M. J. Bickle

The Sholl Shear Zone, West Pilbara: evidence for a domain boundary structure from integrated tectonostratigraphic analyses, SHRIMP UPb dating and isotopic and geochemical data of granitoids

Abstract The Pilbara Block provides a record of Archaean continental growth involving the tectonic accretion of outboard island-arcs and collisions with other continental-scale fragments. This record of continental growth is balanced by breakup and strike-slip dismemberment of the continent. New SHRIMP UPb in zircon ages and SmNd data provide evidence in the West Pilbara which demonstrates that subduction-related and tectonic-accretion processes at the western margin of that ancestral continent between 3.15-2.78 Ga were coeval with, and genetically related to, crustal-scale tectonics and basin formation inboard of that margin. The tectonic division of the West Pilbara is defined by integrated tectonic analyses, geochronology, geochemistry and isotopic analyses. Geochronological studies clearly indicate that the western Pilbara comparises two domains with different recorded geohistories, whereas geochemistry and isotopic systematics reflect the changing tectonic regimes through time. In combination, these studies allow the development of a reconstruction of the relative positions of the domains through time on the western margin of the Pilbara Block. The supracrustal rocks of the northern Roebourne Lithotectonic Complex (Domain 6 in a Pilbarawide scheme) were formed in an island arc setting, facing an ocean to the north-west, prior to 3260 Ma, the time of emplacement of voluminous granitoids into the complex. In contrast, the supracrustal rocks of the southern Sholl Belt (Pilbara Domain 5) were formed in a back-arc setting behind a north-west-facing arc between 3125 and 3112 Ma, with more-or-less synchronous granite emplacement at about 3115 Ma. The two domains were tectonically juxtaposed, between 2991 and 2925 Ma, by the Sholl Shear Zone, a largely sinistral shear zone, with subsequent volcanism in both domains to about 2925 Ma. The Roebourne Lithotectonic Complex (Domain 6) is interpreted to be an allochthonous terrane, which formed north-east relative to its present position, but indigenous to the Pilbara Block rather than an exotic terrane. The East Pilbara is interpreted to have acted as a cratonic hinterland during the convergent margin tectonics that affected the two West Pilbara domains.

The age and origin of younger granitic plutons of the Shaw Batholith in the Archaean Pilbara Block, Western Australia

The whole-rock Pb-Pb method has been used to date four of the younger, mainly adamellite, late-tectonic plutonic phases within the ca. 3.5 Ga Shaw Batholith of the Archaean east Pilbara Block. Three suites give ages within error of 2966 Ma (Porphyritic Granites at 2948±50 Ma, Leuco-adamellites at 2943±46 Ma and Garden Creek Adamellite at 3007±48 Ma). The post-tectonic Cooglegong Adamellite gives an age of 2847±34 Ma. The Sm-Nd model isotopic systematics of all four suites indicate derivation from crust ranging between ca. 3200 and 3600 Ma in age. The sources for these four younger plutonic phases were heterogeneous and, although exhibiting some isotopic characteristics of the older (3.5−3.3 Ga) calc-alkali plutonic suites, were more depleted in the LIL elements Rb, U and Th. In addition, the Garden Creek Adamellite and the Cooglegong Adamellite lack the very fractionated and HREE-depleted REE patterns characteristic of both the older calc-alkali plutonic rocks and the Porphyritic Granites and Leuco-adamellites. The crust underlying the Shaw Batholith at ca. 2950 Ma must have been both markedly heterogeneous and variably depleted, a conclusion consistent with the complex tectonic and plutonic evolution of this region.

A strontium, neodymium and oxygen isotope study of hydrothermal metamorphism and crustal anatexis in the Trois Seigneurs Massif, Pyrenees, France

Nd, Sr, and O isotope analyses have been made on metamorphic and igneous rocks and minerals from a 310–340 Ma Hercynian-age metamorphic terrane in the Pyrenees, France. Lower Paleozoic shales and phyllites have 87Sr/86Sr values of 0.707–0.717 at 310 Ma, but model values at 310 Ma of 0.709–0.736 (based on assumed depositional age of 450 Ma and an initial 87Sr/86Sr=0.707). On a regional scale, 87Sr/86Sr was homogenized to about 0.713 to 0.717 in the higher-grade pelitic schists during metamorphism. Much of this 87Sr/86Sr exchange occurred at very low grades (below the biotite isograd), but significant changes also accompanied the δ18O lowering of the phyllites (+13 to +16) during their transformation to andalusite- and sillimanite-grade schists (δ18O=+11 to +12); all of these effects are attributed to pervasive interactions with hydrothermal fluids (Wickham and Taylor 1985). The data also show that a syn-metamorphic plutonic complex, dominated by a biotite granite body, was derived by mixing of a relatively mafic magmatic end-member (87Sr/86Sr∼ 0.7025–0.7050 and δ18O∼ +7.5 to +8.0) with two metasedimentary sources, both having 87Sr/86Sr∼0.715 and δ18O∼ +10.0 to +12.0, but with one being more homogeneous than the other. The more homogeneous component and the (mantle-derived?) magmatic end-member dominate at low structural levels within the complex. The less homogeneous end-member that dominates at high levels is clearly derived from the local Paleozoic pelitic schists. A Rb-Sr age of 330±20 Ma was obtained on hornblende from a deep level within the complex, which fixes this age for the regional metamorphism, as well. Although a post-metamorphic granodiorite magma body at Trois Seigneurs also displays heterogeneities in δ18O and 87Sr/86Sr (and thus does not give a clear-cut Rb-Sr isochron), the data are consistent with an emplacement age between 260 and 310 Ma, similar to ages of other late granodiorites in the Pyrenees. 143Nd/ 144Nd is very uniform within the Hercynian crust, both at Trois Seigneurs (ɛNd=−3 to −7) and elsewhere in the Pyrenees; almost all igneous lithologies have depleted-mantle, mid-Proterozoic model ages, consistent with efficient recycling of crustal material following original crustal accretion in this area at about 1600 Ma or earlier. Rb-Sr mineral ages exhibit a complex cooling history reflecting late Hercynian and Mesozoic thermal events. Our results show that profound homogenization of the 87Sr/86Sr and 18O/16O ratios of large volumes of the crust can occur during regional metamorphism and crustal anatexis, particularly in regions undergoing extensional tectonics. Such processes can significantly modify the isotopic compositions of the protoliths of granitic magmas; this may explain why many peraluminous Hercynian granitoids of Western Europe have anomalously low (87Sr/86Sr) initial values compared to their probable sedimentary parent rocks.

Origin of the 3500-3300 Ma calc-alkaline rocks in the Pilbara Archaean: isotopic and geochemical constraints from the Shaw Batholith

Abstract Calc-alkaline plutonic rocks, intruded at ∼3450Ma, comprise a major component of the Shaw Batholith in the Archaean east Pilbara Block, Western Australia. New whole-rock Pb isotopic geochronology confirms the extent of these rocks, but a minor plutonic phase is dated at 3338±52 Ma and represents a second plutonic event of the same age as much of the nearby Mt Edgar Batholith. The Sm-Nd isotopic systematics of the ∼3450Ma rocks imply their derivation from a heterogeneous source, which probably included a slightly older crustal component as well as a depleted mantle component. The 3338±52 Ma pluton includes components derived from crustal sources older than 3600 Ma. The geochemistry and SmNd isotopic systematics of these rocks are consistent with crustal growth in the early Archaean from upper mantle sources as depleted as the modern upper mantle. The Shaw Batholith calc-alkaline suites exhibit very similar chemical trends on variation diagrams to modern calc-alkaline plutonic rocks which can be modelled by a combination of mixing and fractionation. A suite collected from outcrops displaying prominent igneous layering shows distinct geochemical trends which can be modelled by differentiation into a component enriched in ferromagnesian minerals, principally hornblende, and possibly sphene, magnetite and epidote, and into a leucocratic component containing quartz, plagioclase and K-feld-par. These Archaean calc-alkaline plutonic rocks, in common with rocks from many other Archaean calc-alkaline provinces, exhibit very fractionated REE patterns with depleted HREE contents, a feature considered to result from equilibrium with garnet at depth in lower crustal regions. The geochemistry of the Pilbara Archaean calc-alkaline rocks is identical to the subset of modern continental-margin calc-alkaline plutonic rocks with fractionated REE patterns, such as those from the central and eastern Peninsular Ranges Batholith, western USA. The tectonic setting in which the Archaean calc-alkaline rocks formed is still not known. This reflects both uncertainty associated with the petrogenesis and environments of modern calc-alkaline rocks, as well as the limited knowledge of the precise timing and relationships of plutonic, depositional and tectonic events in the Pilbara Archaean.

Strontium and oxygen isotope decoupling in the Hercynian Trois Seigneurs Massif, Pyrenees: evidence for fluid circulation in a brittle regime

Systematic shifts of oxygen isotopic compositions in the higher grade parts of the high temperature-low pressure Hercynian metamorphic sequence, exposed in the Trois Seigneurs Massif, have previously been explained as a result of an influx of surface-derived water during the prograde part of the metamorphic cycle. It has been suggested that this caused a regional lowering of 87Sr/86Sr in the metamorphic sequence. Mapping of strontium isotopic compositions across a 15 m meta-carbonate horizon in the higher grade pelite-psammite sequence shows that strontium isotopic compositions were homogenised over length scales of metres or less during the Hercynian metamorphism, which brought the carbonate and pelite-psammite to oxygen isotopic equilibrium with a common fluid. Comparison of model pre-Hercynian 87Sr/86Sr profiles across the carbonate (based on a depositional/diagenetic age of 450 Ma and initial 87Sr/86Sr ratio of 0.7086 given by 10 m length scale averaging) with the post-Hercynian 87Sr/86Sr profile (calculated from analysed 87Sr/86Sr and Rb/Sr compositions) implies strontium isotopic diffusion distances of ca. 0.4 m in the carbonate and ca. 7 m in the pelite-psammite. The limited Sr-isotopic diffusion distance of 0.4–0.7 m within the carbonate is compatible with pervasive oxygen-isotopic exchange over distances restricted to 4–15 m if fluid strontium concentrations were between 4 and 50 ppm. The strontium isotopic transport distances are not compatible with pervasive oxygen isotopic alteration over the observed 5 km regional scale. Either the flow was perfectly layer-parallel or, more probably, the regional-scale alteration of oxygen took place by fluid circulation in the brittle regime early in, or prior to, the Hercynian metamorphic event. Flow along cracks with incomplete diffusive exchange between fluid and wall rock would allow greater decoupling of oxygen and strontium isotopic transport than pervasive advective transport with local fluid-solid equilibrium.

On the kinetics of textural equilibration in forsterite marbles

In the aureole of the Beinn an Dubhaich granite, Skye, the minimum observed median forsterite-calcite-calcite dihedral angle varies from 110° at the olivinein isograd to about 165° (the equilibrium value) at the granite-limestone contact. Laboratory experiments were performed to investigate the kinetics of this textural change. It was found that the rate of change of the forsterite-calcite-calcite dihedral angle followed approximately first-order kinetics with an activation energy of 48±4 kJ mol-1 for fluid-present conditions, and 90 ±4 kJ mol-1 for fluid-absent conditions. Scanning ion imaging demonstrated that, at least in the early stages of textural change, solution-reprecipitation of the calcite was the rate determining step in the fluid-present runs. The latter result and the value of the activation energy are both consistent with the activation energy found by previous authors for (albeit zeroth order) silicate-aqueous solution solution-reprecipitation reactions. The value of activation energy for the dry data does not correspond to those for either grain boundary or volume diffusion of oxygen or magnesium in forsterite. The mechanism for textural equilibration in the fluid-absent runs is uncertain. Application of the experimentally-derived rate equation to the Beinn an Dubhaich marbles gave activation energies higher than those obtained experimentally. It is concluded from consideration of grain growth effects that activation energies derived from the Beinn an Dubhaich marbles probably reflect textural equilibration under predominantly fluid-absent conditions.

Short Paper: Textures of forsterite–calcite marbles from the Beinn an Dubhaich aureole, Skye, and implications for the structure of metamorphic porosity

In the aureole of the Beinn an Dubhaich granite, forsterite grew with dihedral angles of less than 110° against calcite, but was progressively and variably annealed towards the equilibrium dihedral angle of 165°. New experimental estimates of calcite–calcite–fluid dihedral angles are presented, ranging from 50–90°. The early low angles may be due to rapid olivine growth into a fluid-filled porosity. The preservation of a range of textural states in the Beinn an Dubhaich aureole has the potential to provide information on the kinetics of grain boundary readjustments in metamorphic rocks, which control pore geometry and permeability.