M Hunger

Heterogeneous Photocatalysis Applied to Concrete Pavement for Air Remediation

In the present work the degradation of nitrogen oxides (NOx) by concrete paving stones containing TiO2 to be applied in road construction is studied. A kinetic model is proposed to describe the photocatalytic reaction of nitric oxide (NO) in a standard flow laminar photoreactor irradiated with UV lamps. In addition the influence of several parameters that can affect the performance of these stones under outdoor conditions are investigated, such as irradiance, relative humidity and wind speed. The kinetic parameters present in the NO reaction rate are estimated employing experimental data obtained in the photoreactor. The obtained model predictions employing the determined kinetic constants are in good agreement with the experimental results of NO concentration at the reactor outlet.

The effect of various process conditions on the photocatalytic degradation of NO

This paper presents the research conducted on photocatalytic concrete products with respect to the evaluation of the effect of varying process conditions on the degradation of nitric oxide (NO). The degradation process under laboratory conditions is modeled using the Langmuir-Hinshelwood kinetic model as basic reaction model. The suitability of the model is validated by experimental data as well as data obtained from literature. Furthermore, the effect of variations of process conditions like irradiance and relative humidity on the reaction rate constant k and adsorption equilibrium constant K d are considered in the model.