M. D. Bremser
North Carolina State University
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Featured researches published by M. D. Bremser.
Applied Physics Letters | 1997
Ok-Hyun Nam; M. D. Bremser; Tsvetanka Zheleva; Robert F. Davis
Organometallic vapor phase lateral epitaxy and coalescence of GaN layers originating from GaN stripes deposited within 3-μm-wide windows spaced 3 μm apart and contained in SiO2 masks on GaN/AlN/6H–SiC(0001) substrates are reported. The extent and microstructural characteristics of the lateral overgrowth were a strong function of stripe orientation. A high density of threading dislocations, originating from the interface of the underlying GaN with the AlN buffer layer, were contained in the GaN grown in the window regions. The overgrowth regions, by contrast, contained a very low density of dislocations. The coalesced layers had a rms surface roughness of 0.25 nm.
Applied Physics Letters | 1997
Tsvetanka Zheleva; Ok-Hyun Nam; M. D. Bremser; Robert F. Davis
The microstructure and the lateral epitaxy mechanism of formation of homoepitaxially and selectively grown GaN structures within windows in SiO2 masks have been investigated by transmission electron microscopy (TEM) and scanning electron microscopy. The structures were produced by organometallic vapor phase epitaxy for field emission studies. A GaN layer underlying the SiO2 mask provided the crystallographic template for the initial vertical growth of the GaN hexagonal pyramids or striped pattern. The SiO2 film provided an amorphous stage on which lateral growth of the GaN occurred and possibly very limited compliancy in terms of atomic arrangement during the lateral growth and in the accommodation of the mismatch in the coefficients of thermal expansion during cooling. Observations with TEM show a substantial reduction in the dislocation density in the areas of lateral growth of the GaN deposited on the SiO2 mask. In many of these areas no dislocations were observed.
Applied Physics Letters | 1995
T. Warren Weeks; M. D. Bremser; K. Shawn Ailey; Eric Carlson; W. G. Perry; Robert F. Davis
Monocrystalline GaN(0001) thin films, void of oriented domain structures and associated low‐angle grain boundaries, have been grown via organometallic vapor phase epitaxy (OMVPE) on high‐temperature monocrystalline AlN(0001) buffer layers predeposited on vicinal α(6H)–SiC(0001) wafers using TEG, TEA, and ammonia in a cold wall, vertical, pancake‐style reactor. The surface morphology was smooth, and the PL spectrum showed strong near‐band‐edge emission with a full width at half‐maximum (FWHM) value of 4 meV. The dislocation density within the first 0.5 μm was ≊1×109 cm−2; it decreased substantially with increasing film thickness. Controlled n‐type Si doping of GaN has been achieved for net carrier concentrations ranging from ∼1×1017 to 1×1020 cm−3. Double‐crystal XRC measurements indicated a FWHM value of 66 arcsec for the GaN(0004) reflection.
Journal of Applied Physics | 1998
S. W. King; J. P. Barnak; M. D. Bremser; K. M. Tracy; Carsten Ronning; Robert F. Davis; R. J. Nemanich
Successful ex situ and in situ cleaning procedures for AlN and GaN surfaces have been investigated and achieved. Exposure to HF and HCl solutions produced the lowest coverages of oxygen on AlN and GaN surfaces, respectively. However, significant amounts of residual F and Cl were detected. These halogens tie up dangling bonds at the nitride surfaces hindering reoxidation. The desorption of F required temperatures >850 °C. Remote H plasma exposure was effective for removing halogens and hydrocarbons from the surfaces of both nitrides at 450 °C, but was not efficient for oxide removal. Annealing GaN in NH3 at 700–800 °C produced atomically clean as well as stoichiometric GaN surfaces.
Applied Physics Letters | 1997
Scott A. Smith; C. A. Wolden; M. D. Bremser; Andrew Hanser; Robert F. Davis; W. V. Lampert
The etching behavior of gallium nitride (GaN), aluminum gallium nitride (AlxGa1−xN), and aluminum nitride (AlN) has been systematically examined in an inductively coupled plasma (ICP) using Cl2 and Ar as the reagents. Etch rates were strongly influenced by ICP power and dc bias, while relatively insensitive to pressure, flow rate, and gas composition. Maximum etch rates of 9800 A/min for GaN, 9060 A/min for Al0.28Ga0.72N, and 7490 A/min for AlN were attained. The etch profiles were highly anisotropic over the range of conditions studied. The dc bias had to exceed certain voltages before significant etch rates were obtained. These values were −50 V for AlN. As such, increasing selectivity for GaN over Al0.28Ga0.72N and AlN was achieved at dc biases below −40 V. At −20 V, the GaN etch rates were 38 times greater than AlN and a factor of 10 greater than Al0.28Ga0.72N. These results demonstrate the importance of ion bombardment in the etching of these materials.
Japanese Journal of Applied Physics | 1997
Ok Hyun Nam; M. D. Bremser; B. L. Ward; R. J. Nemanich; Robert F. Davis
The selective growth of GaN and Al0.2Ga0.8N has been achieved on stripe and circular patterned GaN/AlN/6H-SiC(0001) multilayer substrates. Growth morphologies on the stripe patterns were a function of the widths of the stripes and the flow rate of triethylgallium. No ridge growth was observed along the top edges of the truncated stripe patterns. Smooth (0001) top facets formed on stripes ≥5 µ m wide. Uniform hexagonal pyramid arrays of undoped GaN and Si-doped GaN were successfully grown on 5 µ m circular patterns. Field emission measurements of a Si-doped GaN hexagonal pyramid array exhibited a turn-on field of 25 V/µ m for an emission current of 10.8 nA at an anode-to-sample distance of 27 µ m.
Applied Surface Science | 1996
Mark C. Benjamin; M. D. Bremser; T.W. Weeks; S. W. King; Robert F. Davis; R. J. Nemanich
Abstract This study presents results of UV photoemission measurements of the surface and interface properties of heteroepitaxial AlGaN on 6H-SiC. Previous results have demonstrated a negative electron affinity of AlN on 6H-SiC. In this study Al x Ga 1− x N alloy films were grown by organometallic vapor phase epitaxy (OMVPE) and doped with silicon. The analytical techniques included UPS, Auger electron spectroscopy, and LEED. All analysis took place in an integrated UHV transfer system which included the analysis techniques, a surface processing chamber and a gas source MBE. The OMVPE alloy samples were transported in air to the surface characterization system while the AlN and GaN investigations were prepared in situ. The surface electronic states were characterized by surface normal UV photoemission to determine whether the electron affinity was positive or negative. Two aspects of the photoemission distinguish a surface that exhibits a NEA: (1) the spectrum exhibits a sharp peak in the low kinetic energy region, and (2) the width of the spectrum is hv - E g . The in situ prepared AlN samples exhibited the characteristics of a NEA while the GaN and Al 0.13 Ga 0.87 N samples did not. The Al 0.55 Ga 0.45 N sample shows a low positive electron affinity. Annealing of the sample to > 400°C resulted in the disappearance of the sharp emission features, and this effect was related to contaminant effects on the surface. The results suggest the potential of nitride based cold cathode electron emitters.
Applied Physics Letters | 1997
A. T. Sowers; J. A. Christman; M. D. Bremser; B. L. Ward; Robert F. Davis; R. J. Nemanich
Cold cathode structures have been fabricated using AlN and graded AlGaN structures (deposited on n-type 6H-SiC) as the thin film emitting layer. The cathodes consist of an aluminum grid layer separated from the nitride layer by a SiO2 layer and etched to form arrays of either 1, 3, or 5 μm holes through which the emitting nitride surface is exposed. After fabrication, a hydrogen plasma exposure was employed to activate the cathodes. Cathode devices with 5 μm holes displayed emission for up to 30 min before failing. Maximum emission currents ranged from 10–100 nA and required grid voltages ranging from 20–110 V. The grid currents were typically 1 to 104 times the collector currents.
Applied Physics Letters | 1996
F. R. Chien; X. J. Ning; Susanne Stemmer; P. Pirouz; M. D. Bremser; Robert F. Davis
Lattice defects in GaN epilayers grown on 6H–SiC(0001) by metalorganic vapor phase epitaxy (MOVPE) have been characterized by transmission electron microscopy (TEM). The predominant defects in the film were threading dislocations and half‐loops with Burgers vectors 1/3〈1120〉, [0001], and 1/3〈1123〉. Planar faults were also observed in the film that are thought to be inversion domain boundaries (IDBs).
Applied Physics Letters | 1996
N. V. Edwards; M. D. Bremser; T. W. Weeks; R. S. Kern; Robert F. Davis; D. E. Aspnes
Spectroscopic ellipsometry was used to assess the preparation of smooth and abrupt GaN, AlN, and AlGaN surfaces by wet chemical treatments in real time. About 20–50 A of overlayer typically can be removed from air‐exposed samples.