with copper concentration with respect to the two sets of boundary conditions. Moreover, the ability of the Fo–Ca for ions sorption was studied by means of leachate analyses. Porosity and retention curves were also given after testing with respect to copper concentrations. Significant changes resulting from the copper solute injection have been obtained for all these material parameters.

Soil drainage as an active agent of recent soil evolution: a review.

Abstract While research on pedogenesis mainly focuses on long-term soil formation and most often neglects recent soil evolution in response to human practices or climate changes, this article reviews the impact of artificial subsurface drainage on soil evolution. Artificial drainage is considered as an example of the impact of recent changes in water fluxes on soil evolution over time scales of decades to a century. Results from various classical studies on artificial drainage including hydrological and environmental studies are reviewed and collated with rare studies dealing explicitly with soil morphology changes, in response to artificial drainage. We deduce that soil should react to the perturbations associated with subsurface drainage over time scales that do not exceeding a few decades. Subsurface drainage decreases the intensity of erosion and must i) increase the intensity of the lixiviation and eluviation processes, ii) affect iron and manganese dynamics, and iii) induce heterogeneities in soil evolution at the ten meter scale. Such recent soil evolutions can no longer be neglected as they are mostly irreversible and will probably have unknown, but expectable, feedbacks on crucial soil functions such as the sequestration of soil organic matter or the water available capacity.

Quantification of soil volumes in the Eg & Bt-horizon of an Albeluvisol using image analysis

In this study, we provide a strategy to quantify the effects on soil evolution of driving forces such as human activities or global change. This strategy was developed for situations in which soil evolution resulted in the formation of a complex juxtaposition of soil volumes with distinct properties including soil colours. It is based on image analysis. Our approach proceeds in two steps: (1) to find the minimum sample size over which the soil anisotropy can be neglected and (2) to define a Representative Elementary Volume (REV) of that sample. This approach was developed on the Eg & Bt horizon of a drained Albeluvisol in which three decimetric soil monoliths were sampled at 60, 110 and 210 cm from a drain. The monoliths were sliced into 1.5-cm horizontal layers. Each slice was photographed and studied by image analysis. At the monolith scale, there was neither lateral nor vertical anisotropy. The sampled monoliths were larger than the REV allowing quantification of the different soil volumes constituting...

Interactions of ammonium smectite with low-molecular-weight carboxylic acids

Abstract The percolation of water through waste landfill sites produces leachates with large amounts of pollutants. Clay barriers are often used to limit soil and underground water pollution. A better understanding of the interaction between ammonium smectite and carboxylic acids would contribute significantly to our understanding of such systems. The SWy-2 (Wyoming smectite) was exchanged with NH4+ and then batched with carboxylic acids (acetic,formic,chloroacetic and oxalic) in concentrations between 0.01 M and 1 M. The solid phases obtained were analysed chemically and characterized by infrared absorption spectroscopy (IR) and powder X-ray diffraction (XRD). Ionic chromatography was used for the quantitative measurement of ammonium ions in the solution after the interaction. For the four acids,the interaction was characterized by a cationic exchange of NH4+ to H3O+. A partial exchange to Al3+ due to a partial dissolution of the sample in strong acidic medium was observed with chloroacetic and oxalic acids for which adsorption of molecules on the clay sample occurs,mainly through H-bonding with the cation. Moreover,the intercalation of oxalic acid in the interlayer space was highlighted.

Soil Drainage as an Active Agent of Recent Soil Evolution

Abstract While research on pedogenesis mainly focuses on long-term soil formation and most often neglects recent soil evolution in response to human practices or climate changes, this article reviews the impact of artificial subsurface drainage on soil evolution. Artificial drainage is considered as an example of the impact of recent changes in water fluxes on soil evolution over time scales of decades to a century. Results from various classical studies on artificial drainage including hydrological and environmental studies are reviewed and collated with rare studies dealing explicitly with soil morphology changes, in response to artificial drainage. We deduce that soil should react to the perturbations associated with subsurface drainage over time scales that do not exceeding a few decades. Subsurface drainage decreases the intensity of erosion and must i) increase the intensity of the lixiviation and eluviation processes, ii) affect iron and manganese dynamics, and iii) induce heterogeneities in soil evolution at the ten meter scale. Such recent soil evolutions can no longer be neglected as they are mostly irreversible and will probably have unknown, but expectable, feedbacks on crucial soil functions such as the sequestration of soil organic matter or the water available capacity.

Interactions of ammonium-smectite with volatile organic compounds from leachates

Abstract The percolation of water through waste landfills produces leachates with high concentrations of NH4+ which can generate NH4+-exchanged clays within geochemical barriers. These leachates also contain several volatile organic compounds (VOCs) which can interact with the clay barrier. The aim of the present study was to characterize the sorption of eight short-chain VOCs (acetonitrile, methyl tert-butyl ether, dichloromethane, benzene, phenol, ethanol, acetone and aniline) on NH4+-smectite, and to identify their sorption mechanisms. The samples treated were characterized by carbon and nitrogen elemental analysis, infrared spectroscopy, powder X-ray diffraction, and thermogravimetric analysis. For acetonitrile, methyl tert-butyl ether, dichloromethane and benzene, no sorption was detected. Phenol, ethanol and acetone were sorbed very weakly, through Van derWaals interactions. Aniline molecules were sorbed strongly on NH4+-smectite mainly with hydrogen bonds between aniline and interlayer water molecules. However, aniline sorption decreased the hydrophilic character of the NH4+-smectite, which may increase the permeability of the clay barrier.