Lynda Bahloul

Optimization of methylene blue removal by stable emulsified liquid membrane using Plackett–Burman and Box–Behnken designs of experiments

The stability of an emulsified liquid membrane composed of Span80 as a surfactant, D2EHPA as an extractant and sulfuric acid as an internal phase was first studied according to different diluents and many operating parameters using the Plackett–Burman design of experiments. Then the removal of methylene blue from an aqueous solution has been carried out using this emulsified liquid membrane at its stability conditions. The effects of operating parameters were analysed from the Box–Behnken design of experiments. The optimization of the extraction has been realized applying the response surface methodology and the results showed that the dye extraction yielding 98.72% was achieved at optimized conditions.

Investigation of microstructure and mechanical properties of phosphocalcic bone substitute using the chemical wet method

Selection of calcium phosphate base materials in reconstructive bone surgery is justified by the surprising similarities in chemical compositions with human bones. The closest to natural apatite material is the hydroxyapatite (HAp) which has a chemical composition based on calcium and phosphate (Ca10(PO4)6(OH)2). In this study, HAp is synthesized using the wet precipitation method from hydrated calcium chloride (CaCl2,12H2O) and di-sodium hydrogen phosphate di-hydrate (HNa2PO4,2H2O). The powder is calcinated at 900°C and 1200°C in order to compare with sintered condition at 1150°C. Vickers microhardness tests and X-ray diffraction analyzes are used for the characterization of the crystalline material. Mechanical properties (Hv, σe, σr, and KC) and the degree of crystallinity (Xc) are discussed according to heat treatment temperatures. Results indicate that heat treating the powder at 1200°C increased crystallinity up to 72%. At the same time, microhardness increased with temperature and even outmatched the sintered case at 1150°C. Fracture toughness is ameliorated with increasing heat treatment temperature by more than two folds.Selection of calcium phosphate base materials in reconstructive bone surgery is justified by the surprising similarities in chemical compositions with human bones. The closest to natural apatite material is the hydroxyapatite (HAp) which has a chemical composition based on calcium and phosphate (Ca10(PO4)6(OH)2). In this study, HAp is synthesized using the wet precipitation method from hydrated calcium chloride (CaCl2,12H2O) and di-sodium hydrogen phosphate di-hydrate (HNa2PO4,2H2O). The powder is calcinated at 900°C and 1200°C in order to compare with sintered condition at 1150°C. Vickers microhardness tests and X-ray diffraction analyzes are used for the characterization of the crystalline material. Mechanical properties (Hv, σe, σr, and KC) and the degree of crystallinity (Xc) are discussed according to heat treatment temperatures. Results indicate that heat treating the powder at 1200°C increased crystallinity up to 72%. At the same time, microhardness increased with temperature and even outmatched th...

Characterization of diatomite from Sig region (West Algeria) for industrial application

Purpose – Diatomite also known Kieselguhr, is a non-metallic mineral composed of the skeletal remains of microscopic single-celled aquatic algae called diatoms. The purpose of this paper is to test and to evaluate the diatomite of Sig region (West Algeria) to substitute the main mould powder used in continuous casting of steel for thermal insulation and lubrication. Design/methodology/approach – To assess the behavior of diatomite at different temperatures, a combination of simultaneous scanning calorimetric and thermogravimetric testing was used and to evaluate the structure of diatomite, the scanning microscopy method was applied. Findings – The results showed different endothermic and exothermic peaks, mainly at 84.7°C and 783.5°C for endothermic peaks and 894.9°C for exothermic peak. The scanning microscopy method was used and a large porosity was observed. The trial industrial in continuous casting of steel showed a weak loss temperature of steel. Originality/value – This product may be used for ther...